KR920018101A - 산 촉매반응에 의해 가교될 수 있는 공중합체 - Google Patents

산 촉매반응에 의해 가교될 수 있는 공중합체 Download PDF

Info

Publication number
KR920018101A
KR920018101A KR1019920002710A KR920002710A KR920018101A KR 920018101 A KR920018101 A KR 920018101A KR 1019920002710 A KR1019920002710 A KR 1019920002710A KR 920002710 A KR920002710 A KR 920002710A KR 920018101 A KR920018101 A KR 920018101A
Authority
KR
South Korea
Prior art keywords
alkyl
hydrogen
copolymer
iii
phenyl
Prior art date
Application number
KR1019920002710A
Other languages
English (en)
Inventor
쉐델리 율리히
Original Assignee
베르너 발데크
시바-가이기 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 베르너 발데크, 시바-가이기 아게 filed Critical 베르너 발데크
Publication of KR920018101A publication Critical patent/KR920018101A/ko

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/038Macromolecular compounds which are rendered insoluble or differentially wettable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/22Oxygen
    • C08F212/24Phenols or alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36Amides or imides
    • C08F222/40Imides, e.g. cyclic imides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
    • G03F7/033Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials For Photolithography (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Manufacturing Of Printed Circuit Boards (AREA)

Abstract

내용 없음

Description

산 촉매반응에 의해 가교될 수 있는 공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 산 촉매반응에 의해 가교될 수 있고 또 a) 1 : 1 내지 1 : 9 비율이 하기 일반식(Ⅰ) 및 (Ⅱ)의 구조반복 단위체 100 내지 80몰% 및 b) 하기 일반식(Ⅲ)의 구조반복 단위체 0 내지 20몰%로 구성되며 겔 투과 크로마토그래피로써 측정된 분자량(Nw)이 103내지 106인 공중합체 :
    (상기식에서, X 및 X'는 서로 독립해서 -CH-CH2-, C(CH3)-CH2- 또는
    이고, R는 수소 또는 산의 작용에 의해 제거될 수 있는 보호기이며, 라디칼 R1은 서로 독립해서 C1-C5알킬, 페닐 또는 나프틸이거나 또는 서로 합쳐져서 1,2-페닐렌 또는 -〔C(R3)(R4)〕x-이며, R3및/또는 R4는 수소 또는 메틸이고, x는 2 내지 5이며, 라디칼 R2는 서로 독립해서 수소, C1-C5알킬 또는 C1-C5알콕시이고, R5및 R7는 각각 수소이며, R6는 수소, 할로겐 또는 메틸이고, R8은 수소, 할로겐, 메틸, -CH2할로겐, -CH2CN, -CN, -COOH, -CONH2, -O-C1-C5알킬, -O-CO-C1-C5알킬, -COO-C1-C5알킬, -COO-페닐 또는 페닐이거나, 또는 R5및 R6는 각각 수소이고, 또
    R7및 R8은 합쳐져서 -CO-O-CO-이거나 또는 서로 독립해서 -COOH 또는 -COO-C1-C5알킬임.
  2. 제1항에 있어서, 100 내지 90몰%의 일반식(Ⅰ) 및 (Ⅱ)의 구조반복 단위체 및 0 내지 10몰%의 일반식(Ⅲ)의 구조반복 단위체로 구성된 공중합체.
  3. 제1항에 있어서, X 및 X'이 -C(CH3)-CH2-이고, 또 특히 각각 -CH-CH2인 공중합체.
  4. 제1항에 있어서, 라디칼 R1이 합쳐져서, -〔C(R3)(R4)〕x-이고 또 라디칼 R2는 각각 수소, 메틸, 에틸, 메톡시 또는 에톡시인 공중합체.
  5. 제1항에 있어서, R이 하기 일반식(Ⅳ), (Ⅴ), (Ⅵ) 또는 (Ⅶ)의 라디칼인 공중합체.
    -COO-C(CH3)3(Ⅵ) 또는 -CO-R13(Ⅶ),
    상기식에서, R9는 수소 또는 메틸이고, R10은 C1-C5알킬, 페닐 또는 나프틸이며, R11및 R12는 서로 독립해서 수소, C1-C5알킬, 페닐 또는 나프틸이거나, 또는 R10및 R12는 합쳐져서 비치환되거나 또는 C1-C4알킬, C1-C4알콕시, 페닐, 나프틸, 페녹시 또는 나프톡시에 의해 치환된 에틸렌, 프로필렌 또는 부틸렌이고, y는 2,3 또는 4이고, 또 R13는 C1-C5알킬 또는 C1-C5알콕시임.
  6. 제5항에 있어서, R은 -COO-C(CH3)3이고, 또 특히 y가 2 또는 3인 일반식(Ⅴ)의 라디칼인 공중합체.
  7. 제1항에 있어서, X 및 X'가 -CH-CH2-이고, R 및 2개의 라디칼 R2가 각각 수소이며 또 라디칼 R1이 합쳐져서 -〔C(R3)(R4)〕x이고 x가 2 내지 4, 특히 2 또는 3인 공중합체.
  8. ⅰ) 한 개 이상의 제1항에 따른 공중합체 및 ⅱ) 화학선하에서 산을 형성하는 한 개 이상의 화합물을 포함하는 감광성 조성물.
  9. 제8항에 있어서, 성분 ⅲ)으로서 용매 또는 용매의 혼합물을 포함하는 조성물.
  10. 제8항에 있어서, 공중합체 ⅰ)이 100 내지 90몰%의 일반식(Ⅰ) 및 (Ⅱ)의 반복구조 단위체 및 0 내지 10몰%의 일반식(Ⅲ)의 반복구조 단위체로 구성된 조성물.
  11. 제8항에 있어서, 공중합체 ⅰ)에서 X 및 X'이 -C(CH3)-CH2이고, 또 특히 각각 -CH-CH2인 조성물.
  12. 제8항에 있어서, 공중합체 ⅰ)중의 R이 -COO-C(CH3)3이고, 또 특히 y가 2 또는 3인 일반식(Ⅴ)의 라디칼인 조성물.
  13. 제8항에 있어서, 공중합체 ⅰ)중의 X 및 X'이 -H-CH2이고, R 및 2개의 라디칼 R2가 각각 수소이며, 또 라디칼 R1이 합쳐져서 X-〔C(R3)(R4)〕|x-이고, x가 2 내지 4 특히 2 또는 3인 조성물.
  14. 제8항에 있어서, 성분 ⅱ)로서 한 개 이상의 하기 일반식(Ⅷ)의 화합물로 포함하는 조성물.
    (Ⅷ)
    상기식에서, Ar1은 각각 비치환되거나 또는 할로겐, C1-C4알킬, C1-C4알콕시, -OH 및/또는 니트로에 의해 치환된 페닐, 나프틸 또는 페닐 -COCH2-이고, Z1은 C1-C6알킬 또는 C3-C7시클로알킬이며, Z2는 테트라히드로티엔일, 테트라히드로푸릴 또는 헥사히드로피릴이고, q는 0, 1, 2 또는 3이고, r은 0, 1 또는 2이며, s는 0 또는 1이고, q+r+s의 합은 3이며,은 염화물, 부롬화물 또는 요오드화물 음이온, 또는 유기 술폰산 또는 카르복시산의 음이온임.
  15. 제14항에 있어서, Ar1이 페닐이고, q가 3이며, r 및 s가 0이며, 인 조성물.
  16. 제8항에 있어서, 화합물 ⅱ)가 공중합체 ⅰ)의 중량을 기준으로 하여 0.1 내지 20중량%, 특히 1 내지 10중량%의 양으로 존재하는 조성물.
  17. 보호 코팅 및 릴리이프 구고 제조용, 특히 인쇄판, 인쇄회로 및 집적회로를 제조하기 위한 제8항에 따른 감광성 조성물의 용도.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920002710A 1991-03-01 1992-02-22 산 촉매반응에 의해 가교될 수 있는 공중합체 KR920018101A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH624/91-8 1991-03-01
CH62491 1991-03-01

Publications (1)

Publication Number Publication Date
KR920018101A true KR920018101A (ko) 1992-10-21

Family

ID=4191344

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920002710A KR920018101A (ko) 1991-03-01 1992-02-22 산 촉매반응에 의해 가교될 수 있는 공중합체

Country Status (6)

Country Link
US (1) US5274060A (ko)
EP (1) EP0502819A1 (ko)
JP (1) JPH07179522A (ko)
KR (1) KR920018101A (ko)
BR (1) BR9200710A (ko)
CA (1) CA2062096A1 (ko)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807947A (en) * 1988-10-21 1998-09-15 Clariant Finance (Bvi) Limited Copolymers 4-hydroxystyrene and alkyl substituted-4-hydroxystyrene
US6166161A (en) * 1996-06-24 2000-12-26 The Dow Chemical Company Incorporation of functionalized comonomers in polyolefins
US7586013B2 (en) * 2004-03-26 2009-09-08 E.I. Du Pont De Nemours And Company Method for preparing hydroxystyrenes and acetylated derivatives thereof
CA2574581A1 (en) * 2004-07-23 2006-02-09 Polnox Corporation Anti-oxidant macromonomers and polymers and methods of making and using the same
US7902317B2 (en) 2004-12-03 2011-03-08 Polnox Corporation Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers
US7799948B2 (en) 2005-02-22 2010-09-21 Polnox Corporation Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis, performances and applications
WO2006104957A2 (en) 2005-03-25 2006-10-05 Polnox Corporation Alkylated and polymeric macromolecular antioxidants and methods of making and using the same
US8629782B2 (en) * 2006-05-10 2014-01-14 Schlumberger Technology Corporation System and method for using dual telemetry
US8004421B2 (en) * 2006-05-10 2011-08-23 Schlumberger Technology Corporation Wellbore telemetry and noise cancellation systems and method for the same
US7705176B2 (en) 2005-10-27 2010-04-27 Polnox Corporation Macromolecular antioxidants based on sterically hindered phenols and phosphites
US20070149660A1 (en) 2005-10-27 2007-06-28 Vijayendra Kumar Stabilized polyolefin compositions
WO2007064843A1 (en) 2005-12-02 2007-06-07 Polnox Corporation Lubricant oil compositions
US7402713B2 (en) * 2006-03-07 2008-07-22 E.I. Du Pont De Nemours And Company Processes for conversion of tyrosine to p-hydroxystyrene and p-acetoxystyrene
WO2008005358A2 (en) 2006-07-06 2008-01-10 Polnox Corporation Novel macromolecular antioxidants comprising differing antioxidant moieties: structures, methods of making and using the same
US7767853B2 (en) 2006-10-20 2010-08-03 Polnox Corporation Antioxidants and methods of making and using the same
US7468415B2 (en) * 2007-01-04 2008-12-23 E. I. Du Pont De Nemours And Company Method for preparing glycidyloxystyrene monomers and polymers thereof
EP3071544B1 (en) 2013-11-22 2022-07-06 Polnox Corporation Macromolecular antioxidants based on dual type moiety per molecule: structures methods of making and using the same
US20180251695A1 (en) 2017-03-01 2018-09-06 Polnox Corporation Macromolecular Corrosion (McIn) Inhibitors: Structures, Methods Of Making And Using The Same
TW202120462A (zh) 2019-08-09 2021-06-01 日商三菱瓦斯化學股份有限公司 化合物、聚合物、組成物、膜形成用組成物、圖型形成方法、絕緣膜之形成方法及化合物之製造方法,以及含有碘之乙烯基聚合物及其乙醯化衍生物之製造方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3063975A (en) * 1960-03-25 1962-11-13 Monsanto Chemicals Copolymers of vinylbenzyl alcohol and vinylbenzyl alkyl ethers
US3779778A (en) * 1972-02-09 1973-12-18 Minnesota Mining & Mfg Photosolubilizable compositions and elements
GB1539192A (en) * 1975-01-27 1979-01-31 Ici Ltd Photopolymerisable compositions
US4205151A (en) * 1975-04-04 1980-05-27 Dynapol Polymeric N-substituted maleimide antioxidants
DE2718254C3 (de) * 1977-04-25 1980-04-10 Hoechst Ag, 6000 Frankfurt Strahlungsempfindliche Kopiermasse
US4225689A (en) * 1978-07-26 1980-09-30 Eastman Kodak Company Aldehyde-containing vinylaryl ethers
US4439517A (en) * 1982-01-21 1984-03-27 Ciba-Geigy Corporation Process for the formation of images with epoxide resin
GB8413395D0 (en) * 1984-05-25 1984-07-04 Ciba Geigy Ag Production of images
US4737426A (en) * 1985-05-15 1988-04-12 Ciba-Geigy Corporation Cyclic acetals or ketals of beta-keto esters or amides
US4800224A (en) * 1986-05-16 1989-01-24 Ciba-Geigy Corporation Optically active styrene derivatives, polymers obtained from these, complexes with iridium(I) and their use
US4800152A (en) * 1987-03-16 1989-01-24 International Business Machines Corporation Negative resist compositions
DE3821585A1 (de) * 1987-09-13 1989-03-23 Hoechst Ag Positiv arbeitendes strahlungsempfindliches gemisch und daraus hergestelltes strahlungsempfindliches aufzeichnungsmaterial fuer hochenergetische strahlung

Also Published As

Publication number Publication date
EP0502819A1 (de) 1992-09-09
JPH07179522A (ja) 1995-07-18
CA2062096A1 (en) 1992-09-02
BR9200710A (pt) 1992-11-10
US5274060A (en) 1993-12-28

Similar Documents

Publication Publication Date Title
KR920018101A (ko) 산 촉매반응에 의해 가교될 수 있는 공중합체
KR940014470A (ko) 포지티브 포토레지스트로서 유용한 중합체 및 이를 포함하는 조성물
KR930021588A (ko) 폴리스티렌 기제 광내식막 물질
DE59606352D1 (de) Reinigungsmittel für harte oberflächen
KR920004450A (ko) 광중합성 조성물 및 이 조성물을 사용하여 제조한 광중합성 기록물질
CA2112000A1 (fr) Compositions polymeres a faible indice de jaune, compositions polymerisables et lentilles les mettant en oeuvre
JPS5577741A (en) Novel photoresist composition
DK158351C (da) Analogifremgangsmaade til fremstilling af substituerede 4-fenylalkylimidazolderivater eller farmaceutisk acceptable syreadditionssalte deraf
EP0718316A3 (en) Crosslinked polymers
AU585898B2 (en) Photosensitive composition
KR970071142A (ko) 반사 방지 코팅용 조성물
EP0491659A3 (en) Novel piperidine compounds containing silane groups for use as stabilizers for organic materials
KR890010615A (ko) 광중합성 혼합물 및 이로부터 제조된 기록물질
KR880004031A (ko) 저장 안정성이 양호한 수지 조성물
JPS57106638A (en) Conjugated polyprenylcarboxylic acid and its derivative
KR920013028A (ko) 광증감제 조성물
JPS5575405A (en) Photopolymerizable composition
JPS54130926A (en) Photographic element
JPS5586848A (en) Coating composition having excellent functional characteristic
JPS5440888A (en) Photosensitive resin composition having good storage stability
IE44184L (en) Imidazole derivatives
JPS5767664A (en) Film forming assistant composition for vinyl polymeric aqueous emulsion
KR840006334A (ko) 설파모일 벤조페논 유도체의 제조방법
JPS54120696A (en) Glucosamine derivative and its preparation
KR930002298A (ko) 올리핀성 불포화 치환기를 함유하는 벤조산염

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid