KR930009649A - 세제 및/또는 표백조성물에 있어서 표백촉매 조성물과 그 제조방법 및 용도 - Google Patents

세제 및/또는 표백조성물에 있어서 표백촉매 조성물과 그 제조방법 및 용도 Download PDF

Info

Publication number
KR930009649A
KR930009649A KR1019920021843A KR920021843A KR930009649A KR 930009649 A KR930009649 A KR 930009649A KR 1019920021843 A KR1019920021843 A KR 1019920021843A KR 920021843 A KR920021843 A KR 920021843A KR 930009649 A KR930009649 A KR 930009649A
Authority
KR
South Korea
Prior art keywords
catalyst composition
bleaching catalyst
weight
bleaching
charge
Prior art date
Application number
KR1019920021843A
Other languages
English (en)
Inventor
델웰 프랑코스
로버트 피. 반 브리에트 마텐
Original Assignee
원본미기재
유니레버 엔브이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 원본미기재, 유니레버 엔브이 filed Critical 원본미기재
Publication of KR930009649A publication Critical patent/KR930009649A/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

잘 부서지지 않는 혼합과립의 형태로서의 표백 촉매 조성물에 관한 것이다. 각 과립은 용이하게 산화가능한 유기물질이 들어있지 않으며, 망간 복합체 촉매와 경우에 따라서 비활성염 및 결합제를 함유한다.
이러한 과립을 함유하는 세제 조성물은 양호한 과산화물과 효소 안정성을 갖는다.

Description

세제 및/또는 표백조성물에 있어서 표백촉매 조성물과 그 제조방법 및 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 잘 부서지지 않는 혼합과립의 형태인 표백 촉매 조성물로서, 개개의 과립은 용이하게 산화가능한 유기물질이 들어 있지 않으며, (i) 망간 복합체 촉매 0.5-8중량%와, (ii)클로라이드, 카보네이트 및 이들의 혼합물로부터 선택된 비활성염 0-90중량%; 및 (iii) 산화불가능한 수용성 중합체, 규산 알칼리금속염, 포화지방산 비누 혼합물 및 이들의 혼합물로부터 선택된 결합제 5-91중량%를 함유하는 것을 특징으로 하는 표백촉매 조성물.
  2. 제1항에 있어서, 망각 복합체 촉매는 다음 일반식을 갖는 것을 특징으로 하는 표백 촉매 조성무.
    [ 위식에서, Mn은 각각 III 또는 IV산화 상태일 수 있는 망간이며, X는 각각 H2O, O2 2-,O2-,-OH, HO2 -, SH-, S2-, ＞ SO, Cl-, SCN-, N3 -, N3-, RSO3 -, RCOO-, NH2 -및 NR3(여기서, R은 H, 알킬, 아릴, 경우에 따라서 양쪽 모두 치환된 것, R1COO(R1은 알킬, 아릴, 경우에 따라서 양쪽 모두 친환된 것)로 구성된 군으로부터 선택된 배위 결합 또는 브리징류이며; L은 질소원자 모두 또는 일부를 통해서 망간 중심에 배위 결합되어 있는 다수의 질소를 함유하는 유기분자인 리간드이며; Z는 복합체의 전하이고 양 또는 음일 수 있는 정수이며; Y는 중성 전하를 이끄는 일가 또는 다가 카운터 - 이온이고 복합체의 Z전하에 다가 좌우되며; q=Z/[전하 Y]임]
  3. 제3항에 있어서, 망간 복합제 촉매는 다음 일반식인 것을 특징으로 하는 표백촉매조성물.
    (위식에서, Mn은 +4 산화상태의 망간이며; R은 알킬, 시클로알킬, 아릴, 벤질 및 이들의 래디칼 조합의 군으로부터 선택된 C1-C20래디칼이며; 적어도 두 개의 R 래디칼은 또한 망간과 배위 결합되어 있는 두 개의 산소사이에 브리징 단위를 형성하도록 다른 하나의 R에 연결될 수 있으며; L은 망간에 배위 결합되어 있는 적어도 3개의 질소원자를 C3-C60래디칼로부터 선택된 리간드이며; Y는 산화에 안정한 카운터이온에 좌우됨)
  4. 제1항에 있어서, 망간 복합체는 다음 일반식인 것을 특징으로 하는 표백촉에 조성물.
    [(위식에서, Mn 은 II, III 또는 IV 산화상태중 어느것일 수 있으며; X는 각각 RO-를 제외한 Cl-, Br-, I, F-, NCS-, N3 -, I3 -, NH3, RCOO-, RSO3, ROS4 -(여기서, R은 알킬, 아릴, 경우에 따라 양쪽 모두 치환된 것, OH-, O2 2-, HOO-, H2O, SH, CN-, OCN-, S4 2-및 이들의 혼합물로부터 선택된 배위 결합류이며; P는 1-3의 정수이며; Z 는 복합체의 전하를 나타내고 양, 제로 또는 음일 수 있는 정수이며; Y는 복합체의 전하 Z에 좌우되는 카운터-이온이며; q=z/[전하 Y]임]이며; L은 다음 일반식의 마크로시클릭 유기분자인 리간드임.
    (여기서, t는 2이고 s는 3이며, R1, R2및 R3는 각각 H, C1-C6알킬, 아릴, 경우에 따라서 양쪽 모두 치환된것임.
  5. 제1항에 있어서, 비활성 염을 50-90중량% 함유하는 것을 특징으로 하는 표백 촉매 조성물.
  6. 제1항에 있어서, 결합체는 30℃이상의 융점을 갖는 특징으로 하는 표백 촉매 조성물.
  7. 제1항 내지 제6항중 어느 한 항에 있어서, 결합제는 알칼리성 규산나트륨인 것을 특징으로 하는 표백 촉매 조성물.
  8. 제1항에 있어서, 비활성 염은 탄산나트륨인 것을 특징으로 하는 표백 촉매 조성물.
  9. 제1항에 있어서, 과립내의 촉매의 평균입자 크기는 200㎛ 이하인 것을 특징으로 하는 표백 촉매 조성물.
  10. 제1항에 있어서, 고립에는 표면 분말 코팅이 구비된 것을 특징으로 하는 표백 촉매 조성물.
  11. 개개의 과립은 용이하게 산화가능한 유기물질이 들어 있지 않으며, (i) 망간 복합체 촉매 0.5-8중량%와, (ii)클로라이드, 카보네이트 및 이들의 혼합물로부터 선택된 비활성염 0-90중량%; 및 (iii) 산화불가능한 수용성 중합체, 규산 알칼리금속염, 포화지방산 비누 혼합물 및 이들의 혼합물로부터 선택된 결합제 5-91%를 함유하는, 잘 부서지지 않는 혼합 과립의 형태인 표백촉매조성물을 제조하는 방법으로서, 이 방법은 (i), (ii), 및 (iii)의 혼합물은 형성한 다음 팬-과립화기; 유동화 베드; 저에너지 혼합기, 압축장치, 및 결합된 혼합기 과립화기로 선택된 장치를 사용하여 과립화시키는 공정을 포함하는 것을 특징으로 하는 제조방법.
  12. (i) 제1항에 따른 표백촉매 조성물 0.02-0.08중량%와, (ii) 계면활성제 0.5-50중량%; 및 (iii) 세척력 빌더 5-80중량%를 함유하는 세제조성물.
  13. 제1항에 따른 표백촉매 조성물을 사용하여 수성 매개물내에서 오염된 기질과 접촉시키는 방법을 포함하는 오염된 기질의 표백방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920021843A 1991-11-20 1992-11-20 세제 및/또는 표백조성물에 있어서 표백촉매 조성물과 그 제조방법 및 용도 KR930009649A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919124581A GB9124581D0 (en) 1991-11-20 1991-11-20 Bleach catalyst composition,manufacture and use thereof in detergent and/or bleach compositions
GB9124581.1 1991-11-20

Publications (1)

Publication Number Publication Date
KR930009649A true KR930009649A (ko) 1993-06-21

Family

ID=10704883

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920021843A KR930009649A (ko) 1991-11-20 1992-11-20 세제 및/또는 표백조성물에 있어서 표백촉매 조성물과 그 제조방법 및 용도

Country Status (13)

Country Link
US (1) US5356554A (ko)
EP (1) EP0544440A3 (ko)
JP (1) JPH0712437B2 (ko)
KR (1) KR930009649A (ko)
CN (1) CN1073477A (ko)
AU (1) AU660199B2 (ko)
BR (1) BR9204465A (ko)
CA (1) CA2083192A1 (ko)
GB (1) GB9124581D0 (ko)
IN (1) IN177134B (ko)
MX (1) MX9206718A (ko)
TR (1) TR28055A (ko)
ZA (1) ZA928998B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000005710A (ko) * 1998-06-05 2000-01-25 성재갑 표백활성화제

Families Citing this family (157)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5194416A (en) * 1991-11-26 1993-03-16 Lever Brothers Company, Division Of Conopco, Inc. Manganese catalyst for activating hydrogen peroxide bleaching
GB9305598D0 (en) * 1993-03-18 1993-05-05 Unilever Plc Bleach catalyst composition
DE69412188T2 (de) * 1993-06-19 1999-03-11 Ciba Geigy Ag Inhibierung der Wiederabsorption von migrierenden Farbstoffen in der Waschlösung
US5691296A (en) * 1993-07-14 1997-11-25 The Procter & Gamble Company Percarbonate bleach particles coated with a partially hydrated crystalline aluminosilicate flow aid
AU7506694A (en) * 1993-09-03 1995-03-22 Unilever Plc Bleach catalyst composition
GB9318295D0 (en) * 1993-09-03 1993-10-20 Unilever Plc Bleach catalyst composition
CA2187169A1 (en) * 1994-04-07 1995-10-19 Gerard Marcel Abel Baillely Bleach compositions comprising metal-containing bleach catalysts
DE69504489T2 (de) * 1994-04-07 1999-05-20 Procter & Gamble Bleichmittel enthaltend metall haltige bleichkatalysatoren und antioxidantien
DE4416438A1 (de) * 1994-05-10 1995-11-16 Basf Ag Ein- oder mehrkernige Metall-Komplexe und ihre Verwendung als Bleich- und Oxidationskatalysatoren
US5560748A (en) * 1994-06-10 1996-10-01 The Procter & Gamble Company Detergent compositions comprising large pore size redox catalysts
ES2221665T3 (es) 1994-07-21 2005-01-01 Ciba Specialty Chemicals Holding Inc. Composicion de blanqueo de tejidos.
AU3077495A (en) * 1994-08-19 1996-03-14 Unilever Plc Detergent bleach composition
US5578136A (en) 1994-08-31 1996-11-26 The Procter & Gamble Company Automatic dishwashing compositions comprising quaternary substituted bleach activators
AU711960B2 (en) * 1995-02-02 1999-10-28 Procter & Gamble Company, The Automatic dishwashing compositions comprising cobalt chelated catalysts
US5968881A (en) * 1995-02-02 1999-10-19 The Procter & Gamble Company Phosphate built automatic dishwashing compositions comprising catalysts
ES2163006T3 (es) * 1995-02-02 2002-01-16 Procter & Gamble Metodo para eliminar manchas de te en lavavajillas automaticos usando composiciones que comprenden catalizadores de cobalto (iii).
GB2297978A (en) 1995-02-15 1996-08-21 Procter & Gamble Detergent compositions containing amylase
US5648064A (en) * 1995-07-07 1997-07-15 Gaffar; Abdul Oral compositions having accelerated tooth whitening effect
ATE203051T1 (de) * 1995-06-16 2001-07-15 Procter & Gamble Maschinengeschirrspülmittel, die kobaltkatalysatoren enthalten
CA2224559A1 (en) * 1995-06-16 1997-01-03 The Procter & Gamble Company Bleach compositions comprising cobalt catalysts
US5703034A (en) * 1995-10-30 1997-12-30 The Procter & Gamble Company Bleach catalyst particles
BR9612095A (pt) * 1995-12-20 1999-05-11 Procter & Gamble Partículas de catalisador de alvejante e enzima
GB9601522D0 (en) * 1996-01-25 1996-03-27 Unilever Plc Detergent composition
WO1997042282A1 (en) 1996-05-03 1997-11-13 The Procter & Gamble Company Detergent compositions comprising polyamine polymers with improved soil dispersancy
US6218351B1 (en) 1998-03-06 2001-04-17 The Procter & Gamble Compnay Bleach compositions
US20050187126A1 (en) * 2002-08-27 2005-08-25 Busch Daryle H. Catalysts and methods for catalytic oxidation
US20030017941A1 (en) 1997-03-07 2003-01-23 The Procter & Gamble Company Catalysts and methods for catalytic oxidation
US20080125344A1 (en) * 2006-11-28 2008-05-29 Daryle Hadley Busch Bleach compositions
BR9808840A (pt) 1997-03-07 2000-07-04 Procter & Gamble Composições alvejantes
ZA981883B (en) * 1997-03-07 1998-09-01 Univ Kansas Catalysts and methods for catalytic oxidation
US6387862B2 (en) 1997-03-07 2002-05-14 The Procter & Gamble Company Bleach compositions
CA2282466C (en) 1997-03-07 2005-09-20 The Procter & Gamble Company Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids
DE19714122A1 (de) * 1997-04-05 1998-10-08 Clariant Gmbh Bleichaktive Metall-Komplexe
DE19719397A1 (de) * 1997-05-07 1998-11-12 Clariant Gmbh Bleichaktive Metall-Komplexe
DE19728021A1 (de) * 1997-07-01 1999-01-07 Clariant Gmbh Metall-Komplexe als Bleichaktivatoren
MA24811A1 (fr) 1997-10-23 1999-12-31 Procter & Gamble Compositions de lavage contenant des variantes de proteases multisubstituees
US6696401B1 (en) 1999-11-09 2004-02-24 The Procter & Gamble Company Laundry detergent compositions comprising zwitterionic polyamines
US6812198B2 (en) 1999-11-09 2004-11-02 The Procter & Gamble Company Laundry detergent compositions comprising hydrophobically modified polyamines
US6846791B1 (en) 1999-11-09 2005-01-25 The Procter & Gamble Company Laundry detergent compositions comprising hydrophobically modified polyamines
AU2002239475A1 (en) 2000-10-27 2002-05-27 The Procter And Gamble Company Stabilized liquid compositions
US6485709B2 (en) * 2001-01-23 2002-11-26 Addent Inc. Dental bleaching gel composition, activator system and method for activating a dental bleaching gel
GB0103871D0 (en) * 2001-02-16 2001-04-04 Unilever Plc Bleaching composition of enhanced stability and a process for making such a composition
JP2006504809A (ja) 2002-05-02 2006-02-09 ザ プロクター アンド ギャンブル カンパニー 洗剤組成物及びその成分
US20040048763A1 (en) * 2002-08-27 2004-03-11 The Procter & Gamble Co. Bleach compositions
KR20040033166A (ko) * 2002-10-11 2004-04-21 주식회사 엘지생활건강 표백활성화제의 제조 방법
WO2004069979A2 (en) 2003-02-03 2004-08-19 Unilever Plc Laundry cleansing and conditioning compositions
BR0318303A (pt) 2003-05-07 2006-07-11 Ciba Sc Holding Ag composição alvejante e composição detergente alvejante
US20070072787A1 (en) * 2003-05-21 2007-03-29 Menno Hazenkamp Stable particulate composition comprising bleach catalysts
US20050090420A1 (en) * 2003-10-28 2005-04-28 Aaron Brian A. Method of cleaning white garments with a detergent, bleach and enzyme combination
PT2402087E (pt) * 2005-05-27 2013-07-22 Catexel Ltd Sais pré-formados de catalisador de metal de transição
GB2428694A (en) * 2005-07-28 2007-02-07 Unilever Plc Acidic granules comprising transition metal catalyst
US7972386B2 (en) * 2005-10-12 2011-07-05 Conopco, Inc. Bleaching of substrates
DE102006036896A1 (de) * 2006-08-04 2008-02-07 Henkel Kgaa Wasch- oder Reinigungsmittel mit größenoptimierten Bleichwirkstoffteilchen
DE102007039651A1 (de) 2006-11-27 2009-02-26 Henkel Ag & Co. Kgaa Bleichkatalysatorgranulat
EP2104765B1 (en) * 2007-01-16 2012-08-01 Catexel Limited Bleaching of substrates
US20080177089A1 (en) 2007-01-19 2008-07-24 Eugene Steven Sadlowski Novel whitening agents for cellulosic substrates
DE102007006628A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006630A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007006629A1 (de) 2007-02-06 2008-08-07 Henkel Ag & Co. Kgaa Reinigungsmittel
GB0718777D0 (en) * 2007-09-26 2007-11-07 Reckitt Benckiser Nv Composition
DE102007059968A1 (de) 2007-12-11 2009-06-18 Henkel Ag & Co. Kgaa Reinigungsmittel
DE102007059970A1 (de) 2007-12-11 2009-09-10 Henkel Ag & Co. Kgaa Reinigungsmittel
JP5422116B2 (ja) * 2007-12-19 2014-02-19 ライオン株式会社 漂白助剤、および該漂白助剤を含有する漂白助剤粒子
JP5401034B2 (ja) * 2007-12-19 2014-01-29 ライオン株式会社 漂白助剤、および該漂白助剤を含有する漂白助剤粒子
JP5150238B2 (ja) * 2007-12-19 2013-02-20 ライオン株式会社 殺菌・除菌用酸化触媒、および該触媒を含有する殺菌・除菌用酸化触媒粒子
JP2009149778A (ja) * 2007-12-20 2009-07-09 Lion Corp 漂白活性化成分の造粒物およびそれを含有する洗浄剤組成物、ならびに漂白活性化成分の造粒物の製造方法
US20090325841A1 (en) * 2008-02-11 2009-12-31 Ecolab Inc. Use of activator complexes to enhance lower temperature cleaning in alkaline peroxide cleaning systems
NZ586396A (en) * 2008-02-11 2012-10-26 Ecolab Inc Cleaning process involving a composition of a transition metal activator, a source of alkalinity and an oxygen-releasing source which is useful for a clean-in-place method
DE102009017724A1 (de) 2009-04-11 2010-10-14 Clariant International Limited Bleichmittelgranulate
DE102009017722A1 (de) 2009-04-11 2010-10-14 Clariant International Limited Bleichmittelgranulate mit Aktivcoating
WO2011005730A1 (en) 2009-07-09 2011-01-13 The Procter & Gamble Company A catalytic laundry detergent composition comprising relatively low levels of water-soluble electrolyte
WO2011005623A1 (en) 2009-07-09 2011-01-13 The Procter & Gamble Company Laundry detergent composition comprising low level of bleach
WO2011005804A1 (en) 2009-07-09 2011-01-13 The Procter & Gamble Company Method of laundering fabric using a liquid laundry detergent composition
EP2451914A1 (en) 2009-07-09 2012-05-16 The Procter & Gamble Company A catalytic laundry detergent composition comprising relatively low levels of water-soluble electrolyte
WO2011005910A1 (en) 2009-07-09 2011-01-13 The Procter & Gamble Company Method of laundering fabric using a compacted laundry detergent composition
GB0913808D0 (en) 2009-08-07 2009-09-16 Mcbride Robert Ltd Dosage form detergent products
PL2292725T5 (pl) 2009-08-13 2022-11-07 The Procter And Gamble Company Sposób prania tkanin w niskiej temperaturze
US20110166370A1 (en) 2010-01-12 2011-07-07 Charles Winston Saunders Scattered Branched-Chain Fatty Acids And Biological Production Thereof
WO2011106906A1 (en) 2010-03-03 2011-09-09 Unilever Plc Preparation of bleaching catalysts
WO2011146604A2 (en) 2010-05-18 2011-11-24 Milliken & Company Optical brighteners and compositions comprising the same
WO2011146602A2 (en) 2010-05-18 2011-11-24 Milliken & Company Optical brighteners and compositions comprising the same
US8476216B2 (en) 2010-05-28 2013-07-02 Milliken & Company Colored speckles having delayed release properties
CN103025930B (zh) 2010-07-02 2014-11-12 宝洁公司 递送活性剂的方法
CN102971408B (zh) 2010-07-02 2016-03-02 宝洁公司 洗涤剂产品
MX337814B (es) 2010-07-02 2016-03-18 Procter & Gamble Procedidmiento para fabricar películas a partir de tramas de tela no tejida.
EP2588652B1 (en) 2010-07-02 2019-06-12 The Procter and Gamble Company Method for treating a fabric
RU2541949C2 (ru) 2010-07-02 2015-02-20 Дзе Проктер Энд Гэмбл Компани Филаменты, содержащие активный агент, нетканые полотна и способы их получения
US20120172281A1 (en) 2010-07-15 2012-07-05 Jeffrey John Scheibel Detergent compositions comprising microbially produced fatty alcohols and derivatives thereof
RU2012154731A (ru) 2010-07-15 2014-08-20 Дзе Проктер Энд Гэмбл Компани Композиции, содержащие соединение с цепью, разветвленной вблизи конца, и способы их получения
US8715368B2 (en) 2010-11-12 2014-05-06 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
RU2013136501A (ru) 2011-02-17 2015-03-27 Дзе Проктер Энд Гэмбл Компани Линейные алкилфенилсульфонаты на основе биологического сырья
EP2678410B1 (en) 2011-02-17 2017-09-13 The Procter and Gamble Company Composiitons comprising mixtures of c10-c13 alkylphenyl sulfonates
CN103492062A (zh) 2011-02-25 2014-01-01 美利肯公司 胶囊及包含其的组合物
WO2013002786A1 (en) 2011-06-29 2013-01-03 Solae Baked food compositions comprising soy whey proteins that have been isolated from processing streams
BR112014005435B1 (pt) 2011-09-08 2019-11-12 Catexel Ltd método de preparação de um pó e pó
AR090031A1 (es) 2011-09-20 2014-10-15 Procter & Gamble Composiciones detergentes que comprenden sistemas tensioactivos sostenibles que comprenden tensioactivos derivados de isoprenoide
AR088442A1 (es) 2011-09-20 2014-06-11 Procter & Gamble Composiciones detergentes que comprenden sistemas surfactantes primarios que comprenden surfactantes con base en isoprenoides altamente ramificados y otros surfactantes
AR088757A1 (es) 2011-09-20 2014-07-02 Procter & Gamble Composiciones detergentes con alta espuma que comprenden surfactantes con base de isoprenoide
AR088758A1 (es) 2011-09-20 2014-07-02 Procter & Gamble Composiciones detergentes de facil enjuague que comprenden surfactantes basados en isoprenoides
WO2013043803A2 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company Detergent compositions comprising specific blend ratios of isoprenoid-based surfactants
FR2985272B1 (fr) 2012-01-04 2021-10-22 Procter & Gamble Structures fibreuses contenant des actifs et ayant des regions multiples aux caracteristiques distinctes
US8980816B2 (en) 2012-01-04 2015-03-17 The Procter & Gamble Company Fibrous structures comprising particles and methods for making same
WO2013103629A1 (en) 2012-01-04 2013-07-11 The Procter & Gamble Company Active containing fibrous structures with multiple regions
WO2014018309A1 (en) 2012-07-26 2014-01-30 The Procter & Gamble Company Low ph liquid cleaning compositions with enzymes
WO2014160820A1 (en) 2013-03-28 2014-10-02 The Procter & Gamble Company Cleaning compositions containing a polyetheramine
DE102013010549A1 (de) 2013-06-15 2014-12-18 Clariant International Ltd. Bleichmittel-Co-Granulate
DE102013010150A1 (de) 2013-06-15 2014-12-18 Clariant International Ltd. Bleichkatalysatorgranulate
HUE036889T2 (hu) 2013-06-20 2018-08-28 Chemsenti Ltd Fehérítõ és oxidációs katalizátor
ES2894685T3 (es) 2013-08-16 2022-02-15 Catexel Tech Limited Composición
DE112014005598B4 (de) 2013-12-09 2022-06-09 The Procter & Gamble Company Faserstrukturen einschließlich einer Wirksubstanz und mit darauf gedruckter Grafik
CA2941253A1 (en) 2014-03-27 2015-10-01 Frank Hulskotter Cleaning compositions containing a polyetheramine
EP3122850A1 (en) 2014-03-27 2017-02-01 The Procter & Gamble Company Cleaning compositions containing a polyetheramine
EP3152288A1 (en) 2014-06-06 2017-04-12 The Procter & Gamble Company Detergent composition comprising polyalkyleneimine polymers
US10196592B2 (en) 2014-06-13 2019-02-05 Ecolab Usa Inc. Enhanced catalyst stability for alkaline detergent formulations
US9624119B2 (en) * 2014-06-13 2017-04-18 Ecolab Usa Inc. Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations
CN106795464B (zh) * 2014-07-08 2020-02-21 诺维信公司 酶和漂白催化剂的共颗粒
DK2966161T3 (en) * 2014-07-08 2019-02-25 Dalli Werke Gmbh & Co Kg ENZYME BLENDIC CATALYST CATEGRANULATE SUITABLE FOR DETERGENT COMPOSITIONS
EP3075832B1 (en) 2015-03-30 2021-04-14 Dalli-Werke GmbH & Co. KG Manganese-amino acid compounds in cleaning compositions
US10280386B2 (en) 2015-04-03 2019-05-07 Ecolab Usa Inc. Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid
US9783766B2 (en) 2015-04-03 2017-10-10 Ecolab Usa Inc. Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid
CN107683326B (zh) * 2015-05-07 2021-10-08 诺维信公司 用于餐具洗涤洗涤剂的锰漂白催化剂/酶颗粒
US9902923B2 (en) 2015-10-13 2018-02-27 The Procter & Gamble Company Polyglycerol dye whitening agents for cellulosic substrates
US10155868B2 (en) 2015-10-13 2018-12-18 Milliken & Company Whitening agents for cellulosic substrates
US9745544B2 (en) 2015-10-13 2017-08-29 The Procter & Gamble Company Whitening agents for cellulosic substrates
US10597614B2 (en) 2015-10-13 2020-03-24 The Procter & Gamble Company Whitening agents for cellulosic substrates
US9976035B2 (en) 2015-10-13 2018-05-22 Milliken & Company Whitening agents for cellulosic substrates
US9777250B2 (en) 2015-10-13 2017-10-03 Milliken & Company Whitening agents for cellulosic substrates
US10308900B2 (en) 2015-12-22 2019-06-04 Milliken & Company Occult particles for use in granular laundry care compositions
PL3190168T3 (pl) 2016-01-06 2019-10-31 Dalli Werke Gmbh & Co Kg Powlekany katalizator bielenia
EP4197598A1 (en) 2017-01-27 2023-06-21 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697906B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles and product-shipping assemblies for containing the same
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697905B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
CA3094073A1 (en) 2018-03-19 2019-09-26 Ecolab Usa Inc. Liquid detergent compositions containing bleach catalyst
WO2019241629A1 (en) 2018-06-15 2019-12-19 Ecolab Usa Inc. Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid
US20200123472A1 (en) 2018-10-18 2020-04-23 Milliken & Company Polyethyleneimine compounds containing n-halamine and derivatives thereof
US11732218B2 (en) 2018-10-18 2023-08-22 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11518963B2 (en) 2018-10-18 2022-12-06 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11299591B2 (en) 2018-10-18 2022-04-12 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11466122B2 (en) 2018-10-18 2022-10-11 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US20200123319A1 (en) 2018-10-18 2020-04-23 Milliken & Company Polyethyleneimine compounds containing n-halamine and derivatives thereof
US20200123475A1 (en) 2018-10-18 2020-04-23 Milliken & Company Polyethyleneimine compounds containing n-halamine and derivatives thereof
WO2020123889A1 (en) 2018-12-14 2020-06-18 The Procter & Gamble Company Foaming fibrous structures comprising particles and methods for making same
US11485934B2 (en) 2019-08-02 2022-11-01 The Procter & Gamble Company Foaming compositions for producing a stable foam and methods for making same
US20210148044A1 (en) 2019-11-15 2021-05-20 The Procter & Gamble Company Graphic-Containing Soluble Articles and Methods for Making Same
JP2023517850A (ja) 2020-02-28 2023-04-27 カテクセル テクノロジーズ リミテッド 分解方法
US20210269747A1 (en) 2020-03-02 2021-09-02 Milliken & Company Composition Comprising Hueing Agent
US11718814B2 (en) 2020-03-02 2023-08-08 Milliken & Company Composition comprising hueing agent
US20210277335A1 (en) 2020-03-02 2021-09-09 Milliken & Company Composition Comprising Hueing Agent
US20220079862A1 (en) 2020-09-14 2022-03-17 Milliken & Company Hair care composition containing polymeric colorant
US11351106B2 (en) 2020-09-14 2022-06-07 Milliken & Company Oxidative hair cream composition containing thiophene azo colorant
US11344492B2 (en) 2020-09-14 2022-05-31 Milliken & Company Oxidative hair cream composition containing polymeric colorant
EP3967742A1 (en) 2020-09-15 2022-03-16 WeylChem Performance Products GmbH Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same
EP4008765A1 (en) 2020-12-07 2022-06-08 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and bleaching agent and cleaning agent comprising same
WO2022197295A1 (en) 2021-03-17 2022-09-22 Milliken & Company Polymeric colorants with reduced staining
CN117043401A (zh) 2021-05-28 2023-11-10 宝洁公司 包含表面活性剂的基于天然聚合物的纤维元件及其制备方法
EP4296343A1 (en) 2022-06-24 2023-12-27 WeylChem Performance Products GmbH Compositions comprising protonated triazacyclic compounds and manganese(ii) acetate, manufacturing thereof, and bleaching and cleaning agent comprising same

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR76237B (ko) * 1981-08-08 1984-08-04 Procter & Gamble
GB8329762D0 (en) * 1983-11-08 1983-12-14 Unilever Plc Manganese adjuncts
US4711748A (en) * 1985-12-06 1987-12-08 Lever Brothers Company Preparation of bleach catalyst aggregates of manganese cation impregnated aluminosilicates by high velocity granulation
US4728455A (en) * 1986-03-07 1988-03-01 Lever Brothers Company Detergent bleach compositions, bleaching agents and bleach activators
GB8720863D0 (en) * 1987-09-04 1987-10-14 Unilever Plc Metalloporphyrins
ES2008833A6 (es) * 1988-10-25 1989-08-01 Camp Jabones Composiciones blanqueantes para materias textiles yno celulosicas con alta efectividad a bajas temperaturas, y procedimiento de blanqueo con las mismas.
GB8908416D0 (en) * 1989-04-13 1989-06-01 Unilever Plc Bleach activation
DE69125309T2 (de) * 1990-05-21 1997-07-03 Unilever Nv Bleichmittelaktivierung
US5194416A (en) * 1991-11-26 1993-03-16 Lever Brothers Company, Division Of Conopco, Inc. Manganese catalyst for activating hydrogen peroxide bleaching
US5153161A (en) * 1991-11-26 1992-10-06 Lever Brothers Company, Division Of Conopco, Inc. Synthesis of manganese oxidation catalyst
US6547501B2 (en) * 2001-03-22 2003-04-15 Heidelberger Druckmaschinen Ag Device and method for binding printed products

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000005710A (ko) * 1998-06-05 2000-01-25 성재갑 표백활성화제

Also Published As

Publication number Publication date
ZA928998B (en) 1994-05-20
MX9206718A (es) 1993-06-01
EP0544440A2 (en) 1993-06-02
JPH0712437B2 (ja) 1995-02-15
US5356554A (en) 1994-10-18
IN177134B (ko) 1996-11-16
AU2855992A (en) 1993-06-17
EP0544440A3 (en) 1994-05-18
BR9204465A (pt) 1993-05-25
CA2083192A1 (en) 1993-05-21
JPH0655078A (ja) 1994-03-01
CN1073477A (zh) 1993-06-23
TR28055A (tr) 1995-12-11
AU660199B2 (en) 1995-06-15
GB9124581D0 (en) 1992-01-08

Similar Documents

Publication Publication Date Title
KR930009649A (ko) 세제 및/또는 표백조성물에 있어서 표백촉매 조성물과 그 제조방법 및 용도
GB2149316B (en) Stabilized and protected manganese bleach catalysts
CA2042738A1 (en) Bleach activation
WO1994021777A1 (en) Bleach catalyst composition
CN105110392B (zh) 一种非选择性重金属废水快速净化剂
KR930012103A (ko) 표백촉매, 표백조성물 및 얼룩기질의 표백방법
RU2007116957A (ru) Стабилизированная кислородвыделяющая композиция
RU97108292A (ru) Отбеливающий агент
JPS62244443A (ja) 脱酸素剤
EP0224953A3 (en) Phosphates in manganese catalyzed bleach compositions
JP2005514478A5 (ko)
JP2002532615A5 (ko)
CA2434620A1 (en) Bleaching composition of enhanced stability and a process for making such a composition
Mehrotra et al. Heterometallic alkoxides containing alkoxometallate (IV) ligands: synthesis and structural comparison
Fukuzumi et al. Electron transfer from tetrakis (isocyanide) rhodium (I) monomers, and the oligomers to iron (III) and cobalt (III) complexes. Enhancement of the reactivity by the oligomerization.
Burgess et al. Solvation of tris-maltolatoaluminium (III) and related complexes in methanol-water mixtures
JPS56152401A (en) Powdery herbicidal composition and its preparation
JPH09509190A (ja) 非水性液体洗剤組成物
JPH0751148B2 (ja) 消臭材料
CA2208038A1 (en) Detergent composition
KR890017265A (ko) 2가 망간이온[Mn(II)] 함유 조성물 및 그의 제조방법
JPH10245310A (ja) カビ取り剤組成物
WO2002043861A8 (en) Novel antimony catalyst compositions
TH36869A3 (th) สารผสมที่ใช้ยับยั้งการถ่ายโอนของสีย้อมและสารผสมซักฟอกชนิดอนุภาคที่มีสารนั้นอยู่
JPH10298017A (ja) カビ取り剤組成物

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E601 Decision to refuse application