KR900016149A - 살충·살비 활성의 피리다지논 - Google Patents

살충·살비 활성의 피리다지논 Download PDF

Info

Publication number
KR900016149A
KR900016149A KR1019900004666A KR900004666A KR900016149A KR 900016149 A KR900016149 A KR 900016149A KR 1019900004666 A KR1019900004666 A KR 1019900004666A KR 900004666 A KR900004666 A KR 900004666A KR 900016149 A KR900016149 A KR 900016149A
Authority
KR
South Korea
Prior art keywords
chloro
pyridazinone
butyl
group
benzylthio
Prior art date
Application number
KR1019900004666A
Other languages
English (en)
Other versions
KR0140208B1 (ko
Inventor
베타리니 프랑코
카푸치 루이기
마씨미니 세르지오
카스트로 파올로
카프리올리 빈센조
Original Assignee
루이기 코티
프레시덴자 델 콘시글리오 데이 미니스트리 우피시오 델 미니스트로 페르 일 코오르디나멘토 델레 이니지아티베 페르 라 리세르카 사이엔티피카 에테크놀로지카
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 루이기 코티, 프레시덴자 델 콘시글리오 데이 미니스트리 우피시오 델 미니스트로 페르 일 코오르디나멘토 델레 이니지아티베 페르 라 리세르카 사이엔티피카 에테크놀로지카 filed Critical 루이기 코티
Publication of KR900016149A publication Critical patent/KR900016149A/ko
Application granted granted Critical
Publication of KR0140208B1 publication Critical patent/KR0140208B1/ko

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
    • C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D237/14—Oxygen atoms
    • C07D237/16—Two oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
    • C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D237/18—Sulfur atoms

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음.

Description

살충·살비 활성의 피리다지논
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 일반식(I)의 피리다지논
    [상기식에서, R은 직쇄 또는 측쇄(C2~C6)알킬기 : 할로겐원자, 저급알킬, 할로알킬, 알콕시, 할로알콕시기로 치환될 수 있는 페닐기를 나타내고; X는 할로겐원자를 나타내며, Y는 산소원자나 황원자 또는 NH기를 나타내고; B는를 나타내며; b는 0 또는 1이고; R1, R2, R3및 R4은 각각 독립적으로 H, 직쇄 또는 측쇄(C1~C4)알킬 또는 할로알킬기를 나타내며; Z는 CH기 또는 N원자를 나타내고; Y1는 O, S, CO 또는(식중, Rk및 Rj는 각각 독립적으로 H, 직쇄 또는 측쇄(C1~C4)알킬 또는 할로알킬기이다)를 나타내며; W는 직쇄 또는 측쇄(C2~C6) 할로알킬렌을 나타내고; y 및 w는 각각 독립적으로 0또는 1이며; Rx는 W=0일 때 치환체로서C1~C3할로알콕시 또는 페닐기(페닐기는 할로겐원자, (C1~C6)알킬, 할로알킬, 알콕시, 할로알콕시기로 이루어진 회전 치환체를 함유할 수 있다)를 함유할 수 있는 직쇄 또는 측쇄(C2~C6)할로알케닐기; (C1~C4)알킬 또는 할로알킬기로 이루어진 치환체를 함유할 수 있는 (C3~C6) 할로시클로알킬기 또는 (C4~C7)할로시클로알킬알킬기를 나타내며; w=1일때는 직쇄 또는 측쇄(C1~C6)할로알킬기를 나타내고; R′은 할로겐원자를 나타내며; n은 0, 1, 2이고; n이 2일때는 R′기는 동일하건 서로 다를 수 있다.]
  2. 제1항에 있어서, 하기 일반식(Ia)의 피리다지논.
    [상기식에서, R은 (C2~C6) 알킬기를 나타내고; X는 할로겐을 나타내며; Y는 O, S를 나타내고; 그 밖의 다른 부호는 제1항에서 정의한 바와 같다.]
  3. 2-t-부틸-4-클로로-5-[4-(1,1,2-트리플루오로-2-트리플루오로메톡시에톡시)-α-메틸벤질옥시]-3(2H)-피리다지논.
  4. 2-t-부틸-4-클로로-5-[4-(1,1,2-트리플루오로-2-트리플루오로메톡시에톡시)-α-메틸벤질티오]-3(2H)-피리다지논.
  5. 2-t-부틸-4-클로로-5-[4-(1,1,2-트리플루오로-2-트리플루오로메톡시에톡시)-벤질옥시]-3(2H)-피리다지논.
  6. 2-t-부틸-4-클로로-5-[4-(1,1,2-트리플루오로-2-트리플루오로메톡시에톡시)-벤질티오]-3(2H)-피리다지논.
  7. 2-t-부틸-4-클로로-5-[4-(2-펜타플루오로에톡시-1,1,2-트리플루오로메톡시)-벤질티오]-3(2H)-피리다지논.
  8. 2-t-부틸-4-클로로-5-[4-(2-펜타플루오로에톡시-1,1,2-트리플루오로메톡시)-α-메틸벤질티오]-3(2H)-피리다지논.
  9. 2-t-부틸-4-클로로-5-[4-(2-클로로-3,3,3-트리플루오로프로메톡시)-벤질티오]-3(2H)-피리다지논.
  10. 2-t-부틸-4-클로로-5-[4-(2,2-디클로로에테닐(0벤질티오]-3(2H)-피리다지논.
  11. 2-t-부틸-4-클로로-5-[4-(1,1,2-트리플루오로)-2-트리플루오로메톡시에톡시)-에틸)-벤질티오]-3(2H)-피리다지논.
  12. 2-t-부틸-4-클로로-5-[4-(1,2-디플루오로)-2-트리플루오로메톡시에톡시)-벤질티오]-3(2H)-피리다지논.
  13. 2-t-부틸-4-클로로-5-[4-(2-클로로-3,3,3-트리플루오로프로페닐)-α-메틸벤질티오]-3(2H)-피리다지논.
  14. 2-t-부틸-4-클로로-5-[4-(2,2-디클로로에테닐)-α-메틸벤질티오]-3(2H)-피리다지논.
  15. 2-t-부틸-4-클로로-5-[4-(1,2-디플루오로-2-트리플루오로메톡시에테닐)-α-메틸벤질티오]-3(2H)-피리다지논.
  16. 2-t-부틸-4-클로로-5-[4-(2-클로로-2-페닐에테닐)-벤질티오]-3(2H)-피리다지논.
  17. 2-t-부틸-4-클로로-5-[4-(2-클로로-(4-클로로페닐)-에테닐)-벤질티오]-3(2H)-피리다지논.
  18. 2-t-부틸-4-클로로-5-[4-(2,2-디클로로-1-메틸시클로로프로필메톡시)-벤질티오]-3(2H)-피리다지논.
  19. 2-t-부틸-4-클로로-5-[4-(2,2-디클로로-1-메틸시클로로프로필카르보닐)-벤질티오]-3(2H)-피리다지논.
  20. 2-(3,4-디클로로페닐)-4-클로로-5-[4-(1,1,2-트리플루오로-2-트리플루오로메톡시에톡시)-벤질옥시]-3(2H)-피리다지논.
  21. 2-(3,4-디클로로페닐)-4-클로로-5-[4-(1,1,2-트리플루오로-2-트리플루오로메톡시에톡시)-벤질티오]-3(2H)-피리다지논.
  22. 유기비힐클중, 무기 또는 유기 염기의 존재하에, 실온에서 반응 혼합물의 비점까지의 온도 범위에서, 하기식(II)의 피리다지논을 식(III)의 화합물과 반응시키는 것을 특징으로 하는, 제1항에서 청구한 식(I)의 피리다지논의 제조방법.
    [상기식에서, R,X,Y,R1,R2,R3,R4,Z,Y1,W,Rx,R′,b,y,w 및 n은 제1항의 식(I)에서 정의한 바와같고; X′ 및 X″는 CL, Br 또는 I원자, 혹은 YH기(여기에서, Y는 상기 정의한 바와같다)를 나타내지만, 이들 중 어느 하나는 YH기로 구성되어야 하며, 다른 하나는 Cl, Br, 또는 I로 구성되어야 한다.]
  23. 제1항에서 청구한 식(I)의 피리다지논 1종 이상을 유효량으로 농작물, 원예작물, 및/또는 인간 및/또는 가축 및/또는 사육동물이 기거하는 공간에 사용함을 특징으로 하는, 농작물, 원예작물 및/또는 기거공간에 있어서 해충 및/또는 진드기의 침투 억제 방법.
  24. 제1항에서 청구한 식(I)의 피리다지논 1종 이상과 1종 이상의 고상 또는 액상 담체, 살충·살비제 분야에서 유용한 기타 첨가제 및/또는 다른 활성물질 및 비료를 함유하는 것을 특징으로 하는, 해충 및/또는 진드기 침투 억제용조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900004666A 1989-04-05 1990-04-04 살충, 살비활성의 피리다지논 KR0140208B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT8920013A IT1229684B (it) 1989-04-05 1989-04-05 Piridazinoni ad attivita' insetticida ed acaricida
IT20013A/89 1989-04-05

Publications (2)

Publication Number Publication Date
KR900016149A true KR900016149A (ko) 1990-11-12
KR0140208B1 KR0140208B1 (ko) 1998-06-01

Family

ID=11163119

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900004666A KR0140208B1 (ko) 1989-04-05 1990-04-04 살충, 살비활성의 피리다지논

Country Status (9)

Country Link
US (1) US5169848A (ko)
EP (1) EP0391390B1 (ko)
JP (1) JP2807035B2 (ko)
KR (1) KR0140208B1 (ko)
AT (1) ATE118210T1 (ko)
CA (1) CA2013687A1 (ko)
DE (1) DE69016687T2 (ko)
ES (1) ES2068935T3 (ko)
IT (1) IT1229684B (ko)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02279676A (ja) * 1989-04-19 1990-11-15 Otsuka Chem Co Ltd ピリダジノン誘導体
US5286725A (en) * 1990-09-17 1994-02-15 Ministero Dell'universita' E Della Ricerca Scientifica E Technologica Pyridazinones endowed with acaricide and insecticide action
US5312990A (en) * 1993-05-28 1994-05-17 Hoechst Celanese Corporation Di-amino compounds
US5300691A (en) * 1993-05-28 1994-04-05 Hoechst Celanese Corporation Substituted benzyl amines
US5670504A (en) * 1995-02-23 1997-09-23 Merck & Co. Inc. 2,6-diaryl pyridazinones with immunosuppressant activity
JP2001335565A (ja) * 2000-05-31 2001-12-04 Mitsubishi Chemicals Corp ピリダジノン類およびこれを有効成分とする有害生物防除剤
JP4640538B2 (ja) * 2000-06-27 2011-03-02 日本農薬株式会社 ピリダジノン類およびこれを有効成分とする有害生物防除剤
US7344702B2 (en) 2004-02-13 2008-03-18 Bristol-Myers Squibb Pharma Company Contrast agents for myocardial perfusion imaging
US7485283B2 (en) * 2004-04-28 2009-02-03 Lantheus Medical Imaging Contrast agents for myocardial perfusion imaging
US7824659B2 (en) 2005-08-10 2010-11-02 Lantheus Medical Imaging, Inc. Methods of making radiolabeled tracers and precursors thereof
PT2257315T (pt) 2008-02-29 2020-01-27 Lantheus Medical Imaging Inc Agentes de contraste para aplicações incluindo imagiologia de perfusão
WO2010057691A2 (en) * 2008-08-11 2010-05-27 Solvay Solexis S.P.A. Hydrofluoroalcohols with improved thermal and chemical stability
CA2758883C (en) 2009-04-15 2020-03-10 Lantheus Medical Imaging, Inc. Stabilization of radiopharmaceutical compositions using ascorbic acid
EP2534136B1 (en) 2010-02-08 2017-09-06 Lantheus Medical Imaging, Inc. Methods for synthesizing imaging agents, and intermediates thereof
AU2013203000B9 (en) 2012-08-10 2017-02-02 Lantheus Medical Imaging, Inc. Compositions, methods, and systems for the synthesis and use of imaging agents
US8962879B2 (en) 2012-11-14 2015-02-24 E I Du Pont De Nemours And Company Perfluoropolyvinyl modified aryl intermediates/monomers
US9145356B2 (en) * 2012-11-14 2015-09-29 E I Du Pont De Nemours And Company Perfluoropolyvinyl modified aryl intermediates and monomers
US9365476B2 (en) 2012-11-14 2016-06-14 E I Du Pont De Nemours And Company Aryl compounds modified with perfluorovinyl ethers
US9193702B2 (en) 2013-10-31 2015-11-24 E I Du Pont De Nemours And Company Fluorinated aryl epoxide compounds

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4571397A (en) * 1982-03-05 1986-02-18 Nissan Chemical Industries Pyridazinone derivatives, preparation thereof, and agricultural and horticultural fungicidal, insecticidal, acaricidal, nematicidal compositions containing said derivatives
GR79933B (ko) * 1983-06-23 1984-10-31 Nissan Chemical Ind Ltd
EP0183212B1 (en) * 1984-11-29 1990-06-20 Nissan Chemical Industries Ltd. Pyridazinone derivatives, preparation thereof, and insecticidal, acaricidal, nematicidal, fungicidal compositions
US4837217A (en) * 1985-04-19 1989-06-06 Nissan Chemical Industries, Ltd. Pyridazinone derivatives, preparation thereof, and insecticidal, acaricidal, nematicidal, fungicidal compositions
YU134686A (en) * 1985-07-30 1988-02-29 Nissan Chemical Ind Ltd Process for preparing new derivatives 3-(2h)-pyridazinone
ZA87704B (en) * 1986-02-08 1987-09-30 Nissan Chemical Ind Ltd Pyridazinone derivatives,preparation thereof,and insecticidal,acaricidal,nematicidal,fungicidal compositions
EP0283271A3 (en) * 1987-03-17 1990-04-25 Ube Industries, Ltd. Pyridazinone derivative, process for producing thereof and insecticide, acaricide and fungicide containing said derivative as active ingredient
JPS63275569A (ja) * 1987-05-07 1988-11-14 Nissan Chem Ind Ltd ピリダジノン誘導体および害虫防除剤
JPH0638630B2 (ja) * 1987-07-13 1994-05-18 株式会社日立製作所 マルチスキャン水平発振回路
JPH01112057A (ja) * 1987-10-23 1989-04-28 Japan Autom Transmission Co Ltd 副変速機付多段自動変速機

Also Published As

Publication number Publication date
EP0391390A1 (en) 1990-10-10
CA2013687A1 (en) 1990-10-05
IT1229684B (it) 1991-09-06
IT8920013A0 (it) 1989-04-05
ES2068935T3 (es) 1995-05-01
KR0140208B1 (ko) 1998-06-01
DE69016687T2 (de) 1995-06-08
US5169848A (en) 1992-12-08
EP0391390B1 (en) 1995-02-08
DE69016687D1 (de) 1995-03-23
ATE118210T1 (de) 1995-02-15
JPH0356466A (ja) 1991-03-12
JP2807035B2 (ja) 1998-09-30

Similar Documents

Publication Publication Date Title
KR900016149A (ko) 살충·살비 활성의 피리다지논
HRP960596A2 (en) Novel pesticides
ATE227269T1 (de) 1-arylpyrazole insektizide
KR20000062319A (ko) 살충 1-아릴피라졸
CZ228399A3 (cs) Pesticidní 1-arylpyrazolové sloučeniny, způsob jejich použití a prostředky, které je obsahují
CZ438790A3 (en) N-phenylpyrazole derivative, insecticidal and acaricidal agent containing this derivative and method of killing harmful insects and mites
RO107407B1 (ro) Derivati de 1-aril-5-alchilidenimino-pirazoli, procedeu pentru prepararea acestora, compozitie pesticida continandu-i si metoda de control
KR100742976B1 (ko) 살충용 1-아릴-3-이미노피라졸
CA2217205C (en) Methods of attracting and combatting insects
KR910002843A (ko) 치환된 이미다졸일메틸옥시란 및 치환된 이미다졸일프로펜, 이들의 제법 및 이들을 함유하는 살균제
KR870001179A (ko) 1-디메틸카르바모일-3-치환-5-치환-1h-1,2,4-트리아졸
KR870011093A (ko) N-시아노알킬이소니코틴아미드 유도체
JPH08217609A (ja) 殺虫、殺ダニ剤組成物
TW526043B (en) Pesticidal 1-arylpyrazoles
JPS6241564B2 (ko)
KR890014493A (ko) 아졸일메틸알릴 알콜 및 이 화합물을 함유하는 살균제
JP4055022B2 (ja) 殺虫・殺ダニ剤
JPH04334374A (ja) Ｎ−（２−チアゾリル）尿素誘導体、その製造方法および該化合物を含有する殺虫剤
JPH115708A (ja) 殺虫殺菌組成物
PT99616B (pt) Processo para a preparacao de compostos diarilpirrolecarbonitrilo e diarilnitropirrole insecticidas e acaricidas
KR900016148A (ko) 3(2h)-피리다진온 유도체 및 이들을 사용하여 해충을 억제하는 방법
KR950005826A (ko) 살충제 및 진드기구충제로서 티에닐-및 푸릴피롤 화합물
JPS61145106A (ja) 殺虫・殺ダニ剤組成物
US4211778A (en) Use of carbothiolates as insecticides
JP4698729B2 (ja) 殺ダニトリアゾリジン誘導体

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee