KR920021619A - 열가소성 베리어수지로서의 하이드록시-작용성 폴리에스테르 - Google Patents

열가소성 베리어수지로서의 하이드록시-작용성 폴리에스테르 Download PDF

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Publication number
KR920021619A
KR920021619A KR1019920007967A KR920007967A KR920021619A KR 920021619 A KR920021619 A KR 920021619A KR 1019920007967 A KR1019920007967 A KR 1019920007967A KR 920007967 A KR920007967 A KR 920007967A KR 920021619 A KR920021619 A KR 920021619A
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KR
South Korea
Prior art keywords
polyester
phenylene
independently
dialkylene
diarylene
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KR1019920007967A
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English (en)
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KR100208921B1 (ko
Inventor
엔. 맹 마이클
이. 화이트 제리
Original Assignee
리챠드 지. 워터맨
더 다우 케미칼 캄파니
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Publication of KR920021619A publication Critical patent/KR920021619A/ko
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Publication of KR100208921B1 publication Critical patent/KR100208921B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
    • C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

열가소성 베리어수지로서의 하이드록시-작용성 폴리에스테르
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 일반식(I)의 반복 단위를 갖는, 일반적으로 고형인 열가소성 메틸올 폴리에스테르.
    상기식에서, R1및 R2는 각각 독립적으로 2가의 유기 잔기, 주로 2가의 탄화수소 잔기이고, R3는 각각 독립적으로 수소 또는 저급 알킬이며, y는 0 내지 0.5의 소수이고, x는 0.05 내지 0.4의 소수이다.
  2. 제1항에 있어서, R1및 R2가 각각 독립적으로 아릴렌, 알킬렌아릴렌, 디알킬렌아릴렌, 디아릴렌케톤, 디아릴렌설폰, 디아릴렌설폭사이드, 알킬렌카보닐아릴렌, 알킬렌설포닐아릴렌, 알킬리덴-디아릴렌, 디아릴렌 옥사이드, 알킬렌옥시아릴렌, 알킬렌티오아릴렌, 디아릴렌 설파이드 및 디아릴렌시아노메탄 중에서 선택된 2가의 방향족 잔기인 폴리에스테르.
  3. 제2항에 있어서, R1및 R2가 각각 독립적으로 m-페닐렌, p-페닐렌, 이소프로필리덴 디페닐렌, 비페닐렌, 비페닐렌옥사이드, 메틸렌디페닐렌, 비페닐렌 설파이드 나프틸렌, 비페닐렌시아노메탄, 3,3'-디알킬디페닐렌-이소프로필리덴 및 3,3',4,4'-테트라알킬디페닐렌-이스프로필리덴중에서 선택된 2가의 방향족 잔기 또는 이와 유사한 상기 방향족 잔기의 알킬-치환된 유도체인 폴리에스테르.
  4. 제3항에 있어서, R1및 R2가 각각 독립적으로 m-페닐렌, p-페닐렌 및 이소프로필리덴 디페닐렌인 폴리에스테르.
  5. 제1항에 있어서, R1및 R2가 각각 독립적으로 알킬렌, 디알킬렌케톤, 디알킬렌설폰, 디알킬렌설폭사이드, 디알킬렌옥사이드 및 디알킬렌설파이드 중에서 선택된 2가의 지방족 잔기인 폴리에스테르.
  6. 제5항에 있어서, R1및 R2가 각각 독립적으로 에틸렌, 프로필렌 및 부틸렌 중에서 선택된 2가의 지방족 잔기인 폴리에스테르.
  7. 제1항에 있어서, x가 0.1 내지 0.3의 수인 폴리에스테르.
  8. 제7항에 있어서, x가 0.l 내지 0.2의 수인 폴리에스테르.
  9. 제8항에 있어서, 하기 일반식(II)의 폴리에스테르.
    상기 식에서, Y 및 Y'는 각각 독립적으로 수소 또는 1가의 유기 말단 그룹이고, n은 10 내지 1,000의 정수이며, R1, R2, R3, x 및 y는 제1항에서 정의한 바와 같다.
  10. 제9항에서 R1이 m-페닐렌이고, R2가 이소프로필덴디페닐렌이며, x가 0.2이고, n이 200 내지 800의 수인 폴리에스테르.
  11. 제9항에 있어서, R1이 p-페닐렌이고, y가 0이며, x가 0.2이고 n이 200 내지 800의 수인 폴리에스테르.
  12. 제9항에 있어서, R1이 m-페닐렌 또는 p-페닐렌이고, R2가 이소프로필리덴 디페닐렌, 디페닐렌카보닐, m-페닐렌, p-페닐렌 및 비페닐렌이고, R3가 수소이며, y가 0.5이고, X가 0.125이며, n이 200 내지 800의 수인 폴리에스테르.
  13. 제1항에 있어서, 배리어용기(barrier container) 형태인 폴리에스테르.
  14. 제2항에 있어서, 배리어 필름 형태인 폴리에스테르.
  15. 제1항에 있어서, 배리어 피복재 형태인 폴리에스테르.
  16. 제1항에 있어서, 발포체 형태인 폴리에스테르.
    ※ 참고사항:최초출원 내용에 의하여 공개되는 것임.
KR1019920007967A 1991-05-13 1992-05-12 열가소성 차단 수지로서의 하이드록시 관능성 폴리에스테르 KR100208921B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/699,046 1991-05-13
US7/699,046 1991-05-13
US07/699,046 US5171820A (en) 1991-05-13 1991-05-13 Hydroxy-functional polyesters as thermoplastic barrier resins

Publications (2)

Publication Number Publication Date
KR920021619A true KR920021619A (ko) 1992-12-18
KR100208921B1 KR100208921B1 (ko) 1999-07-15

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Country Status (9)

Country Link
US (1) US5171820A (ko)
EP (1) EP0513679B1 (ko)
JP (1) JP3207921B2 (ko)
KR (1) KR100208921B1 (ko)
AU (1) AU643173B2 (ko)
CA (1) CA2068497C (ko)
DE (1) DE69231139T2 (ko)
ES (1) ES2147179T3 (ko)
TW (1) TW206974B (ko)

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Publication number Publication date
EP0513679A2 (en) 1992-11-19
AU643173B2 (en) 1993-11-04
DE69231139T2 (de) 2000-12-14
JP3207921B2 (ja) 2001-09-10
JPH05306332A (ja) 1993-11-19
EP0513679A3 (en) 1994-10-26
EP0513679B1 (en) 2000-06-07
CA2068497C (en) 2003-11-18
US5171820A (en) 1992-12-15
AU1618192A (en) 1992-11-19
KR100208921B1 (ko) 1999-07-15
TW206974B (ko) 1993-06-01
ES2147179T3 (es) 2000-09-01
DE69231139D1 (de) 2000-07-13
CA2068497A1 (en) 1992-11-14

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