KR910021302A - 적층제 및 그 제조방법 - Google Patents

적층제 및 그 제조방법 Download PDF

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KR910021302A
KR910021302A KR1019910001838A KR910001838A KR910021302A KR 910021302 A KR910021302 A KR 910021302A KR 1019910001838 A KR1019910001838 A KR 1019910001838A KR 910001838 A KR910001838 A KR 910001838A KR 910021302 A KR910021302 A KR 910021302A
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polyphenylene sulfide
film
sulfide film
temperature
range
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KR1019910001838A
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KR0174559B1 (ko
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야스히꼬 무다구찌
신이찌로오 미야지
유우기찌 데구찌
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마에다 가쯔노스케
도오레 가부시기가이샤
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/286—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysulphones; polysulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/121—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives by heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/02—Polythioethers; Polythioether-ethers
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/032—Organic insulating material consisting of one material
    • H05K1/0333—Organic insulating material consisting of one material containing S
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/036—Multilayers with layers of different types
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/91—Product with molecular orientation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

내용 없음

Description

적층체 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 무배향 황화폴리페닐렌 필름의 구성되는 Ａ층과, 2축배향 황화폴리페닐렌 필름으로 구성되어 접착제를 사용하지 않고 전기한 Ａ층의 적어도 한쪽 표면에 접합되는 Ｂ층으로 이루어 지며, 전기한 Ａ층의 잔류결정화열은 전기한 Ａ층을 구성하는 수지의 결정화열의 20%이상이고, 전기한 Ｂ층은 20-180℃의 범위에서 결정화에 의한 발열피크를 실제적으로 보유하지 않는 것을 특징으로 하는 적층제.
  2. 제1항에 있어서, 전기한 2축배향 황화폴리페닐렌필름은 접착제를 사용하지 않고 전기한 Ａ층의 양면에 접합되는 것을 특징으로 하는 적층제.
  3. 제1항에 있어서, 전기한 Ａ층의 잔류결정화열은 전기한 Ａ층을 구성하는 수지의 결정화열의 40%이상인 것을 특징으로 하는 적층제.
  4. 제1항에 있어서, 전기한 Ａ층과 Ｂ층의 두께비는 0.2이상 5.0이하의 범위내인 것을 특징으로 하는 적층체.
  5. 제4항에 있어서, 전기한 Ａ층과 Ｂ층의 두께비는 0.3이상 3.0이하의 범위내인 것을 특징으로 하는 적층체.
  6. 제1항에 있어서, 전기한 무배향 황화폴리페닐렌 필름의 용융점도는, 온도 300℃및 전단속도 200sec-1의 조건하에서 700 내지 20000포아즈의 범위내인 것을 특징으로 하는 적층체.
  7. 제1항에 있어서, 전기한 제2축배향 황화폴리페닐렌 필름의 용융점도는, 온도 300℃및 전단속도 200sec-1의 조건하에서 500 내지 12000포아즈의 범위내인 것을 특징으로 하는 적층체.
  8. 제7항에 있어서, 전기한 2측배향 황화폴리페닐렌 필름의 용융점도는, 온도300℃및 전단속도 200sec-1의 조건하에서 700 내지 10000포아즈의 범위내인 것을 특징으로 하는 적층체.
  9. 2측배향 황화폴리페닐렌 필름을 무배향 황화폴리페닐렌 필름의 적어도 한쪽 표면위에 적층하는 단계와, 적층된 필름을 180-270℃범위의 온도와 1-20㎏/㎤범위의 압력조건하에서 열압착에 의해 접합하는 단계와, 접합된 필름을 60초내에 전기한 무배향 황화폴리페닐렌 필름의 결정화온도 이하의 온도까지 냉각시키는 단계로 이루어지는 것을 특징으로 하는 적층제의 제조방법.
  10. 제9항에 있어서, 전기한 적층단계와 전기한 접합단계사이에 적층된 필름을 80-130℃범위의 온도와 1-20 ㎏/㎤범위의 압력조건하에서 미리 열고착시키는 단계가 더 구성되어 있는 것을 특징으로 하는 적층체의 제조방법.
  11. 제9항에 있어서, 전기한 2축배향 황화폴리페닐렌 필름과 전기한 무배향 황화폴리페닐렌 필름이 전기한 2축배향 황화폴리페닐렌 필름위의 황화폴리페닐렌 필름을 제외하고 용융에 의해 시이트형상으로 적층되는 것을 특징으로 하는 적층체의 제조방법.
  12. 제9항에 있어서, 전기한 2축배향 황화폴리페닐렌 필름의 전기한 무배향 황화폴리페닐렌 필름의 표면에 적층시키고, 적층된 필름을 180-270℃범위의 온도와 1-20㎏/㎤범위의 압력조건하에서 열압착에 의해 접합시키고 결합된 60초이내에 전기한 무배향 황화폴리페닐렌 필름의 결정화 온도 이하의 온도까지 냉각시킨 후에, 다른 2축배향 황화폴리페닐렌 필름을 전기한 무배향 황화폴리페닐렌 필름을 180-270℃범위의 온도와 1-20㎏.㎤범위의 압력조건하에서 열압착에 의해 결합시키고, 결합된 필름을 60초이내에 전기한 무배향 황화폴리페닐렌 필름의 결정화온도 이하의 온도까지 냉각시키는 것을 특징으로 하는 적층체의 제조방법.
  13. 제12항에 있어서, 전기한 2축배향 황화폴리페닐렌 필름과 전기한 무배향 황화폴리페닐렌 필름이 전기한 2축배향 황화폴리페닐렌 필름위의 황화폴리페닐렌을 제외하고 시이트형상으로 용융에 의해 적층되는 것을 특징으로 하는 적층체의 제조방법.
  14. 제9항에 있어서, 2축배향 황화폴리페닐렌 필름, 무배향 황화폴리페닐렌 및 다른 2축 배향 황화폴리페닐렌 필름을 실제적으로 동시에 이 순서대로 적층하고 적층된 필름을 전기한 180-270℃범위의 온도와 1-20㎏/㎤범위의 압력조건하에서 열압착에 의해 접합시키고, 접합된 필름을 60초이내에 전기한 무배향 황화폴리페닐렌 필름의 결정화온도 이하의 온도까지 냉각시키는 것을 특징으로 하는 적층체의 제조방법.
  15. 제14항에 있어서, 전기한 2축배향 황화폴리페닐렌 필름들과 전기한 무배향 황화폴리페닐렌 필름은 전기한 2축배향 황화폴리페닐렌 필름 사이의 황화폴리페닐렌을 제외하고 용융에 의해 시이트형상으로 적층되는 것을 특징으로 하는 적층체의 제조방법.
  16. 제9항에 있어서, 전기한 냉각온도는 80℃이하인 것을 특징으로 하는 적층체의 제조방법.
  17. 제9항에 있어서, 불활성가스 분위기내에서 필름이 20℃부터 180℃까지 가열될때, 시차주사열량게에 의해 측정된 발열피크가 250 ℃이상인 무배향 황화폴리페닐렌 필름으로서 사용되는 것을 특징으로 하는 적층체의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910001838A 1990-02-02 1991-02-02 적층제 및 그 제조방법 KR0174559B1 (ko)

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JP2024765A JPH0773902B2 (ja) 1990-02-02 1990-02-02 積層体
JP2-24765 1990-02-02

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KR0174559B1 KR0174559B1 (ko) 1999-03-20

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US (1) US5130181A (ko)
EP (1) EP0440502B1 (ko)
JP (1) JPH0773902B2 (ko)
KR (1) KR0174559B1 (ko)
DE (1) DE69109311T2 (ko)
HK (1) HK1007425A1 (ko)

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JPH0725151B2 (ja) * 1986-06-12 1995-03-22 東レ株式会社 積層フイルム
JPS62292431A (ja) * 1986-06-13 1987-12-19 東レ株式会社 積層フイルム
JPH01192547A (ja) * 1988-01-27 1989-08-02 Toray Ind Inc ポリフェニレンスルフィド樹脂積層体及びその製造方法
JPH0771842B2 (ja) * 1988-08-04 1995-08-02 東レ株式会社 積層体及びその製造方法

Also Published As

Publication number Publication date
EP0440502A1 (en) 1991-08-07
JPH03227624A (ja) 1991-10-08
EP0440502B1 (en) 1995-05-03
US5130181A (en) 1992-07-14
DE69109311D1 (de) 1995-06-08
HK1007425A1 (en) 1999-04-09
DE69109311T2 (de) 1996-01-25
KR0174559B1 (ko) 1999-03-20
JPH0773902B2 (ja) 1995-08-09

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