KR900014465A - 변형 폴리아미드 구성된 대형 성형품의 제조방법 - Google Patents
변형 폴리아미드 구성된 대형 성형품의 제조방법 Download PDFInfo
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- KR900014465A KR900014465A KR1019900004352A KR900004352A KR900014465A KR 900014465 A KR900014465 A KR 900014465A KR 1019900004352 A KR1019900004352 A KR 1019900004352A KR 900004352 A KR900004352 A KR 900004352A KR 900014465 A KR900014465 A KR 900014465A
- Authority
- KR
- South Korea
- Prior art keywords
- polyisocyanate
- amount
- polyoxyalkylene
- polyamine
- modulus
- Prior art date
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- 239000004952 Polyamide Substances 0.000 title claims 3
- 229920002647 polyamide Polymers 0.000 title claims 3
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 238000000034 method Methods 0.000 claims 8
- 239000005056 polyisocyanate Substances 0.000 claims 7
- 229920001228 polyisocyanate Polymers 0.000 claims 7
- 229920000768 polyamine Polymers 0.000 claims 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical group O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- 238000006116 polymerization reaction Methods 0.000 claims 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims 3
- 239000013543 active substance Substances 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- 150000001412 amines Chemical group 0.000 claims 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims 2
- 150000003951 lactams Chemical class 0.000 claims 2
- 239000012744 reinforcing agent Substances 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims 1
- -1 HDI isocyanate Chemical class 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000012190 activator Substances 0.000 claims 1
- YDLSUFFXJYEVHW-UHFFFAOYSA-N azonan-2-one Chemical group O=C1CCCCCCCN1 YDLSUFFXJYEVHW-UHFFFAOYSA-N 0.000 claims 1
- 238000005452 bending Methods 0.000 claims 1
- 239000004917 carbon fiber Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 239000003365 glass fiber Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 159000000001 potassium salts Chemical class 0.000 claims 1
- 238000001175 rotational moulding Methods 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
- 239000004416 thermosoftening plastic Substances 0.000 claims 1
- 229940098465 tincture Drugs 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/04—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8074—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/02—Polyureas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/56—Processes of molding lactams
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/61—Processes of molding polyamide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Ceramic Capacitors (AREA)
- Forging (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (20)
- 주조 기술 또는 회전 성형기술에 따라, 폴리아미드에 대응하는 ω-락탐 외에도, a) ω-락탐의 나트륨 및 칼륨염 및 관련 혼합물로 부터 선택한 중합촉매, b) 400-5000의 분자량 및 1.9∼2.5의 실질적인 범위의 아민 관능성을 갖는 탄성화제로서의 폴리옥시알킬렌-폴리아민, c) 락탐으로 모두 블록된 이소시아네이트기를 갖는 폴리이소시아네이트로 구성된 활성제를 포함하는 혼합물을, 상기 시료를 130∼170℃, 바람직하게는 130∼160℃의 온도로 가열한 주형에 105∼125℃의 온도에서 공급하여 중합시킴을 특징으로 하는 변형 폴리아미드로 구성된 대형 성형품 제조방법.
- 제1항에 있어서, 중합 반응전에 한 탱크는 1부의 ω-락탐과 촉매 (a)를 포함하고, 다른 팅크는 잔존량의 카프롤락탐과 활성제 (c)를 함께 포함하도록 하여 시료를 두 개의 구별되는 공급탱크에 분배함을 특징으로 하는 방법.
- 제2항에 있어서, 폴리옥시알킬렌-폴리아민을 촉매를 포함하는 탱크 및 활성제를 포함하는 탱크로부터 선택된 공급탱크 중에 첨가함을 특징으로 하는 방법.
- 제2항에 있어서, 폴리옥시알킬렌-폴리아민을 두공급 탱크중에 분배함을 특징으로 하는 방법.
- 제1 내지 4항중 어느 한 항에 있어서, ω-락탐은 ω-카플롤락탐, ω-라우릴-락탐 및 그의 혼합물로부터 선택함을 특징으로 하는 방법.
- 제4항에 있어서, 폴리옥시알킬렌-폴리아민은 아민관능성이 실질적으로 2이고 분자량이 400∼4,000인 폴리옥시프로필렌-다아민이며, 상기 디아민의 양은 총 시료양에 대하여 1∼60중량%, 바람직하게는 3∼40중량%(더욱 바람직하게는 5∼25중량%)임을 특징으로 하는 방법.
- 제1 내지 6항중 어느 한 항에 있어서, 촉매(a)량은 전환될 락탐 100몰당 0.10∼2(바람직하게는 0.5∼1.5)당량임을 특징으로 하는 방법.
- 제1 내지 7항중 어느 한 항에 있어서, 폴리이소시아네이트는 헥사메틸렌-디이소시아네이트(HDI), 톨루엔-디이소시아네이트(TDI), 메틸렌-비스(페닐 이소시아네이트)(MDI), 비우레트화된 HDI, HDI이소시아누레이트, 부분적으로 비우레트화된 TDI, 부분적으로 비우레트화된 MDI 및 대응 혼합물로부터 선택함을 특징으로하는 방법.
- 제8항에 있어서, 폴리 이소시아네이트는 HDI이소시아네이트임을 특징으로 하는 방법.
- 제1내지 제9항중 어느 한 항에 있어서, 블록된(NCO)기를 갖는 폴리 이소시아네이트의 양은 중합할 ω-락탐 100몰당 0.2∼15(바람직하게는 1∼10)당량이고, 대응하여 당량비는 0.002∼0.15이고 바람직하게는 0.01∼0.10임을 특징으로 하는 방법.
- 제1항 내지 제10항중 어느 한 항에 있어서, 모두 블록된(NCO)기를 갖는 폴리이소시아네이트 및 유리(NH₂)기를 갖는 폴리옥시알킬렌 폴리아민의 양은 당량비가 1이상이고, 바람직하게는 1∼3이며, 더욱 바람직하게는 1.5∼2가 되도록 함을 특징으로 하는 방법.
- 제1 내지 11항중 어느 한 항에 있어서, (NMe)기 (식중 Me는 알칼리 이온임)를 갖는 알칼리 락타메이트의 양 및 모두 블록된(NCO)기를 갖는 폴리이소시아네이트의 양은 당량비가 1이상이고, 바람직하게는 1∼40이며, 더욱 바람직하게는 1.5∼15가 되도록 함을 특징으로 하는 방법.
- 제1내지 12항중 어느 한 항에 있어서, 당량비는 0.01이상이고, 바람직하게는 0.01∼20임을 특징으로 하는 방법.
- 제1 내지 13항중의 어느 한항에 있어서, 중합반응은 임의 크기의 보강제, 바람직하게는 유리섬유 또는 탄소섬유의 존재하에 수행함을 특징으로 하는 방법.
- 내부 및 외부가 균질이고, 탄성율이 200이상 및 바람직하게는 425J/m이상이고 및 굴곡 모둘러스가 1250MPa이상이며, 제1내지 14항중 어느 한 항의 방법에 따라 제조하며, 보강제를 임의로 함유하는 대형 성형품.
- 제15항에 있어서, 탄성율이 450J/m이상이고, 모둘러스는 1500MPa이상임을 특징으로 하는 제품.
- 제15항에 있어서, 탄성율이 500J/m이상이고, 모둘러스는 1270MPa이상임을 특징으로 하는 제품.
- 제15항 내지 제17항중 어느 한 항에 있어서, 황색지수가 -10이하이고, 바람직하게는 -15이하임을 특징으로 하는 제품.
- 제15내지 18항중 어느 한 항에 있어서, 열가소성 변형온도 (HDT)가 60℃이상임을 특징으로 하는 제품.
- 배, 자동차 및 조선소의 정착물 부위에서의 제15내지 19항중 어느 한 항에 따른 물품의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19972A/89 | 1989-03-31 | ||
| IT8919972A IT1229220B (it) | 1989-03-31 | 1989-03-31 | Processo per la produzione di articoli formati di grandi dimensioni, costituiti da poliammide modificata |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR900014465A true KR900014465A (ko) | 1990-10-24 |
Family
ID=11162754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900004352A KR900014465A (ko) | 1989-03-31 | 1990-03-30 | 변형 폴리아미드 구성된 대형 성형품의 제조방법 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5205975A (ko) |
| EP (1) | EP0390189B1 (ko) |
| JP (1) | JPH02286718A (ko) |
| KR (1) | KR900014465A (ko) |
| AT (1) | ATE114687T1 (ko) |
| AU (1) | AU633063B2 (ko) |
| BR (1) | BR9001486A (ko) |
| CA (1) | CA2013358A1 (ko) |
| DE (1) | DE69014374T2 (ko) |
| ES (1) | ES2065424T3 (ko) |
| IT (1) | IT1229220B (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100473165B1 (ko) * | 1996-01-25 | 2005-07-21 | 에엠에스-인벤타 아게 | 열적으로후성형될수있는폴리락탐매트릭스를포함하는복합재료의제조방법 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5254668A (en) * | 1992-06-29 | 1993-10-19 | Texaco Chemical Company | Polyamidopolyfunctional amine from lactam and ether amine |
| EP0618268A1 (en) * | 1993-04-02 | 1994-10-05 | ENICHEM S.p.A. | Thermoplastic composition based on polyphenylene ether and modified polyamide |
| DE19502085A1 (de) * | 1995-01-24 | 1996-07-25 | Bayer Ag | Hohlkörper mit mehrschichtigem Wandaufbau und Verfahren zu dessen Herstellung |
| EP1543995A1 (en) * | 2003-12-18 | 2005-06-22 | Ford Global Technologies, LLC | Method for making plastic products and product made by such a method |
| JP2007084747A (ja) * | 2005-09-26 | 2007-04-05 | Nippon Polypenco Ltd | 耐熱性及び寸法安定性モノマーキャストナイロン成形体 |
| DE102008000352A1 (de) * | 2008-02-20 | 2009-08-27 | Rhein Chemie Rheinau Gmbh | Gusspolyamid-Herstellung unter Verwendung spezieller Aktivatoren |
| EP2570448A1 (de) * | 2011-09-13 | 2013-03-20 | Basf Se | Verwendung von Polyethyleniminen in der Herstellung von Polyamiden |
| EP3320022B1 (de) * | 2015-07-06 | 2018-11-14 | Basf Se | Verfahren zur herstellung eines polyamids |
| JP6277575B1 (ja) * | 2017-07-03 | 2018-02-14 | 株式会社二幸技研 | アルカリ重合法によるナイロン製造方法と成型ナイロン |
| KR102275688B1 (ko) * | 2017-11-28 | 2021-07-12 | 한화솔루션 주식회사 | 말단 봉지재를 이용한 폴리아마이드의 제조 방법 및 이에 의해 제조된 폴리아마이드 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022719A (en) * | 1971-11-13 | 1977-05-10 | Bridgestone Tire Company Limited | Process for producing polyamide foam |
| DE2633560A1 (de) * | 1976-07-26 | 1978-02-09 | Elteka Kunststoff | Verfahren zur herstellung von gusskoerpern durch die aktivierte anionische polymerisation von lactamen |
| JPS6043369B2 (ja) * | 1982-03-04 | 1985-09-27 | 宇部興産株式会社 | 耐衝撃性ポリアミドの製法 |
| JPS6053536A (ja) * | 1983-09-01 | 1985-03-27 | Ube Ind Ltd | 耐衝撃性ポリアミドの製法 |
| US4617355A (en) * | 1984-06-21 | 1986-10-14 | Dsm Rim Nylon Vof | Cross-linked nylon block copolymers |
| US4582879A (en) * | 1984-03-22 | 1986-04-15 | Frisch Kurt C | Reaction injection molding process and reaction injection molded products |
| DE3521230A1 (de) * | 1984-06-14 | 1985-12-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von formkoerpern aus faserverstaerktem polyamid |
| JPS61106623A (ja) * | 1984-10-30 | 1986-05-24 | Ube Ind Ltd | ラクタム共重合体の製法 |
| DE3631842A1 (de) * | 1986-09-19 | 1988-03-24 | Basf Ag | Innere formtrennmittel, deren verwendung zur herstellung von formkoerpern nach dem polyisocyanat-polyadditionsverfahren und verfahren zur herstellung der formkoerper |
| US4732919A (en) * | 1986-11-06 | 1988-03-22 | Texaco Inc. | Reaction injection molded elastomer made from a quasi-prepolymer of a polyoxyalkylene polyamine and an aromatic isocyanate |
| EP0288067A1 (en) * | 1987-04-24 | 1988-10-26 | Asahi Glass Company Ltd. | Process for producing polyurethane elastomer and compositon as starting material therefor |
| IT1233835B (it) * | 1988-01-11 | 1992-04-21 | Montedipe Spa | Processo per la preparazione di poliammidi con migliorate proprieta' meccaniche e poliammidi cosi' ottenute. |
| IT1226388B (it) * | 1988-07-11 | 1991-01-15 | Montedipe Spa | Processo per la produzione di poliammidi modificate resistenti all'urto. |
| BG49760A1 (en) * | 1989-03-16 | 1992-02-14 | Vissh Khim T I | Copolyamides of cyclic lactames |
| JP3122536B2 (ja) * | 1992-08-03 | 2001-01-09 | シャープ株式会社 | 太陽電池モジュール |
-
1989
- 1989-03-31 IT IT8919972A patent/IT1229220B/it active
-
1990
- 1990-03-29 CA CA002013358A patent/CA2013358A1/en not_active Abandoned
- 1990-03-30 EP EP90106153A patent/EP0390189B1/en not_active Expired - Lifetime
- 1990-03-30 BR BR909001486A patent/BR9001486A/pt not_active Application Discontinuation
- 1990-03-30 US US07/501,477 patent/US5205975A/en not_active Expired - Fee Related
- 1990-03-30 KR KR1019900004352A patent/KR900014465A/ko not_active Application Discontinuation
- 1990-03-30 ES ES90106153T patent/ES2065424T3/es not_active Expired - Lifetime
- 1990-03-30 AU AU52471/90A patent/AU633063B2/en not_active Ceased
- 1990-03-30 AT AT90106153T patent/ATE114687T1/de not_active IP Right Cessation
- 1990-03-30 DE DE69014374T patent/DE69014374T2/de not_active Expired - Fee Related
- 1990-03-31 JP JP2087337A patent/JPH02286718A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100473165B1 (ko) * | 1996-01-25 | 2005-07-21 | 에엠에스-인벤타 아게 | 열적으로후성형될수있는폴리락탐매트릭스를포함하는복합재료의제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0390189A2 (en) | 1990-10-03 |
| BR9001486A (pt) | 1991-04-16 |
| AU633063B2 (en) | 1993-01-21 |
| ES2065424T3 (es) | 1995-02-16 |
| EP0390189A3 (en) | 1991-01-30 |
| DE69014374T2 (de) | 1995-05-04 |
| EP0390189B1 (en) | 1994-11-30 |
| US5205975A (en) | 1993-04-27 |
| AU5247190A (en) | 1990-10-04 |
| JPH02286718A (ja) | 1990-11-26 |
| IT1229220B (it) | 1991-07-26 |
| ATE114687T1 (de) | 1994-12-15 |
| CA2013358A1 (en) | 1990-09-30 |
| IT8919972A0 (it) | 1989-03-31 |
| DE69014374D1 (de) | 1995-01-12 |
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| A201 | Request for examination | ||
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| E601 | Decision to refuse application |