KR920006261A - 올레핀 올리고머의 제조방법 - Google Patents

올레핀 올리고머의 제조방법 Download PDF

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Publication number
KR920006261A
KR920006261A KR1019910016485A KR910016485A KR920006261A KR 920006261 A KR920006261 A KR 920006261A KR 1019910016485 A KR1019910016485 A KR 1019910016485A KR 910016485 A KR910016485 A KR 910016485A KR 920006261 A KR920006261 A KR 920006261A
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South Korea
Prior art keywords
producing
olefin oligomer
anhydride
oligomer according
alcohol
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KR1019910016485A
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English (en)
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KR0146376B1 (ko
Inventor
마고토 아가쓰
사토루 미야지
다쓰야 가와무라
Original Assignee
홍고오 무쓰비
이데미쓰 세끼유 가가꾸 가부시끼가이샤
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Publication of KR920006261A publication Critical patent/KR920006261A/ko
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Publication of KR0146376B1 publication Critical patent/KR0146376B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1213—Boron fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

올레핀 올리고머의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 촉매로서 3플르오르화 붕소의 존재하 및 긍촉매로서 물 및/또는 알코올과 무수카르복시 산의 공존하에서 올레핀을 중합하는 것을 특징으로 하는 올레핀 올리그머의 제조방법.
  2. 제1항에 있어서, 올레핀이 탄소수 6-18의 α-올레핀인 올레핀 올리그머의 제조방법.
  3. 제1항에 있어서, 알코올이 1차알코올 및/또는 2차알코올인 올레핀 올리그머의 제조방법.
  4. 제3항에 있어서, 1차 알코올이 탄소수 1-10의 1차 알코일인 올레핀 올리그머의 제조방법.
  5. 제3항에 있어서, 2차 알코올이 탄소수 3-10의 2차 알코올인 올레핀 올리그머의 제조방법.
  6. 제1항에 있어서, 무수 카르복시산이 지방족 무수 카르복시산 및/또는 지방족 무수 카르복시산인 올레핀 올리그머의 제조방법.
  7. 제6항에 있어서, 지방족 무수 카르복시산이 무수 아세트산, 무수 프로피온산, 무수 부티르산, 무수 발레르산 및 무수 숙신산중 1종이상인 올레핀 올리그머의 제조방법.
  8. 제6항에 있어서, 지방족 무수 카르복시산이 무수 벤존산 및 무수 프탈산중 1종이상인 올레핀 올리그머의 제조방법.
  9. 제1항에 있어서, 촉매 및 공촉매를 (3프루오르화붕소)/(물및/또는 알코올과 무수 카르복시산)의 몰비 1.01-5.0으로 사용하는 것인 올레핀 올리그머의 제조방법.
  10. 제1항에 있어서, 공촉매를 무수 카르복시산/(물및/또는 알코올)의 몰비 0.1-2.0으로 사용하는 것인 올레핀 올리그머의 제조방법.
  11. 제1항에 있어서, 물, 알코올 및 무수 카르복시산이 3플루오르화 붕소의 착물로서 전부 또는 부분적으로 존재하는 것인 올레핀 올리그머의 제조방법.
  12. 제1항에 있어서, 반응이 용매중에서 행해지는 것인 올레핀 올리그머의 제조방법.
  13. 제12항에 있어서, 용매가 수소화 탄화수소, 선형포화 탄화수소 및 지방족 고리 탄화수소중 1종이상인 올레핀 올리그머의 제조방법.
  14. 제1항에 있어서, 반응이 -10℃∼80℃ 및 0-35kg/㎤G 하에서 행해지는 것인 올레핀 올리그머의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910016485A 1990-09-20 1991-09-20 올레핀 올리고머의 제조방법 KR0146376B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2251446A JPH0764757B2 (ja) 1990-09-20 1990-09-20 オレフィンオリゴマーの製造方法
JP251446/1990 1990-09-20
JP90-251446 1990-09-20

Publications (2)

Publication Number Publication Date
KR920006261A true KR920006261A (ko) 1992-04-27
KR0146376B1 KR0146376B1 (ko) 1998-08-17

Family

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Family Applications (1)

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KR1019910016485A KR0146376B1 (ko) 1990-09-20 1991-09-20 올레핀 올리고머의 제조방법

Country Status (7)

Country Link
US (1) US5191140A (ko)
EP (1) EP0477673B1 (ko)
JP (1) JPH0764757B2 (ko)
KR (1) KR0146376B1 (ko)
BR (1) BR9104025A (ko)
DE (1) DE69119011T2 (ko)
TW (1) TW228005B (ko)

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US5633420A (en) * 1995-09-22 1997-05-27 Amoco Corporation Olefin oligomerization process
US5744676A (en) * 1996-02-26 1998-04-28 Theriot; Kevin J. Olefin oligomerization process
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US5922636A (en) 1997-11-19 1999-07-13 Sarin; Rakesh Catalyst for oligomerization of alpha-olefins
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US6734329B1 (en) * 2000-10-02 2004-05-11 Chevron U.S.A. Inc. Oligomerization of alpha olefins in the presence of carboxylic acids
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CN110627603A (zh) * 2018-06-21 2019-12-31 中国石化工程建设有限公司 连续法生产聚α-烯烃的装置及方法
US10961167B2 (en) 2018-09-20 2021-03-30 Novvi Llc Process for preparing hydrocarbon mixture exhibiting unique branching structure
CN111321002A (zh) 2018-12-14 2020-06-23 中国石油天然气股份有限公司 一种低粘度聚α-烯烃润滑油及其合成方法
CN115212922A (zh) * 2021-04-15 2022-10-21 中国石油天然气股份有限公司 一种α-烯烃聚合的催化剂组合物及其制备与应用

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Also Published As

Publication number Publication date
DE69119011T2 (de) 1996-09-12
JPH04128242A (ja) 1992-04-28
EP0477673B1 (en) 1996-04-24
US5191140A (en) 1993-03-02
JPH0764757B2 (ja) 1995-07-12
EP0477673A1 (en) 1992-04-01
KR0146376B1 (ko) 1998-08-17
DE69119011D1 (de) 1996-05-30
BR9104025A (pt) 1992-06-02
TW228005B (ko) 1994-08-11

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