KR900014443A - 락톤 중합체로 변성된 염화비닐 중합체의 제조방법과 락톤 중합체로 변성된 새로운 염화비닐 중합체 - Google Patents

락톤 중합체로 변성된 염화비닐 중합체의 제조방법과 락톤 중합체로 변성된 새로운 염화비닐 중합체 Download PDF

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KR900014443A
KR900014443A KR1019900003265A KR900003265A KR900014443A KR 900014443 A KR900014443 A KR 900014443A KR 1019900003265 A KR1019900003265 A KR 1019900003265A KR 900003265 A KR900003265 A KR 900003265A KR 900014443 A KR900014443 A KR 900014443A
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South Korea
Prior art keywords
vinyl chloride
polymer
chloride polymer
lactone
modified
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KR1019900003265A
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English (en)
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KR0150791B1 (ko
Inventor
피에르 맬프로이드
퀴 롱 느구옌
니콜 드와엘
장-마리에 블론딘
장-폴 부르나이
Original Assignee
엘. 메이어스
솔베이 앤드 시에(소시에떼 아노님)
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Priority claimed from FR8903371A external-priority patent/FR2645159B1/fr
Priority claimed from BE8901305A external-priority patent/BE1003634A3/fr
Application filed by 엘. 메이어스, 솔베이 앤드 시에(소시에떼 아노님) filed Critical 엘. 메이어스
Publication of KR900014443A publication Critical patent/KR900014443A/ko
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Publication of KR0150791B1 publication Critical patent/KR0150791B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/682—Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

내용 없음

Description

락톤중합체로 변성된 염화비닐 중합체와 제조방법과 락톤 중합체로 변성된 새로운 염화비닐 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 첫 번째 단계에서, 락톤을 염화비닐에서 이온 방식에 의하여 중합하고, 두 번째 단계에서, 라디칼 방식에 의하여 중합될 수 있는 다른 에틸렌 불포화 단량체를 첨가하는 상기 염화 비닐을 현탁액에서와 첫 번째 단계에서 나온 중합 매체의 존재하에 라디칼 방식에 의하여 중합하는, 락톤 중합체로 변성된 염화비닐 중합체의 제조방법에서, 첫 번째 단계의 이온 촉매가 테트라하이드로푸란으로 착화되고, 물의 존재하에서 에틸렌 불포화 알코올과 알킬금속이 반응하는 생성물로 구성됨을 특징으로 하는 상기 제조방법.
  2. 제1항에 있어서, 알킬금속이 1-18개의 탄소원자를 함유하는 직쇄 또는 분지쇄 알킬을 함유하고 에틸렌 불포화 알코올을, 에틸렌 불포화가 쇄의 말단에 위치하고 3-20개의 탄소 원자를 갖는 1차, 2차 또는 3차 에틸렌 불포화 알코올에서 선택함을 특징으로 하는 변성 염화비닐 중합체의 제조방법.
  3. 제1항 또는 제2항에 있어서, 알킬금속이 2-5개의 탄소원자를 갖는 동일 알킬기로 이루어지고, 알킬금속의 알루미늄과/또는 아연에서 선택하고 에틸렌 불포화 알코올을, 에틸렌 불포화가 쇄의 말단에 위치하고 3-6개의 탄소원자를 갖는 에틸렌 일불포화 1차 알코올에서 선택함을 특징으로 하는 변성 염화비닐중합체의 제조방법.
  4. 제1항에 있어서, 0.1-0.3몰의 에틸렌 불포화 알코올과, 활성 금속의 그람-원자당 0.01-0.5몰의 물을, 0.1-20몰의 테트라하이드로푸란의 존재하에 반응시킴을 특징으로하는 변성 염화비닐 중합체의 제조방법.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 첫 번째 단계의 이온 촉매가 테트라하이드로푸란의 착화됨을 특징으로하는 변성 염화비닐 중합체의 제조방법.
  6. 제1항 내지 제4항중의 어느 한 항에 있어서, 첫 번째 단계의 이온 촉매가 테트라하이드로푸란으로 착화되지 않음을 특징으로 하는 변성 염화비닐 중합체의 제조방법.
  7. 제1항에 있어서, 촉매를 이온 방식에 의하여 중합될 수 있는 단량체의 몰당 0.001-0.1그람-원자의 활성 금속의 비율로 사용함을 특징으로하는 변성 염화비닐 중합체의 제조방법.
  8. 제7항에 있어서, 촉매 농도를 조절하여 수-평균 분자량이 10.000이하인 락톤 중합체를 생성시킴을 특징으로 하는 변성 염화비닐 중합체의 제조방법.
  9. 제1항에 있어서, 락톤이 ε-카프로락톤임을 특징으로 하는 변성염화 비닐 중합체의 제조방법.
  10. 제1항에 있어서, 두 번째 단계에서, 라디칼 방식에 의한 중합이 현탁액에서 일어남을 특징으로 하는 변성 염화 비닐 중합체의 제조 방법.
  11. 수-평균 분자량이 5,000이하이고, 염화 비닐중합체로 그래프트된 락톤 중합체로 구성됨을 특징으로하는 락톤 중합체로 변성된 염화비닐 중합체.
  12. 제11항에 있어서, 수-평균 분자량이 5,000이하이고, 염화비닐 중합체로 그래프트되고 그래프트도가 50%이상인 ε-카프로락톤 중합체로 구성됨을 특징으로 하는 변성 염화비닐 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900003265A 1989-03-13 1990-03-12 락톤 중합체로 변성된 염화비닐 중합체의 제조방법과 락톤 중합체로 변성된 새로운 염화비닐 중합체 KR0150791B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
FR89-03371 1989-03-13
FR8903371A FR2645159B1 (fr) 1989-03-13 1989-03-13 Procede pour la fabrication de polymeres du chlorure de vinyle modifies par des polymeres de lactones
FR89.03371 1989-03-13
BE8901305A BE1003634A3 (fr) 1989-12-06 1989-12-06 Procede pour la fabrication de polymeres du chlorure de vinyle modifies par des polymeres de lactones et nouveaux polymers du chlorure de vinyle modifies par des polymeres de lactones.
BE8901305 1989-12-06
BE89-01305 1989-12-06

Publications (2)

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KR900014443A true KR900014443A (ko) 1990-10-24
KR0150791B1 KR0150791B1 (ko) 1998-10-15

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KR1019900003265A KR0150791B1 (ko) 1989-03-13 1990-03-12 락톤 중합체로 변성된 염화비닐 중합체의 제조방법과 락톤 중합체로 변성된 새로운 염화비닐 중합체

Country Status (13)

Country Link
US (1) US5003038A (ko)
EP (1) EP0391455B1 (ko)
JP (2) JP2983571B2 (ko)
KR (1) KR0150791B1 (ko)
AT (1) ATE89841T1 (ko)
BR (1) BR9001135A (ko)
CA (1) CA2011092C (ko)
DE (1) DE69001706T2 (ko)
ES (1) ES2042196T3 (ko)
FI (1) FI100976B (ko)
HU (1) HU210265B (ko)
NO (1) NO177313C (ko)
PT (1) PT93382B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4111628A1 (de) * 1991-04-10 1992-10-15 Huels Chemische Werke Ag Innerlich weichgemachte vinylchloridpolymerisate und verfahren zu deren herstellung
US5314970A (en) * 1993-01-07 1994-05-24 Elf Atochem North America, Inc. OO-t-alkyl O-polycaprolactone monoperoxycarbonates
US5290660A (en) * 1993-04-23 1994-03-01 Minnesota Mining And Manufacturing Company Dye permeable polymer interlayers
JP4654601B2 (ja) * 2004-05-14 2011-03-23 富士ゼロックス株式会社 樹脂粒子及びその製造方法、静電荷現像用トナー及びその製造方法、静電荷像現像剤並びに画像形成方法。

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2604178B1 (fr) * 1986-09-18 1988-11-18 Solvay Procede pour la fabrication de polymeres d'halogenures de vinyle modifies par des polymeres de composes heterocycliques oxygenes

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Publication number Publication date
FI100976B (fi) 1998-03-31
CA2011092C (fr) 2000-06-06
PT93382A (pt) 1990-11-07
PT93382B (pt) 1996-03-29
JPH11263817A (ja) 1999-09-28
US5003038A (en) 1991-03-26
DE69001706T2 (de) 1993-12-23
EP0391455B1 (fr) 1993-05-26
JPH02284907A (ja) 1990-11-22
JP2983571B2 (ja) 1999-11-29
HU901409D0 (en) 1990-06-28
EP0391455A1 (fr) 1990-10-10
KR0150791B1 (ko) 1998-10-15
ES2042196T3 (es) 1993-12-01
ATE89841T1 (de) 1993-06-15
BR9001135A (pt) 1991-03-05
NO901137D0 (no) 1990-03-12
CA2011092A1 (fr) 1990-09-13
FI901244A0 (fi) 1990-03-13
HUT53136A (en) 1990-09-28
NO177313B (no) 1995-05-15
DE69001706D1 (de) 1993-07-01
NO901137L (no) 1990-09-14
HU210265B (en) 1995-03-28
NO177313C (no) 1995-08-23

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