GB1269067A - Process for the polymerization and copolymerization of olefins - Google Patents

Process for the polymerization and copolymerization of olefins

Info

Publication number
GB1269067A
GB1269067A GB3863569A GB3863569A GB1269067A GB 1269067 A GB1269067 A GB 1269067A GB 3863569 A GB3863569 A GB 3863569A GB 3863569 A GB3863569 A GB 3863569A GB 1269067 A GB1269067 A GB 1269067A
Authority
GB
United Kingdom
Prior art keywords
polymerization
olefin
aug
molecular weight
copolymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3863569A
Inventor
Jacques Stevens
Robert Van Weynbergh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of GB1269067A publication Critical patent/GB1269067A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

1,269,067. Product control in supported catalytic olefin polymerization. SOLVAY & CIE. 1 Aug., 1969 [26 Aug., 1968], No. 38635/69. Heading C3P. Olefin polymers with a broad molecular weight distribution (C D ) and a low melt index (M.I.) are obtained by polymerization in the presence of an organometallic compound-transition metal compound catalyst on an inert support, in which process C D is controlled by varying the hydrogen concentration from 20 to 50 gms. per kg. of olefin and the desired low M.I. is obtained by carrying out the polymerization at 40‹ to 65‹ C. and/or by using an agent for increasing molecular weight, e.g. an alcohol, ether or acid. In examples and comparative examples, ethylene is homo- or co-polymerized with butene-1 in the presence of (C 2 H 5 ) 3 Al or (i-C 4 H 9 ) 3 Al/TiCl 4 -MgO or hydromagnesite/H 2 , and optionally octanol.
GB3863569A 1968-08-26 1969-08-01 Process for the polymerization and copolymerization of olefins Expired GB1269067A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR164128 1968-08-26

Publications (1)

Publication Number Publication Date
GB1269067A true GB1269067A (en) 1972-03-29

Family

ID=8654008

Family Applications (2)

Application Number Title Priority Date Filing Date
GB3863569A Expired GB1269067A (en) 1968-08-26 1969-08-01 Process for the polymerization and copolymerization of olefins
GB4511771A Expired GB1269068A (en) 1968-08-26 1969-08-01 Process for the polymerization and copolymerization of olefins

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB4511771A Expired GB1269068A (en) 1968-08-26 1969-08-01 Process for the polymerization and copolymerization of olefins

Country Status (17)

Country Link
JP (1) JPS4837753B1 (en)
AT (1) AT312278B (en)
BE (1) BE737643A (en)
BR (1) BR6911488D0 (en)
CH (1) CH513216A (en)
CS (1) CS167250B2 (en)
DE (1) DE1938461A1 (en)
DK (1) DK124761B (en)
ES (1) ES369932A1 (en)
FR (1) FR1582942A (en)
GB (2) GB1269067A (en)
IE (1) IE33193B1 (en)
NL (1) NL6911629A (en)
NO (1) NO131678C (en)
PL (1) PL80207B1 (en)
RO (1) RO55763A (en)
SE (1) SE382067B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0003159A1 (en) * 1978-01-06 1979-07-25 Du Pont Canada Inc. Ethylene copolymers with a high melt index and manufacture of containers with these
US4315999A (en) * 1979-09-26 1982-02-16 Nippon Oil Company, Limited Process for preparing polyolefins
US4342855A (en) * 1980-08-27 1982-08-03 Idemitsu Kosan Company Limited Process for the production of polyethylene

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2126725C3 (en) * 1970-05-29 1983-04-21 Mitsui Petrochemical Industries Ltd., Tokyo Process for the production of a modified polyethylene wax
DE2630262C2 (en) * 1976-07-06 1985-01-03 Ruhrchemie Ag, 4200 Oberhausen Process for the production of polyolefins

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0003159A1 (en) * 1978-01-06 1979-07-25 Du Pont Canada Inc. Ethylene copolymers with a high melt index and manufacture of containers with these
US4315999A (en) * 1979-09-26 1982-02-16 Nippon Oil Company, Limited Process for preparing polyolefins
US4342855A (en) * 1980-08-27 1982-08-03 Idemitsu Kosan Company Limited Process for the production of polyethylene

Also Published As

Publication number Publication date
FR1582942A (en) 1969-10-10
BE737643A (en) 1970-02-19
JPS4837753B1 (en) 1973-11-13
DK124761B (en) 1972-11-20
IE33193B1 (en) 1974-04-17
DE1938461A1 (en) 1970-05-06
ES369932A1 (en) 1971-06-16
BR6911488D0 (en) 1973-01-09
CH513216A (en) 1971-09-30
NL6911629A (en) 1970-03-02
AT312278B (en) 1973-12-27
NO131678C (en) 1975-07-09
CS167250B2 (en) 1976-04-29
PL80207B1 (en) 1975-08-30
SE382067B (en) 1976-01-12
NO131678B (en) 1975-04-01
RO55763A (en) 1974-01-03
GB1269068A (en) 1972-03-29
IE33193L (en) 1970-02-26

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