KR900006499A - 액상 세탁제에서 부분 에스테르화 공중합체의 용도 - Google Patents

액상 세탁제에서 부분 에스테르화 공중합체의 용도 Download PDF

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KR900006499A
KR900006499A KR1019890015678A KR890015678A KR900006499A KR 900006499 A KR900006499 A KR 900006499A KR 1019890015678 A KR1019890015678 A KR 1019890015678A KR 890015678 A KR890015678 A KR 890015678A KR 900006499 A KR900006499 A KR 900006499A
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South Korea
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copolymer
partially esterified
molar ratio
olefin
esterified
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KR1019890015678A
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KR970001226B1 (ko
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디이셀 파울
페르너 요한네스
덴찡어 발터
하르트만 하인리히
라우벤하임머 한스-위르겐
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하우프터.라이싱어
바스프 악티엔게젤샤프트
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Publication of KR900006499A publication Critical patent/KR900006499A/ko
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

액상 세탁제에서 부분 에스테르화 공중합체의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 주성분으로서, (1) 1종이상의 음이온성 계면활성제, 1종 이상의 비이온성 계면활성제, 또는 이들의 혼합물, (2) (a) 1종 이상의 C4-C28-올레핀 또는 1종 이상의 C4-C28-올레핀과 20몰%이하의 C1-C4-알킬 비닐 에테르의 혼합물과 (b) 에틸렌계 불포화된 탄소수 4 내지 8의 디카르복실산 무수물을 몰비율 1:1로 공중합하여 K=6 내지 100(1중량%의 중합체 및 25℃, 테트라히드로푸란 중에서 H.Fikentscher의 방법으로 측정)인 공중합체를 수득한후, 상기 공중합체를 (A) C1-C30-알코올, C8-C22-지방산, C1-C12-알킬페놀, 2차 C2-C30-아민 또는 이들의 혼합물을 (B) 1종 이상의 C2-C4-알킬렌 옥시드 또는 테트라히드로 푸란과 (A) : (B)의 몰비 1 : 2 내지 1 : 50으로 반응시켜 생성된 반응 생성물로 공중합체의 카르복실기의 5-50%이상이 전환될때까지 부분에스테르화시키고 공중합체의 무수물기를 카르복실기로 가수분해 시킴으로써 수득가능한 부분 에스테르화 공중합체 0.1-20중량%, 및 (3) 물을 함유함을 특징으로 하는, 액상 알칼리성 세탁제제.
  2. 제1항에 있어서, 부분 에스테르화 공중합체가 먼저 (a) 측쇄 C6-C18-올레핀 또는 측쇄 C6-C18-올레핀 혼합물과 (b) 말레산 무수물 또는 이타콘산 무수물을 공중합시켜 생성된 공중합체를 (A) C1-C30-알코올, C8-C18-지방산, C1-C12-알킬페놀 또는 2차 C2-C30-아민과 (B) 에틸렌 옥시드 또는 프로필렌 옥시드((A) : (B)몰비 1 : 2 내지 1 : 50)의 반응 생성물로 공중합체의 카르복실기 9-30%가 에스테르화될 때까지 부분 에스테르화 시킴으로써 제조되는, 액상 알칼리성 세탁제제.
  3. 제1항에 있어서, 부분 에스테르화 공중합체가 (a) 성분으로서 2,4,4'-트리메틸-1-펜텐과 2,4,4'-트리메틸-2-펜텐의 혼합물 및 (b) 또다른 성분으로서 말레산 무수물을 사용하여 제조되는, 액상 알칼리성 세탁제제.
  4. 제1항에 있어서, 부분에스테르화 공중합체가 (a) 1종 이상의 C1-C30-알코올 또는 2차 C2-C30-아민과 (B) 에틸렌 옥시드 또는 에틸렌 옥시드 및 프로필렌 옥시드의 반응생성물로 부분 에스테르화 됨으로서 수득가능한, 액상 알칼리성 세탁제제.
  5. 제1항에 있어서, 부분 에스테르화 공중합체가 (a) 1종 이상의 C4-C28-올레핀 또는 1종 이상의 C4-C28-올레핀과 20몰%이하의 C1-C28-알킬 비닐 에테르의 혼합물을 (b)(b1)에틸렌계 불포화된 탄소수 4 내지 8의 디카르복실산무수물과 (b2)(A) C1-C30-알코올, C8-C22-지방산, C1-C12-알킬페놀 또는 2차 C2-C30-아민과 (B) 1종이상의 C2-C4-알킬렌 옥시드 도는 테트라히드로 푸란((A) : (B)의 몰비 = 1 : 2 내지 1 : 50)의 반응 생성물(무수물기의 5내지 50%가 에스테르화됨)을 반응시켜 생성된 반응 생성물과 (a) : (b)의 몰비 1 : 1로 공중합시켜 K=6 내지 100인 공중합체를 수득하고 공중합체의 미전환 무수물기를 카르복실기 또는 그의 염으로 가수분해함으로써 수득가능한, 액상 알칼리성 세탁제제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890015678A 1988-10-31 1989-10-31 액체 알칼리성 세정 제제 KR970001226B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3837013.1 1988-10-31
DE3837013A DE3837013A1 (de) 1988-10-31 1988-10-31 Verwendung von partiell veresterten copolymerisaten in fluessigwaschmitteln

Publications (2)

Publication Number Publication Date
KR900006499A true KR900006499A (ko) 1990-05-08
KR970001226B1 KR970001226B1 (ko) 1997-02-04

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KR1019890015678A KR970001226B1 (ko) 1988-10-31 1989-10-31 액체 알칼리성 세정 제제

Country Status (9)

Country Link
US (1) US5008032A (ko)
EP (1) EP0367049B1 (ko)
JP (1) JP2636938B2 (ko)
KR (1) KR970001226B1 (ko)
AT (1) ATE101192T1 (ko)
AU (1) AU617888B2 (ko)
CA (1) CA2000731A1 (ko)
DE (2) DE3837013A1 (ko)
ES (1) ES2048810T3 (ko)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5205960A (en) * 1987-12-09 1993-04-27 S. C. Johnson & Son, Inc. Method of making clear, stable prespotter laundry detergent
DE4116807A1 (de) * 1991-05-23 1992-11-26 Henkel Kgaa Konzentriertes waessriges fluessigwaschmittel
DE4300239A1 (de) * 1993-01-07 1994-07-14 Basf Ag Verwendung von partiell veresterten Carboxylgruppen enthaltenden Copolymerisaten als Dispergiermittel
SK53294A3 (en) * 1993-05-07 1995-04-12 Albright & Wilson Concentrated aqueous mixture containing surface active matter and its use
US6090762A (en) * 1993-05-07 2000-07-18 Albright & Wilson Uk Limited Aqueous based surfactant compositions
US5486307A (en) * 1993-11-22 1996-01-23 Colgate-Palmolive Co. Liquid cleaning compositions with grease release agent
US5573702A (en) * 1993-11-22 1996-11-12 Colgate-Palmolive Co. Liquid cleaning compositions with grease release agent
DE19755295A1 (de) * 1997-12-12 1999-06-17 Agfa Gevaert Ag Entwickler für bestrahlte, strahlungsempfindliche Aufzeichnungsmaterialien
US5962400A (en) * 1998-12-22 1999-10-05 National Starch And Chemical Investment Holding Corporation Amino acid copolymers having pendent polysaccharide moieties and uses thereof
DE19904513A1 (de) 1999-02-04 2000-08-10 Cognis Deutschland Gmbh Detergensgemische
US6498136B2 (en) 1999-03-23 2002-12-24 National Starch And Chemical Investment Holding Corporation Polymer having a hydrophilic backbone and hydrophobic moieties as soil suspending agent in powder detergents
US6458752B1 (en) 1999-03-23 2002-10-01 National Starch And Chemical Investment Holding Corporation Powder laundry detergent having enhanced soils suspending properties
DE59912559D1 (de) 1999-07-02 2005-10-20 Cognis Ip Man Gmbh Mikrokapseln - III
ATE304343T1 (de) 1999-07-02 2005-09-15 Cognis Ip Man Gmbh Mikrokapseln - iv
ES2213948T3 (es) 1999-07-02 2004-09-01 Cognis Iberia, S.L. Microcapsulas ii.
ATE258417T1 (de) 1999-07-02 2004-02-15 Cognis Iberia Sl Mikrokapseln - i
DE19939538A1 (de) 1999-08-20 2001-02-22 Cognis Deutschland Gmbh Verzweigte, weitgehend ungesättigte Fettalkoholpolyglycolether
DE19939565A1 (de) 1999-08-20 2001-02-22 Cognis Deutschland Gmbh Verzweigte, weitgehend ungesättigte Fettalkoholsulfate
US6100016A (en) * 1999-09-14 2000-08-08 Agfa-Gevaert Ag Developer for irradiated, radiation-sensitive recording materials
DE10063762A1 (de) 2000-12-21 2002-06-27 Cognis Deutschland Gmbh Nichtionische Tenside
DE10104470A1 (de) * 2001-02-01 2002-08-08 Basf Ag Reinigerformulierungen zur Verhinderung der Verfärbung von Kunststoffgegenständen
US6331517B1 (en) * 2001-08-02 2001-12-18 Colgate Palmolive Co. Cleaning composition containing a hydrophilizing polymer
DE10156997A1 (de) * 2001-11-21 2003-08-14 Basf Ag Verwendung bestimmter Copolymere als Adjuvans und Mittel für den agrotechnischen Bereich
EP2553072B1 (en) 2010-04-01 2015-05-06 Unilever PLC Structuring detergent liquids with hydrogenated castor oil
EP2495300A1 (en) 2011-03-04 2012-09-05 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Structuring detergent liquids with hydrogenated castor oil
EP2476743B1 (en) 2011-04-04 2013-04-24 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Method of laundering fabric
WO2013139702A1 (en) 2012-03-21 2013-09-26 Unilever Plc Laundry detergent particles
WO2015113681A1 (de) * 2014-01-29 2015-08-06 Basf Se Polycarbonsäure-basierte additive für kraft und schmierstoffe
WO2016155993A1 (en) 2015-04-02 2016-10-06 Unilever Plc Composition
WO2017133879A1 (en) 2016-02-04 2017-08-10 Unilever Plc Detergent liquid
BR112018075521B1 (pt) 2016-06-09 2022-11-08 Unilever Ip Holdings B.V Combinação de reservatórios que proveem estoques multidose segregados de componentes para produtos para lavagem de roupas
EP3469048A1 (en) 2016-06-09 2019-04-17 Unilever PLC Laundry products
WO2018127390A1 (en) 2017-01-06 2018-07-12 Unilever N.V. Stain removing composition
EP3635166A1 (en) 2017-06-09 2020-04-15 Unilever PLC, a company registered in England and Wales under company no. 41424 Laundry liquid dispensing system
WO2019038186A1 (en) 2017-08-24 2019-02-28 Unilever Plc IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS
WO2019038187A1 (en) 2017-08-24 2019-02-28 Unilever Plc IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS
DE112018004365T5 (de) 2017-09-29 2020-09-24 Unilever N.V. Waschprodukte
CN216764833U (zh) 2017-10-05 2022-06-17 联合利华知识产权控股有限公司 储器的组合
DE102019007303A1 (de) * 2019-10-21 2021-04-22 Henkel Ag & Co. Kgaa Vergrauungsinhilbierende Waschmittel
DE102019007302A1 (de) * 2019-10-21 2021-04-22 Henkel Ag & Co. Kgaa Vergrauungsinhibierende Waschmittel

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA722623A (en) * 1963-10-21 1965-11-30 General Aniline And Film Corporation Stabilized liquid heavy duty detergent composition
GB1126479A (en) * 1966-07-08 1968-09-05 Diversey Ltd Improvements in and relating to detergent compositions
DE3305637A1 (de) * 1983-02-18 1984-08-23 Basf Ag, 6700 Ludwigshafen Copolymerisate, ihre herstellung und ihre verwendung als hilfsmittel in wasch- und reinigungsmitteln
GB2164339A (en) * 1984-09-11 1986-03-19 Ciba Geigy Ag Polymaleic anhydride derivatives
DE3514878A1 (de) * 1985-04-25 1986-11-06 Henkel KGaA, 4000 Düsseldorf Oelloesliche ester von copolymeren des maleinsaeureanhydrids
PH25826A (en) * 1986-03-14 1991-11-05 Johnson & Son Inc S C Prespotter laundry detergent
US4871823A (en) * 1987-09-11 1989-10-03 S. C. Johnson & Son, Inc. 1-Alkene/excess maleic anhydride polymers

Also Published As

Publication number Publication date
AU617888B2 (en) 1991-12-05
EP0367049A2 (de) 1990-05-09
EP0367049B1 (de) 1994-02-02
ATE101192T1 (de) 1994-02-15
EP0367049A3 (en) 1990-11-07
AU4384089A (en) 1990-05-03
JPH02170897A (ja) 1990-07-02
ES2048810T3 (es) 1994-04-01
DE58906888D1 (de) 1994-03-17
JP2636938B2 (ja) 1997-08-06
DE3837013A1 (de) 1990-05-03
KR970001226B1 (ko) 1997-02-04
US5008032A (en) 1991-04-16
CA2000731A1 (en) 1990-04-30

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