KR920011576A - 활성화된 촉매의 제조방법 - Google Patents

활성화된 촉매의 제조방법 Download PDF

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Publication number
KR920011576A
KR920011576A KR1019910022515A KR910022515A KR920011576A KR 920011576 A KR920011576 A KR 920011576A KR 1019910022515 A KR1019910022515 A KR 1019910022515A KR 910022515 A KR910022515 A KR 910022515A KR 920011576 A KR920011576 A KR 920011576A
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South Korea
Prior art keywords
catalyst
compound
vanadium
antimony
atoms
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KR1019910022515A
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English (en)
Inventor
스태포드 린치 챠알스
클레어 글래서 린다
프랭크 브라즈딜 제임스
앤쏘니 토프트 마아크
Original Assignee
래리 윌리암 에반스
더 스탠다드 오일 컴패니
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Application filed by 래리 윌리암 에반스, 더 스탠다드 오일 컴패니 filed Critical 래리 윌리암 에반스
Publication of KR920011576A publication Critical patent/KR920011576A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

활성화된 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 750℃이상의 온도에서 산화물 형태의 바나듐 및 안티몬-함유 조성물을 하소시킨 후, 하소된 촉매를 (1)시클로헥산올, (2) 시클로펜탄올, (3) C1-C8의 모노히드록시 비고리형 탄화수소 및 (4) C2-C4의 디히드록시 비고리형 탄화수소로부터 선택된 액체 형태의 히드록시 화합물과 접촉시키고, 이 화합물이 상기 촉매를 적시는 양 이상으로 존재하는 한, 상기 촉매로부터 상기 화합물을 액체로서 분리시킨 후, 상기 촉매를 건조시키는 것으로 이루어지는, 0.8-4의 SB : V의 원자비를 갖는 산화물 형태의 활성화된 안티몬 및 바나듐- 함유 촉매의 제조방법.
  2. 제1항에 있어서, 상기 하소 온도가 780℃ 이상임을 특징으로 하는 방법.
  3. 제1항에 있어서, 상기 촉매가 V 원자 1개당 Ti,Sn, Fe, Cr 및 Ga 중 하나 이상의 원자를 0.01 내지 2개 함유하고, V원자 1개당 Li, Mg, Ca, Ba, Co, Ni, Zz, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B 및 Mn 중 하나 이상의 원자를 2개까지 함유하는 것을 특징으로 하는 방법.
  4. 제3항에 있어서, 하소 온도가 780℃ 이상임을 특징으로 하는 방법.
  5. 제1항에 있어서, 상기 히드록시 화합물이 제1항의 화합물 (3)내지 (4)로부터 선택됨을 특징으로 하는 방법.
  6. 제1항에 있어서, 상기 히드록시 화합물이 이소부탄올임을 특징으로 하는 방법.
    ※ 참고사항：최초출원 내용에 의하여 공개하는 것임.
KR1019910022515A 1990-12-21 1991-12-10 활성화된 촉매의 제조방법 KR920011576A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US7/631,837 1990-12-21
US07/631,837 US5094989A (en) 1990-12-21 1990-12-21 Process for activation of catalysts

Publications (1)

Publication Number Publication Date
KR920011576A true KR920011576A (ko) 1992-07-24

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KR1019910022515A KR920011576A (ko) 1990-12-21 1991-12-10 활성화된 촉매의 제조방법

Country Status (13)

Country Link
US (1) US5094989A (ko)
EP (1) EP0492805B1 (ko)
JP (1) JP2559938B2 (ko)
KR (1) KR920011576A (ko)
CN (1) CN1030435C (ko)
AT (1) ATE106277T1 (ko)
BR (1) BR9105578A (ko)
CA (1) CA2056923A1 (ko)
DE (1) DE69102258T2 (ko)
ES (1) ES2054446T3 (ko)
MX (1) MX9102713A (ko)
MY (1) MY106880A (ko)
TW (1) TW206926B (ko)

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FR2687670B1 (fr) * 1992-02-20 1995-05-19 Rhone Poulenc Chimie Procede d'ammoxydation d'hydrocarbures satures.
KR100331289B1 (ko) * 1993-08-26 2002-11-23 비피아메리카인코포레이티드 산화및암모산화촉매의개선방법
TR28292A (tr) * 1993-09-02 1996-04-17 Standard Oil Co Ohio Olefinlerin ammoksidasyonu icin yöntem.
US5432141A (en) * 1994-03-15 1995-07-11 The Standard Oil Company Preparation of attrition resistant vanadium-antimony oxide catalysts
US5498588A (en) * 1994-09-09 1996-03-12 The Standard Oil Company Surface modification and promotion of vanadium antimony oxide catalysts
TR28227A (tr) * 1994-10-07 1996-02-16 Bp America Katalizör faaliyetinin gelistirilmesi yöntemi, gelistirilmis katalizörler ve bunlarin kullanimi.
FR2729651A1 (fr) * 1995-01-24 1996-07-26 Rhone Poulenc Chimie Catalyseurs d'ammoxydation et leur procede de preparation
US5576469A (en) * 1995-06-05 1996-11-19 The Standard Oil Co. Paraffin ammoxidation using vanadium antimony oxide based catalysts with halide promoters
US5693587A (en) * 1995-06-06 1997-12-02 The Standard Oil Company Method for preparing vanadium antimony oxide based oxidation and ammoxidation catalysts
CN1085110C (zh) * 1995-11-14 2002-05-22 标准石油公司 表面改性的钒锑氧化物催化剂的制备方法
WO1998022421A1 (fr) * 1996-11-15 1998-05-28 Mitsubishi Chemical Corporation Procede d'elaboration simultanee d'acrylonitrile et d'acide acrylique
US5854172A (en) * 1997-01-17 1998-12-29 The Standard Oil Company Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O
MY119391A (en) * 1997-07-24 2005-05-31 Standard Oil Co Method for preparing improved vanadium antimony oxide based oxidation and ammoxidation catalysts
US6514902B1 (en) 1998-08-28 2003-02-04 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing an oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
CN1148257C (zh) * 1999-10-26 2004-05-05 标准石油公司 用于烷烃氨氧化反应的催化剂
JP4647858B2 (ja) * 2001-09-06 2011-03-09 旭化成ケミカルズ株式会社 酸化またはアンモ酸化用酸化物触媒及びその製造方法
US6710011B2 (en) 2001-12-21 2004-03-23 Saudi Basic Industries Corporatioin Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US20040102318A1 (en) * 2002-11-27 2004-05-27 Brazdil James F. Method for enhancing the productivity of vanadium antimony oxide catalysts
US6864384B2 (en) * 2002-11-27 2005-03-08 The Standard Oil Company Preparation of vanadium antimony oxide based catalysts using nano-scale iron
US6887825B2 (en) * 2002-11-27 2005-05-03 The Standard Oil Company Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media
KR100671978B1 (ko) * 2005-07-19 2007-01-24 한국과학기술연구원 탈질환원촉매
CN106833801B (zh) * 2017-02-23 2020-07-28 广州市芬芳环保科技有限公司 Fe-Ti-Tb三元复合型节煤固硫除焦添加剂及其制备方法和应用

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CA795810A (en) * 1967-04-18 1968-10-01 L. Barclay John Production of unsaturated aliphatic nitriles
EP0148544A1 (en) * 1984-01-10 1985-07-17 Exxon Research And Engineering Company Process for preparing inorganic metal oxygen composition capable of dehydrocoupling toluene
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Also Published As

Publication number Publication date
BR9105578A (pt) 1992-09-01
MX9102713A (es) 1994-04-29
CA2056923A1 (en) 1992-06-22
EP0492805B1 (en) 1994-06-01
CN1063240A (zh) 1992-08-05
JPH05293374A (ja) 1993-11-09
ES2054446T3 (es) 1994-08-01
MY106880A (en) 1995-08-30
JP2559938B2 (ja) 1996-12-04
DE69102258T2 (de) 1994-09-15
CN1030435C (zh) 1995-12-06
ATE106277T1 (de) 1994-06-15
EP0492805A1 (en) 1992-07-01
US5094989A (en) 1992-03-10
DE69102258D1 (de) 1994-07-07
TW206926B (ko) 1993-06-01

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