GB1497524A - Method of oligomerizing 1-olefins - Google Patents

Method of oligomerizing 1-olefins

Info

Publication number
GB1497524A
GB1497524A GB3850676A GB3850676A GB1497524A GB 1497524 A GB1497524 A GB 1497524A GB 3850676 A GB3850676 A GB 3850676A GB 3850676 A GB3850676 A GB 3850676A GB 1497524 A GB1497524 A GB 1497524A
Authority
GB
United Kingdom
Prior art keywords
olefins
reactor
reactors
tank
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3850676A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Research and Development Co
Original Assignee
Gulf Research and Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/633,677 external-priority patent/US4045508A/en
Priority claimed from US05/633,671 external-priority patent/US4045507A/en
Application filed by Gulf Research and Development Co filed Critical Gulf Research and Development Co
Publication of GB1497524A publication Critical patent/GB1497524A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1213—Boron fluoride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1497524 Multistage oligomerization of C 5 -C 14 olefins GULF RESEARCH & DEVELOPMENT CO 17 Sept 1976 [20 Nov 1975 (2)] 38506/76 Heading C5E C 5 -C 14 olefins are oligomerized to give a product including trimer and tetramer with a homogeneous catalyst comprising BF 3 and a cocatalyst that complexes with BF 3 in at least two reactors in series. The co-catalyst may be a C 1 -C 10 aliphatic alcohol. Preferably the first reactor is a "tank" reactor and the subsequent reactor(s) may be "tank" or "tube" reactors. The oligomer product may be hydrogenated using Pd, Pt or Ni catalysts either before or after dimer removal. The feed is preferably 1-octene, 1-decene, 1-dodecene or a mixture thereof.
GB3850676A 1975-11-20 1976-09-17 Method of oligomerizing 1-olefins Expired GB1497524A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/633,677 US4045508A (en) 1975-11-20 1975-11-20 Method of making alpha-olefin oligomers
US05/633,671 US4045507A (en) 1975-11-20 1975-11-20 Method of oligomerizing 1-olefins

Publications (1)

Publication Number Publication Date
GB1497524A true GB1497524A (en) 1978-01-12

Family

ID=27091954

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3850676A Expired GB1497524A (en) 1975-11-20 1976-09-17 Method of oligomerizing 1-olefins

Country Status (5)

Country Link
JP (1) JPS5265204A (en)
DE (1) DE2651637C2 (en)
FR (1) FR2332289A1 (en)
GB (1) GB1497524A (en)
NL (1) NL187007C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300006A (en) 1980-03-21 1981-11-10 Philips Petroleum Company Synthetic lube oil production
US4319064A (en) 1980-03-21 1982-03-09 Phillips Petroleum Company Olefin dimerization
US4386229A (en) 1980-03-21 1983-05-31 Phillips Petroleum Company Olefin dimerization
EP0081851A2 (en) * 1981-12-16 1983-06-22 Phillips Petroleum Company Viscosity index improver soluble in synthetic poly(alpha-olefin) lubricants
GB2156377A (en) * 1984-03-26 1985-10-09 Chevron Res Co-oligomerization of olefins
EP0352723A1 (en) * 1988-07-29 1990-01-31 Ethyl Corporation Process for making an alpha-olefin oligomer product

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0764757B2 (en) * 1990-09-20 1995-07-12 出光石油化学株式会社 Method for producing olefin oligomer
JP4891469B2 (en) * 1998-07-01 2012-03-07 出光興産株式会社 Traction drive fluid
US6147271A (en) * 1998-11-30 2000-11-14 Bp Amoco Corporation Oligomerization process
US6824671B2 (en) * 2001-05-17 2004-11-30 Exxonmobil Chemical Patents Inc. Low noack volatility poly α-olefins
US6869917B2 (en) * 2002-08-16 2005-03-22 Exxonmobil Chemical Patents Inc. Functional fluid lubricant using low Noack volatility base stock fluids
JP5185489B2 (en) * 2004-04-20 2013-04-17 出光興産株式会社 Base oil for lubricating oil comprising decene oligomer hydride, lubricating oil composition, and method for producing decene oligomer hydride
US7544850B2 (en) * 2006-03-24 2009-06-09 Exxonmobil Chemical Patents Inc. Low viscosity PAO based on 1-tetradecene
JP2008214643A (en) * 2008-05-07 2008-09-18 Idemitsu Kosan Co Ltd Method for producing traction drive fluid base oil
JP5400865B2 (en) * 2011-12-19 2014-01-29 出光興産株式会社 Base oil for lubricating oil comprising decene oligomer hydride, lubricating oil composition, and method for producing decene oligomer hydride

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3382291A (en) * 1965-04-23 1968-05-07 Mobil Oil Corp Polymerization of olefins with bf3

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300006A (en) 1980-03-21 1981-11-10 Philips Petroleum Company Synthetic lube oil production
US4319064A (en) 1980-03-21 1982-03-09 Phillips Petroleum Company Olefin dimerization
US4386229A (en) 1980-03-21 1983-05-31 Phillips Petroleum Company Olefin dimerization
EP0081851A2 (en) * 1981-12-16 1983-06-22 Phillips Petroleum Company Viscosity index improver soluble in synthetic poly(alpha-olefin) lubricants
EP0081851A3 (en) * 1981-12-16 1983-07-20 Phillips Petroleum Company Viscosity index improver soluble in synthetic poly(alpha-olefin) lubricants
US4418234A (en) 1981-12-16 1983-11-29 Phillips Petroleum Company Viscosity index improver soluble in synthetic poly(α-olefin) lubricants
GB2156377A (en) * 1984-03-26 1985-10-09 Chevron Res Co-oligomerization of olefins
EP0352723A1 (en) * 1988-07-29 1990-01-31 Ethyl Corporation Process for making an alpha-olefin oligomer product

Also Published As

Publication number Publication date
NL187007B (en) 1990-12-03
NL187007C (en) 1991-05-01
JPS61326B2 (en) 1986-01-08
JPS5265204A (en) 1977-05-30
FR2332289A1 (en) 1977-06-17
DE2651637C2 (en) 1984-12-20
NL7612195A (en) 1977-05-24
FR2332289B1 (en) 1980-04-25
DE2651637A1 (en) 1977-06-02

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19960916