KR930000545A - 올레핀 중합용 촉매, 그 촉매를 사용하는 올레핀 중합방법 및 그 촉매용으로 사용할 수 있는 천이금속화합물 - Google Patents

올레핀 중합용 촉매, 그 촉매를 사용하는 올레핀 중합방법 및 그 촉매용으로 사용할 수 있는 천이금속화합물 Download PDF

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KR930000545A
KR930000545A KR1019920010752A KR920010752A KR930000545A KR 930000545 A KR930000545 A KR 930000545A KR 1019920010752 A KR1019920010752 A KR 1019920010752A KR 920010752 A KR920010752 A KR 920010752A KR 930000545 A KR930000545 A KR 930000545A
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transition metal
halogen atom
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준이찌 이무따
준지 사이또
다까시 유에다
테루아끼 무까이야마
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다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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Priority claimed from JP15185392A external-priority patent/JP3164417B2/ja
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    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

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  • Polymers & Plastics (AREA)
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  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

올레핀 중합용 촉매, 그 촉매를 사용하는 올레핀 중합방법 및 그 촉매용으로 사용할 수 있는 천이금속화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1∼3 도는 본 발명에 의한 올레핀 중합용 촉매의 제조방법의 단계도.

Claims (10)

  1. [A] 주기율표 IVB족 천이금속원자와, -SO3R기(R은 알킬기, 할로겐원자로 치환된 아킬기, 아릴기 또는 할로겐원자 또는 알킬기로 치환된 아릴기임)를 함유하는 리간드와 시클로펜타디에닐 골격을 갖는 리간드를 갖는 천이금속화합물의 촉매성분과 [B] 유기알미늄옥시화합물로 구성된 것이 특징인 올레핀 중합용 촉매.
  2. [A] 주기율표 IVB족 천이금속원자와, -SO3R기(R은 알킬기, 할로겐원자로 치환된 아킬기, 아릴기 또는 할로겐원자 또는 알킬기로 치환된 아릴기임)를 함유하는 리간드와 시클로펜타디에닐 골격을 갖는 리간드를 갖는 천이금속화합물의 촉매성분과 [B] 유기알미늄옥시화합물, [C] 유기알미늄화합물로 구성된 것이 특징인 올레핀 중합용 촉매.
  3. 미립자담체와 [A] 주기율표 IVB족 천이금속원자와 -SO3R기(R은 알킬기, 할로겐원자로 치환된 알킬기, 아릴기 또는 할로겐원자 또는 알킬기로 치환된 아릴기임)을 함유하는 리간드와 시클로펜타디에닐 골격을 갖는 리간드를 갖는 천이금속화합물의 촉매성분과 [B] 유기알미늄옥시화합물로 구성되고 상기 천이금속화합물[A]와 상기 유기알미늄화합물[B]은 미립자담체에 담지되어 있는 것이 특징인 올레핀 중합용 촉매.
  4. 고체촉매성분과 유기알미늄화합물[C]로 구성하되 상기 고체촉매성분은 : 미립자담체와, [A] 주기율표 IVB족 천이금속원소와, -SO3R기(R은 알킬기, 할로겐원자로 치환된 알킬기, 아릴기 또는 할로겐원자 또는 알킬기로 치환된 아릴기임)를 함유하는 리간드와 시클로펜타디에닐 골격을 갖는 리간드를 갖는 천이금속화합물의 촉매성분과 [B] 유기알미늄옥시화합물로 구성되고, 상기 천이금속화합물[B]와 상기 유기알미늄화합물[B]은 미립자담체에 담지된 것이 특징인 올레핀 중합용 촉매.
  5. 미립자담체와, [A] 주기율표 IVB족 천이금속원자와, -SO3R기(R은 알킬기, 할로겐원자로 치환된 알킬기, 아릴기 또는 할로겐원자 또는 알킬기로 치환된 아릴기임)를 함유하는 리간드와 시클로펜타디에닐 골격을 갖는 리간드를 갖는 천이금속화합물의 촉매성분과 [B] 유기알미늄옥시화합물 미립자담체와, 예비중합에 의해 제조된 올레핀 중합체로 구성된 것이 특징인 올레핀 중합용 촉매.
  6. 미립자담체와, [A] 주기율표 IVB족 천이금속원자와, -SO3R기(R은 알킬기, 할로겐원자로 치환된 알킬기, 아릴기 또는 할로겐원자 또는 알킬기로 치환된 아릴기임)를 함유하는 리간드와 시클로펜타디에닐 골격을 갖는 리간드를 갖는 천이금속화합물의 촉매성분과 [B] 유기알미늄옥시화합물과, [C] 유기알미늄화합물과, 예비중합에 의해 제조된 올레핀 중합체로 구성된 것이 특징인 올레핀 중합용 촉매.
  7. 제 1∼6 항중 임의의 한 항에 있어서, 상기 천이금속화합물[A]는 하기식으로 표시되는 것이 특징인 올레핀 중합용 촉매.
    상기식에서 M은 주기율표 IVB족의 천이금속이며, Cp1과 Cp2는 각각 시클로펜타디에닐 골격을 갖는 기이며, 상기 기는 치환기를 가질 수도 있고, Cp1과 Cp2는 알킬렌기, 치환된 알키렌기, 실리렌기 또는 치환된 실리렌기를 통해 서로 결합될 수도 있으며 R은 알킬기, 할로겐원자로 치환된 알킬기, 알릴기, 또는 할로겐원자 또는 알킬기로 치환된 아릴기이며, X는 SO3R, 할로겐원자, R, OR, NRn, S(O)qR, SiR3또는 P(O)qR3이며, n은 1, 2 또는 3이며 q는 0, 1 또는 2이다.
  8. 제 1∼6 항중 임의의 한 항에서 청구한 올레핀 중합용 촉매의 존재하에서 올리핀을 중합 또는 공중합시키는 것이 특징인 올레핀 중합방법.
  9. 제 5 또는 6 항에서 청구한 올레핀 중합용 촉매와 유기 알미늄 화합물의 존재하에서 올레핀을 중합 또는 공중합시키는 것이 특징인 올레핀 중합방법.
  10. 하기식을 갖는 신규한 천이금속화합물.
    상기식에서 M은 주기율표 IVB족의 천이금속이며, Cp1과 Cp2는 각각 시클로펜타디에닐 골격을 갖는 기이며, 상기 기는 치환기를 가질 수도 있고, Cp1과 Cp2는 알키렌기, 치환된 알키렌기, 실리렌기 또는 치환된 실리렌기를 통해 서로 결합될 수도 있으며 R은 알킬기, 할로겐원자로 치환된 알킬기, 알릴기, 또는 할로겐 원자 또는 알킬기로 치환된 아릴기이며, X는 SO3R, 할로겐원자, R, OR, NRn, S(O)qR, SiR3또는 P(O)qR3이며, n은 1, 2 또는 3이며 q는 0, 1 또는 2이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920010752A 1991-06-20 1992-06-20 올레핀 중합용 촉매, 그 촉매를 사용하는 올레핀 중합방법 및 그촉매용으로 사용할 수 있는 천이금속화합물 KR940010531B1 (ko)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
JP91-148846 1991-06-20
JP14884691 1991-06-20
JP91-215606 1991-08-27
JP03215606A JP3142903B2 (ja) 1991-08-27 1991-08-27 オレフィン重合触媒およびオレフィンの重合方法
JP91-227977 1991-09-09
JP91-227976 1991-09-09
JP3227977A JPH0565309A (ja) 1991-09-09 1991-09-09 オレフイン重合用触媒およびオレフインの重合方法
JP3227976A JPH0565308A (ja) 1991-09-09 1991-09-09 オレフイン重合用触媒およびオレフインの重合方法
JP91-151853 1992-06-11
JP15185392A JP3164417B2 (ja) 1991-06-20 1992-06-11 新規な遷移金属化合物およびその用途

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KR930000545A true KR930000545A (ko) 1993-01-15
KR940010531B1 KR940010531B1 (ko) 1994-10-24

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CA2071706A1 (en) 1992-12-21
US5412128A (en) 1995-05-02
EP0519746A1 (en) 1992-12-23
US5409874A (en) 1995-04-25
US5424378A (en) 1995-06-13
KR940010531B1 (ko) 1994-10-24

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