KR920016390A - 산화 시클로헥센, 시클로헥산올 및 시클로헥사논의 순환식 제조방법 - Google Patents

산화 시클로헥센, 시클로헥산올 및 시클로헥사논의 순환식 제조방법 Download PDF

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KR920016390A
KR920016390A KR1019920001726A KR920001726A KR920016390A KR 920016390 A KR920016390 A KR 920016390A KR 1019920001726 A KR1019920001726 A KR 1019920001726A KR 920001726 A KR920001726 A KR 920001726A KR 920016390 A KR920016390 A KR 920016390A
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KR
South Korea
Prior art keywords
mixture
cyclohexanone
cyclohexene
cyclohexane
essentially
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KR1019920001726A
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KR100201986B1 (ko
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에이저 데이비드
베베어 파울-미하엘
하. 슈슈테어 한즈
노이바우어 게랄트
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라이싱어, 바르츠
바스프 악티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

산화 시클로헥센, 시클로헥산올 및 시클로 헥사논의 순환식 제조방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. (a) 130 내지 200°C 및 5 내지 125bar 에서 액체상으로 산소분자 또는 산소분자 함유 기체를 사용하여 시클로 핵산을 산화시킴에 의한, 본질적으로 히드로과산화 시클로헥실, 시클로 헥산올, 시클로헥사논 및 시클로헥산으로 이루어진 혼합물의 제조단계, (b)(b1) 본질적으로 산화 시클로헥산과 시클로헥센으로 이루어지고 수호화후 단계(a)로 재순환되는 분획(b2)본질적으로 산화시클로 헥센으로 이루어지는 분획,(b3) 본질적으로 시클로헥사올과 시클로헥사논으로 이루어진 혼합물 및(b4) 본질적으로 히드로과산화 시클로헥실, 시클로헥산을, 시클로 헥사논 및 촉매로 이루어진 혼합물을 얻기 위한, 단계(c)로 부터 생성되고 산화 시클로헥센을 함유하는 에폭시화 혼합물과 단계(a)로 부터 혼합물의 공동 증류 분리단계, 및(c) 본질적으로 산화 시클로 헥센, 시클로헥산올, 시틀로헥사논, 시클로헥센, 시클로헥산 및 촉매로 이루어지고 단계(a)로 부터의 혼합물과 함께 단계 (b)에서 증류에 의해 분리되는 에폭시화 혼합물을 얻기위해, 주기율표의 제4내지 6족으로부터의 전이금속 화합물의 존재하에 상승된 온도에서, 분획(b4)으로서 얻어지고 히드로과산화 시클로 헥실을 함유하는 혼합물을 시클로-헥산과의 혼합물중의 시클로헥센과 반응시키는 단계를 포함하는, 산화시클로헥센, 시클로헥산을 및 시클로헥사논의 순화식 제조방법.
  2. 제1항에 있어서, 시클로헥산에 용해될 수 있는 몰리브덴 화합물이 사용됨을 특징으로 하는 방법.
  3. 제1항에 있어서,히드로과산화 시클로헥실을 함유하는 혼합물의 분리가 120분의 최대 진류시간으로 수행됨을 특징으로 하는 방법.
  4. 제1항에 잇어서, 0.7 내지 1의 시클로헥센과 히드로과산화 시클로 헥실 사이의 몰비가 유지됨을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920001726A 1991-02-14 1992-02-07 시클로헥센옥사이드 시클로헥산올 및 시클로헥사논의 순환식 제조방법 KR100201986B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4104419A DE4104419A1 (de) 1991-02-14 1991-02-14 Kreislaufverfahren zur herstellung von cyclohexenoxid sowie cyclohexanol und cyclohexanon
DEP4104419.3 1991-02-14

Publications (2)

Publication Number Publication Date
KR920016390A true KR920016390A (ko) 1992-09-24
KR100201986B1 KR100201986B1 (ko) 1999-06-15

Family

ID=6424993

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Application Number Title Priority Date Filing Date
KR1019920001726A KR100201986B1 (ko) 1991-02-14 1992-02-07 시클로헥센옥사이드 시클로헥산올 및 시클로헥사논의 순환식 제조방법

Country Status (6)

Country Link
US (1) US5175316A (ko)
EP (1) EP0499054B1 (ko)
JP (1) JP3137706B2 (ko)
KR (1) KR100201986B1 (ko)
DE (2) DE4104419A1 (ko)
ES (1) ES2084196T3 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1011041A3 (nl) * 1997-03-12 1999-04-06 Dsm Nv Werkwijze voor het ontleden van cycloalkylhydroperoxide.
KR100508428B1 (ko) * 1999-02-23 2005-08-17 건국대학교 산학협력단 피흡연자용 휴대형 공기정화장치
US6448454B1 (en) * 2000-04-07 2002-09-10 The University Of Kansas Catalytic oxidation of organic substrates by transition metal complexes in organic solvent media expanded by supercritical or subcritical carbon dioxide
JP4601805B2 (ja) 2000-11-24 2010-12-22 ダイセル化学工業株式会社 シクロヘキサンの酸化方法
DE10247496A1 (de) * 2002-10-11 2004-04-22 Degussa Ag Verwendung eines Absatzbeschleunigers bei der Epoxidierung
CN100436435C (zh) * 2005-07-15 2008-11-26 岳阳昌德化工实业有限公司 一种用环己烷制备1，2-环氧环己烷的方法
CN104803951A (zh) * 2015-05-15 2015-07-29 南京工业大学 一种采用微流场反应技术制备高品质环氧环己烷的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA978986A (en) * 1971-03-16 1975-12-02 Atlantic Richfield Company Method for the production of epoxides
FR2216277B1 (ko) * 1973-02-02 1976-05-14 Rhone Poulenc Ind
NL8201695A (nl) * 1982-04-23 1983-11-16 Stamicarbon Werkwijze voor de bereiding van cyclohexanol en cyclohexanon.
DE3328771A1 (de) * 1983-08-10 1985-02-28 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von sauerstoff enthaltenden verbindungen
DE3636056A1 (de) * 1986-10-23 1988-04-28 Basf Ag Verfahren zur aufarbeitung von cyclohexylhydroperoxid enthaltenden reaktionsgemischen
JP2562150B2 (ja) * 1986-10-23 1996-12-11 バスフ アクチェンゲゼルシャフト シクロヘキシルヒドロペルオキシドを含有する反応混合物の後処理法

Also Published As

Publication number Publication date
EP0499054A1 (de) 1992-08-19
DE4104419A1 (de) 1992-08-20
EP0499054B1 (de) 1996-03-27
ES2084196T3 (es) 1996-05-01
JP3137706B2 (ja) 2001-02-26
US5175316A (en) 1992-12-29
KR100201986B1 (ko) 1999-06-15
DE59205802D1 (de) 1996-05-02
JPH0592931A (ja) 1993-04-16

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