KR900018214A - 관능화 플루오로 폴리에테르 - Google Patents

관능화 플루오로 폴리에테르 Download PDF

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KR900018214A
KR900018214A KR1019890005939A KR890005939A KR900018214A KR 900018214 A KR900018214 A KR 900018214A KR 1019890005939 A KR1019890005939 A KR 1019890005939A KR 890005939 A KR890005939 A KR 890005939A KR 900018214 A KR900018214 A KR 900018214A
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South Korea
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group
carbon atoms
alog
alogcf
alkyl
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KR1019890005939A
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KR0184599B1 (ko
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마르시오니 주제페
가베조티 피에로
스트레파롤라 에지오
Original Assignee
지오반니 디 드루스코
오시몬트 에스. 알.엘
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
    • C08G65/226—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Indole Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

내용 없음

Description

관능화 플루오로 폴리에테르
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 중에서 선택되는 퍼플루오로옥시알킬렌 단위의 랜덤 분포 서열들로 구성되며, 관능성 말단기 Y를 갖고, 다른 말단기는 불소가 아닌 할로겐 1 또는 2원자를 함유하는 퍼할로알킬기인, 하기일반식(Ⅰ),(Ⅱ) 및 (Ⅲ)으로 표현되는 관능화 플루오로폴리에테르.
    (Ⅰ)
    {상기식에서, X는 F또는 CF3이고, R은 F또는 C1 또는 Br 또는 I이고, R과 같거나 다른 R'은 역시 F 또는 C1 또는 Br 또는 I이며, T는 1~3탄소원자와 C1 또는 Br 또는 I중 1 또는 2원자를 함유하는 퍼할로알킬기이며, 특히 T는 CF2-,, Alog CF2C(CF3)-(식중에서 Alog은 Cl 또는 Br 또는 I이고, n은 1~15임과 동시에 m/n은 0.01~0.5로 표현됨)알수 있고, Y는 -CN 또는 -CH2Z 또는 -COR'기 또는
    또는1/3
    (식중에서, E는 NH, 또는 O 또는 S원자일 수 있음)일 수 있으며 또한, (A)Y=-CH2일때, Z는 OR기 일 수 있고, 여기에서 R는 수소원자 또는;(식중에서 b는 1~15의 수임)-(-CH2CH2O)b--CH=CH2:-(-CH2CH2O)b--=CH2;-CH2-CH=CH2;-CH2--CH2;-(-CH2--CH2O)cH(식중에서 c는 1~3의 수임)-CH2-;[식중에서 R1은 1~30 탄소원자와 -C-O-C-유형의 에테르 결합을 임의적으로 함유하는 알킬이거나 또는 R1은 -(CH2-CH2O)nH (여기에서 n은 1내지 15의 수임), -CH2--OH, -CH2-CH2-CH2SO3H,및 또한 나프킬기, 또는
    유형의 모노 또는 폴리치환된 알킬벤질기 또는 모노 폴리치환된 알콕시벤질기(여기에서 R2는 탄소원자수 1~4의 알킬임)임]이며; 또는 Z는 질소-함유기-NR2R4기일수 있고, 여기에서 서로 유사하거나 다른 R3와 R4는 수소원자이거나, 개별적으로 또는 둘다가 상기 정의된 R1기 일 수 있으며, 또는 R3=H일때, R4는 --CH=CH2또는 --;=CH3;일 수 있고, 또는 R3와 R4는 함께 하기식의 아미드고리를 형성할 수 있으며;
    (식중에서 페닐기는 무수물 유형의 치환기를 함유할수 있음) (B)Y=COR'기일때, R'는 -NHR5기일 수 있으며, 여기에서 R5는 수소 또는 탄소원자수 1~8의 알킬일수 있고, 또는 R5는 탄소원자수 1~8의 모노-또는 폴리히드록시알킬, 탄소원자수 1~8의 아미노알킬, 알릴기, 메트 알릴기, 식 R6-Si(OCH3)3또는 R6Si(OC2H5)3의 트리메톡시- 또는 트리에톡시-실란기(식중에서 R6는 1~8탄소원자의 알킬렌임), 또는 R6NCO의 이소시아노 알킬 또는 5~6탄소원자의 이소시아노시클로알킬기, 또는 임의적 알킬-치환된 6~10 탄소원자의 이소시아노아릴기일수 있으며; 또는 R'는 임의적으로 알킬-또는 할로겐-치환된 방향족 라디칼, 예컨대 펜타플루오로페닐,브로모테트라플루오로페닐, 디브로모디플루오로페닐, 브로모페닐, 브로모벤조페닐일 수 있다.
    T'-O(CF2CF2O)p(CF2O)sCRR'Y (Ⅱ)
    (상기식에서 T'는 AlogCF2CF2-, AlogCF2-, AlogCF2CF(Alog)-이며; R, R', Alog, Y는 앞에서 식(Ⅰ)에 대해 정의된 바와 같고; p는 1~20이고 s/p는 0.5~2이다.)
    (상기식에서, Y,X,R 및 R'는 앞에서 식(Ⅰ)에 대해 정의된 바와 같고, T는 T 또는 T'와 같고, o와 q는 o+q=1~20, z/o+q가 0.01~0.05인, 0를 포함하는 수이다.)
  2. 제1항에 있어서, T가 AlogCF2-, Alog-, AlogCF2CF(CF3)- (식중에서 Alog는 Cl, Br 또는 I임)중에서 선택되는 기인 플루오로폴리에테르.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890005939A 1989-04-20 1989-05-02 관능학 플루오로폴리에테르 KR0184599B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT8947869A IT1231758B (it) 1989-04-20 1989-04-20 Fluoropolieteri funzionalizzati
IT47869A/89 1989-04-20

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KR900018214A true KR900018214A (ko) 1990-12-20
KR0184599B1 KR0184599B1 (ko) 1999-05-15

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US (3) US5446205A (ko)
EP (1) EP0393230B1 (ko)
JP (1) JP2804077B2 (ko)
KR (1) KR0184599B1 (ko)
AU (1) AU619286B2 (ko)
CA (1) CA1336908C (ko)
CZ (1) CZ280100B6 (ko)
DE (1) DE68924845T2 (ko)
ES (1) ES2079360T3 (ko)
IL (1) IL90155A (ko)
IT (1) IT1231758B (ko)
RU (1) RU2034000C1 (ko)
ZA (1) ZA893233B (ko)

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Also Published As

Publication number Publication date
IL90155A (en) 1994-04-12
US5714637A (en) 1998-02-03
US6156937A (en) 2000-12-05
ZA893233B (en) 1990-03-28
US5446205A (en) 1995-08-29
IL90155A0 (en) 1989-12-15
CA1336908C (en) 1995-09-05
IT1231758B (it) 1991-12-21
AU3396489A (en) 1990-10-25
EP0393230B1 (en) 1995-11-15
DE68924845T2 (de) 1996-06-05
JP2804077B2 (ja) 1998-09-24
AU619286B2 (en) 1992-01-23
CZ269589A3 (en) 1995-06-14
KR0184599B1 (ko) 1999-05-15
ES2079360T3 (es) 1996-01-16
EP0393230A2 (en) 1990-10-24
EP0393230A3 (en) 1991-05-02
JPH03197436A (ja) 1991-08-28
DE68924845D1 (de) 1995-12-21
CZ280100B6 (cs) 1995-10-18
RU2034000C1 (ru) 1995-04-30
IT8947869A0 (it) 1989-04-20

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