KR900015814A - 유기 화합물을 탈수소화 시키는 촉매, 그 제조 및 사용방법 - Google Patents
유기 화합물을 탈수소화 시키는 촉매, 그 제조 및 사용방법 Download PDFInfo
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- KR900015814A KR900015814A KR1019890005582A KR890005582A KR900015814A KR 900015814 A KR900015814 A KR 900015814A KR 1019890005582 A KR1019890005582 A KR 1019890005582A KR 890005582 A KR890005582 A KR 890005582A KR 900015814 A KR900015814 A KR 900015814A
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- potassium
- iron
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- oxide
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- 238000000034 method Methods 0.000 title claims 21
- 239000003054 catalyst Substances 0.000 title claims 11
- 150000002894 organic compounds Chemical class 0.000 title claims 2
- 239000003153 chemical reaction reagent Substances 0.000 claims 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 9
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims 9
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 7
- 238000006356 dehydrogenation reaction Methods 0.000 claims 7
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 6
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims 6
- 229910001950 potassium oxide Inorganic materials 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 claims 3
- 235000010333 potassium nitrate Nutrition 0.000 claims 3
- 239000004323 potassium nitrate Substances 0.000 claims 3
- 235000010289 potassium nitrite Nutrition 0.000 claims 3
- 239000004304 potassium nitrite Substances 0.000 claims 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 2
- 238000002441 X-ray diffraction Methods 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229940056319 ferrosoferric oxide Drugs 0.000 claims 2
- 229910052598 goethite Inorganic materials 0.000 claims 2
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims 2
- VPBPOXIFRZBJEU-UHFFFAOYSA-L iron(2+);dinitrite Chemical compound [Fe+2].[O-]N=O.[O-]N=O VPBPOXIFRZBJEU-UHFFFAOYSA-L 0.000 claims 2
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 claims 2
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical group [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 claims 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims 2
- KAQHZJVQFBJKCK-UHFFFAOYSA-L potassium pyrosulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OS([O-])(=O)=O KAQHZJVQFBJKCK-UHFFFAOYSA-L 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- YNVZDODIHZTHOZ-UHFFFAOYSA-K 2-hydroxypropanoate;iron(3+) Chemical compound [Fe+3].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O YNVZDODIHZTHOZ-UHFFFAOYSA-K 0.000 claims 1
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 claims 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000004153 Potassium bromate Substances 0.000 claims 1
- 241000656145 Thyrsites atun Species 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 150000001720 carbohydrates Chemical class 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- MAPCAVCZPLEVPL-UHFFFAOYSA-L dibromoiron iron Chemical compound [Fe].[Fe](Br)Br MAPCAVCZPLEVPL-UHFFFAOYSA-L 0.000 claims 1
- XALJLKNTPLIEGK-UHFFFAOYSA-L dioxido-oxo-sulfanylidene-$l^{6}-sulfane;iron(2+) Chemical compound [Fe+2].[O-]S([O-])(=O)=S XALJLKNTPLIEGK-UHFFFAOYSA-L 0.000 claims 1
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims 1
- 238000000407 epitaxy Methods 0.000 claims 1
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 claims 1
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 claims 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims 1
- 235000014413 iron hydroxide Nutrition 0.000 claims 1
- ZPKLYVJENOZRAW-UHFFFAOYSA-L iron(2+);dichlorate Chemical compound [Fe+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O ZPKLYVJENOZRAW-UHFFFAOYSA-L 0.000 claims 1
- FPNCFEPWJLGURZ-UHFFFAOYSA-L iron(2+);sulfite Chemical compound [Fe+2].[O-]S([O-])=O FPNCFEPWJLGURZ-UHFFFAOYSA-L 0.000 claims 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 claims 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 claims 1
- SHXXPRJOPFJRHA-UHFFFAOYSA-K iron(iii) fluoride Chemical compound F[Fe](F)F SHXXPRJOPFJRHA-UHFFFAOYSA-K 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229960003975 potassium Drugs 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 235000015497 potassium bicarbonate Nutrition 0.000 claims 1
- 239000011736 potassium bicarbonate Substances 0.000 claims 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims 1
- 229940094037 potassium bromate Drugs 0.000 claims 1
- 235000019396 potassium bromate Nutrition 0.000 claims 1
- 229910000027 potassium carbonate Inorganic materials 0.000 claims 1
- 229940093956 potassium carbonate Drugs 0.000 claims 1
- 235000011181 potassium carbonates Nutrition 0.000 claims 1
- 239000001103 potassium chloride Substances 0.000 claims 1
- 235000011164 potassium chloride Nutrition 0.000 claims 1
- 239000011698 potassium fluoride Substances 0.000 claims 1
- 235000003270 potassium fluoride Nutrition 0.000 claims 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims 1
- 229940093928 potassium nitrate Drugs 0.000 claims 1
- 238000010791 quenching Methods 0.000 claims 1
- 230000000171 quenching effect Effects 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 229910052596 spinel Inorganic materials 0.000 claims 1
- 239000011029 spinel Substances 0.000 claims 1
- 229940071182 stannate Drugs 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 229910000859 α-Fe Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/322—Catalytic processes with metal oxides or metal sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compounds Of Iron (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (28)
- 철 : 칼륨 원자비로서 계산된 산화철 제공 시약 및 산화 칼륨 제공 시약 사이의 몰 비율이 1.5-60범위에 있고 K2Fe12O19상이 팔면체의 Fe3O4매트릭스 안에 존재하여, K2Fe12O19의 변형구조와 Fe3O4스피넬 구조의 (111) 평면사이에 결정성 적층 성장(epitaxy)을 보여주는 것을 특징으로 하는, 산화 철 제공 시약 및 산화 칼륨 제공시약으로부터 유도 가능한 탈수소화 촉매.
- 제1항에 있어서, 결정성 입자 크기가 0.5-15㎛범위에서 변화하는 탈수소화 촉매.
- 제2항에 있어서, 결정성 입자 크기가 1-10㎛범위에서 변화하는 것을 특징으로 하는 탄수소화 촉매.
- 제1항 및 제2항에 있어서, d=12.4A-d=1.60Å면적에서 가장 강한 X-선 회절 파이크를 갖는 것을 특징으로 하는 탈수소화 촉매.
- 제1항 내지 제4항 중 어느 한 항에 있어서, d=11.9Å, 2.83Å 및 2.65Å에서 가장 강한 X-선 회절 파이크를 갖는 특징으로 하는 탈수소화 촉매.
- 제1항 내지 제5항 중 어느 한 항에 있어서, 40-240Å범위의 육변형 K2Fe12O19판 두께를 갖는 것을 특징으로 하는 탈수소화 촉매.
- 제1항 내지 제6항 중 어느 한 항에 있어서, K Fe(Ⅲ)O2상이 본질적으로 없는 것을 특징으로 하는 탈수소화 촉매.
- 임계초과 조건하에서 환원제로서 작용하는 용매가 존재하는 가운데, 100-1000바아 범위의 압력에서, 300-1000℃ 범위의 온도에서, 산화 칼륨 제공 시약과 임의로 혼합된, 페르소(ferroso)-산화 제이철 제공 시약을 반응시키고, 반응 혼합물을 빨리 퀸칭시킨 다음 얻어진 팔면체 페르소-산화 제이철을 산화 칼륨 제공 시약과 혼합시키거나 함침시키고 불활성 분위기하에 300-1000℃ 범위의 온도에서 혼합물을 소성시키는 것을 포함하는 탈수소화 촉매의 제조 방법.
- 제8항에 있어서, 페로소-산화 제이철 제공 시약이, 수산화 철, 침철석(α-Fe OOH), 탄산 철, 옥살산 철, 질산 철, 아질산 철, 염화 철, 브롬화 철, 불화 철, 염소산 철, 브롬산 철, 아세트산 철, 황화 철, 시트르산 철, 주석산 철, 락트산 철, 티오황산 철, 아황산 철로부터 선택되며, 철의 원자가 3인 것이 바람직한 것을 특징으로 하는 방법.
- 제8항 내지 제9항 중 어느 한 항에 있어서, 산화 칼륨 제공시약이 탄산 칼륨, 탄산수소 칼륨, 질산 칼륨, 옥살산 칼륨, 아질산 칼륨, 불화칼륨, 염화 칼륨, 브롬화 칼륨, 요오드화 칼륨, 피로황산 칼륨, 과산화이황산 칼륨, 염소산 칼륨, 브롬산 칼륨, 또는 요오드산 칼륨으로 부터 선택되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 침철석, 수화된 산화 철, 아세트산 철, 질산 철, 아질산 철, 시트르산 철 또는그 혼합물이 사용되는 것을 특징으로 하는 방법.
- 제10항에 있어서, 질산 칼륨, 아질산 칼륨, 피로황산 칼륨, 과산화이황산 칼륨, 요오드산 칼륨, 염소산 칼륨, 브롬산 칼륨 등, 또는 그 혼합물이 사용되는 것을 특징으로 하는 방법.
- 제10항 및 제12항에 있어서, 질산 칼륨, 아질산 칼륨 또는 그 혼합물이 사용되는 것을 특징으로 하는 방법.
- 제8항 내지 제13항 중 어느 한 항에 있어서, 용매로서 1-4개의 탄소원자를 함유하는 알콜이 사용되는 것을 특징으로 하는 방법.
- 제8항 내지 제14항 중 어느 한항에 있어서, 알콜이 20-100부피 %의 알콜 함량으로 물과 혼합되는 것을 특징으로 하는 방법.
- 제1항 내지 제15항 중 어느 한 항에 있어서, 350-850℃범위의 온도가 적용되는 것을 특징으로 하는 방법.
- 제8항 내지 제16항 중 어느 한 항에 있어서, 350-750바아 범위의 압력이 페로소-산화제이철 상 형성 단계 동안 적용되는 것을 특징으로 하는 방법.
- 제8항 내지 제17항 중 어느 한 항에 있어서, 페로소-산화 제이철 상 형성 단계를 위한 공정시간이 6-12시간 범위인 것을 특징으로 하는 방법.
- 제18항에 있어서, 공정 시간이 8-12시간 범위인 것을 특징으로 하는 방법.
- 제8항 내지 제19항 중 어느 한 항에 있어서, 페로소-산화 제이철 상-K2Fe12O19상 형성 단계가 1-4시간 범위인 것을 특징으로 하는 방법
- 제1항 내지 제7항에 따른 촉매를 적용시켜, 임의로 치환된 알칸을 올레핀으로 탈수소화 시키는 방법.
- 제21항에 있어서, 2-12개의 탄소원자를 함유하는 화합물이 탈수소화되는 방법.
- 제21항 및 제22항에 있어서, 에틸벤젠이 전환되는 것을 특징으로 하는 방법.
- 제21항 내지 제23항 중 어느 한 항에 있어서, 온도가 450-650℃ 범위에 있는 것을 특징으로 하는 방법.
- 제21항 내지 제24항 중 어느 한 항에 있어서, 유기 화합물이 2-20범위의 몰비율로 스팀과 혼합되는 것을 특징으로 하는 방법.
- 제25항에 있어서, 스팀 대 알칸의 몰 비율이 5-13범위에 있는 것을 특징으로 하는 방법.
- 제21항 내지 제26항 중 어느 한 항에 있어서. 매시간마다의 액체 공간 속도가 0.1-5.01알킬벤젠/촉매 1/h범 위로 적용되는 것을 특징으로 하는 방법.
- 제21항 내지 제26항 중 어느 한 항에 있어서, 순환하는 고형물을 함유하는 접촉 다운플로우(downflow)반응 기가 사용되는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8805764A FR2630662A1 (fr) | 1988-04-29 | 1988-04-29 | Catalyseur pour la deshydrogenation de composes organiques, procede pour sa preparation et son utilisation |
| NL8805764 | 1988-04-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR900015814A true KR900015814A (ko) | 1990-11-10 |
| KR0130067B1 KR0130067B1 (ko) | 1998-04-06 |
Family
ID=9365834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890005582A KR0130067B1 (ko) | 1988-04-29 | 1989-04-27 | 유기 화합물을 탈수소화시키는 촉매, 그 제조 및 사용 방법. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4975407A (ko) |
| EP (1) | EP0339704B1 (ko) |
| JP (1) | JP2729831B2 (ko) |
| KR (1) | KR0130067B1 (ko) |
| CN (1) | CN1023883C (ko) |
| AU (1) | AU612022B2 (ko) |
| BR (1) | BR8901978A (ko) |
| CA (1) | CA1335729C (ko) |
| DE (1) | DE68904682T2 (ko) |
| ES (1) | ES2053948T3 (ko) |
| FR (1) | FR2630662A1 (ko) |
| SA (1) | SA90100156B1 (ko) |
| ZA (1) | ZA893126B (ko) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5171914A (en) * | 1991-08-30 | 1992-12-15 | Shell Oil Company | Dehydrogenation catalyst and process |
| JPH07178340A (ja) * | 1993-11-11 | 1995-07-18 | Idemitsu Petrochem Co Ltd | アルキル芳香族炭化水素の脱水素反応用触媒及びこれを用いたビニル芳香族炭化水素の製造方法 |
| WO1996018457A1 (en) * | 1994-12-14 | 1996-06-20 | Shell Internationale Research Maatschappij B.V. | Restructured iron oxide |
| CA2207560A1 (en) * | 1994-12-14 | 1996-06-20 | Shell Internationale Research Maatschappij B.V. | Large particle dehydrogenation catalyst and process |
| DE19535416A1 (de) * | 1995-09-23 | 1997-03-27 | Basf Ag | Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen |
| JPH10273452A (ja) * | 1997-03-31 | 1998-10-13 | Idemitsu Petrochem Co Ltd | アルキル芳香族炭化水素の脱水素反応用触媒およびその製造方法ならびにこれを用いたビニル芳香族炭化水素の製造方法 |
| DE19814080A1 (de) * | 1998-03-30 | 1999-10-07 | Basf Ag | Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung |
| US6756339B1 (en) | 1998-04-01 | 2004-06-29 | Sud-Chemie Inc. | Dehydrogenation catalysts |
| US6242379B1 (en) * | 1998-04-01 | 2001-06-05 | United Catalysts Inc. | Dehydrogenation catalysts |
| JP4841888B2 (ja) * | 2005-08-03 | 2011-12-21 | 株式会社トクヤマ | 塩化ビニルモノマーの貯蔵方法 |
| JP4670603B2 (ja) * | 2005-11-18 | 2011-04-13 | 株式会社デンソー | 触媒用粒子およびその製造方法 |
| CN101602004B (zh) * | 2008-06-12 | 2011-04-27 | 中国石油化工股份有限公司 | 制备乙苯脱氢制苯乙烯催化剂的方法 |
| AU2012253913B2 (en) * | 2011-05-11 | 2017-03-02 | Archer Daniels Midland Company | Processes for making acrylic-type monomers and products made therefrom |
| CN103008011B (zh) * | 2011-09-23 | 2015-11-25 | 中国石油化工股份有限公司 | 一种含甲酰基或异丁酰基取代的1,10-菲咯啉缩胺合铁(ⅱ)配合物的乙烯齐聚催化剂组合物 |
| EP2831021B1 (en) | 2012-03-29 | 2019-11-27 | TPC Group LLC | Improved controllability oxidative dehydrogenation process for producing butadiene |
| CN103933987A (zh) * | 2013-01-18 | 2014-07-23 | 济南大学 | 一种氧化铁皮制备的用于工业合成氨的熔铁催化剂 |
| CN108203365B (zh) * | 2016-12-16 | 2021-01-29 | 中国石油天然气股份有限公司 | 用于乙苯脱氢制苯乙烯的方法 |
| CN109988082B (zh) * | 2019-05-05 | 2022-04-19 | 山东豪迈化工技术有限公司 | 一种连续氧化脱氢制备丙烯腈的方法 |
| JP7410397B2 (ja) * | 2020-03-27 | 2024-01-10 | 日本製鉄株式会社 | 芳香族化合物製造用触媒、芳香族化合物用触媒の製造方法、及び芳香族化合物の製造方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4658074A (en) * | 1965-05-28 | 1987-04-14 | Petro-Tex Chemical Corporation | Catalytic oxidative dehydrogenation process |
| US3644549A (en) * | 1970-09-09 | 1972-02-22 | Gulf Research Development Co | Dehydrogenation of ethylbenzene to styrene using so2 and ferrite catalysis in the form of spinels or perovskites |
| US3862910A (en) * | 1971-01-22 | 1975-01-28 | Phillips Petroleum Co | Oxidative dehydrogenation catalyst and process of preparation thereof |
| US3862997A (en) * | 1971-05-06 | 1975-01-28 | Phillips Petroleum Co | Oxidative dehydrogenation catalysts |
| US3810973A (en) * | 1973-01-12 | 1974-05-14 | Gen Electric | Method of preparing ferrites |
| US3929979A (en) * | 1974-09-10 | 1975-12-30 | Us Energy | Process for generating hydrogen |
| US3998757A (en) * | 1975-05-19 | 1976-12-21 | Petro-Tex Chemical Corporation | Lithium ferrite oxidative dehydrogenation catalysts |
| FR2411169A1 (fr) * | 1977-12-12 | 1979-07-06 | Shell France | Procede de deshydrogenation sans oxydation et composition catalytique pour la mise en oeuvre de ce procede |
| FR2497192A1 (fr) * | 1980-12-29 | 1982-07-02 | Shell France | Procede de deshydrogenation non oxydante |
| JPS58177148A (ja) * | 1982-04-13 | 1983-10-17 | Mitsubishi Petrochem Co Ltd | スチレン製造用触媒 |
| US4480051A (en) * | 1983-08-03 | 1984-10-30 | E. I. Du Pont De Nemours And Company | Activated iron hydrogenation catalyst |
| DE3417793A1 (de) * | 1984-05-14 | 1985-11-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung feinteiliger, nadelfoermiger und hochkoerzitiver hexagonaler ferrite sowie ihre verwendung zur herstellung magnetischer aufzeichnungstraeger und plastoferrite |
| US4565899A (en) * | 1984-12-14 | 1986-01-21 | Mobil Oil Corporation | Iron oxide catalysts containing copper and zinc compounds and process for para-ethyltoluene dehydrogenation |
| US4684619A (en) * | 1985-02-20 | 1987-08-04 | The Dow Chemical Company | Process for making a dehydrogenation catalyst having improved moisture stability |
-
1988
- 1988-04-29 FR FR8805764A patent/FR2630662A1/fr active Pending
-
1989
- 1989-04-10 DE DE8989200902T patent/DE68904682T2/de not_active Expired - Lifetime
- 1989-04-10 EP EP89200902A patent/EP0339704B1/en not_active Expired - Lifetime
- 1989-04-10 ES ES89200902T patent/ES2053948T3/es not_active Expired - Lifetime
- 1989-04-19 CA CA000597093A patent/CA1335729C/en not_active Expired - Fee Related
- 1989-04-26 US US07/343,228 patent/US4975407A/en not_active Expired - Lifetime
- 1989-04-27 KR KR1019890005582A patent/KR0130067B1/ko not_active IP Right Cessation
- 1989-04-27 BR BR898901978A patent/BR8901978A/pt not_active IP Right Cessation
- 1989-04-27 AU AU33781/89A patent/AU612022B2/en not_active Expired
- 1989-04-27 CN CN89102963A patent/CN1023883C/zh not_active Expired - Lifetime
- 1989-04-27 ZA ZA893126A patent/ZA893126B/xx unknown
- 1989-04-27 JP JP1106111A patent/JP2729831B2/ja not_active Expired - Lifetime
-
1990
- 1990-04-11 SA SA90100156A patent/SA90100156B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SA90100156B1 (ar) | 2002-05-29 |
| FR2630662A1 (fr) | 1989-11-03 |
| BR8901978A (pt) | 1989-12-05 |
| DE68904682D1 (de) | 1993-03-18 |
| AU612022B2 (en) | 1991-06-27 |
| CN1037282A (zh) | 1989-11-22 |
| ZA893126B (en) | 1989-12-27 |
| US4975407A (en) | 1990-12-04 |
| AU3378189A (en) | 1989-11-02 |
| KR0130067B1 (ko) | 1998-04-06 |
| EP0339704B1 (en) | 1993-02-03 |
| DE68904682T2 (de) | 1993-05-19 |
| ES2053948T3 (es) | 1994-08-01 |
| JP2729831B2 (ja) | 1998-03-18 |
| CN1023883C (zh) | 1994-03-02 |
| CA1335729C (en) | 1995-05-30 |
| JPH0221945A (ja) | 1990-01-24 |
| EP0339704A1 (en) | 1989-11-02 |
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