KR920016486A - 생분해성 삼원공중합체, 및 그를 함유하는 조성물 - Google Patents

생분해성 삼원공중합체, 및 그를 함유하는 조성물 Download PDF

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KR920016486A
KR920016486A KR1019920001177A KR920001177A KR920016486A KR 920016486 A KR920016486 A KR 920016486A KR 1019920001177 A KR1019920001177 A KR 1019920001177A KR 920001177 A KR920001177 A KR 920001177A KR 920016486 A KR920016486 A KR 920016486A
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monomer
mole percent
terpolymer
composition
polymerized units
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KR1019920001177A
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스위프트 그레이엄
와인스타인 배리
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원본미기재
롬 앤드 하스 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

생분해성 삼원 공중합체, 및 그를 함유하는 조성물.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

15-55 몰퍼센트의 비닐 아세테이트, 비닐 에테르 및 비닐 카보네이트로 구성된 군으로부터 선택된 최소한 하나의 제1단량체; 10-70몰프센트의 에틸렌계 볼포화 모노카르 복시산으로부터 선택된 최소한 하나의 제2단량체;및 15-55 몰퍼센트의 디카르복시산의무수물로부터 선택된 최소한 하나의 제3단량체를 중합단위들로서 함유하며, 중합동안 1몰퍼센트 이하의 단량체들이 가수분해되는 비수성 시스템내에서 형성된 삼원공중합체.
제1항에 있어서, 상기 삼원공중합체가 중합후 가수분해 반응처리된 것인 삼원공중합체.
제1항에 있어서, 상기 삼원공중합체가 증합후 비누화 반응 처리된 것인 삼원공중합체.
제1항에 있어서, 상기 삼원공중합체가 중합후 비누화 반응처리되고, 비누화 반응산물이 산화반응 처리된 것인 삼원공중합체.
제1항에 있어서, 25-50몰퍼센트의 상기 제1단량체; 15-30몰퍼센트의 상기 제2단량체; 및 20-50몰퍼센트의 상기 제3단량체를 중합 단위들로서 함유하는 삼원공중합체.
제1항에 있어서, 35-45몰퍼센트의 상기 제1단량체; 18-25 몰퍼센트의 상기 제2단량체; 및 35-45몰퍼센트의 상기 제3단량체를 중합 단위들로서 함유하는 삼원공중합체.
제1항에 있어서, 상기 제1단량체가 비닐 아세테이트이고, 상기 제2단량체가 아크릴산이며, 상기 제3단량체가 무수말레산인 삼원공중합체.
세제 증강제 또는 결각 방지제로서 작용하기에 유효한 양의 상기 청구범위1,2,3 또는 4항의 삼원 공중합체, 및 불황성 희석제를 함유하는 세척 조성물.
제8항에 있어서, 삼원공중합체가 세제 증강제이며 조성물의 1-50wt%의 양으로 존재하는 세척 조성물.
제8항에 있어서, 삼원공중합체가 결각 방지제이며, 조성물의 1-10wt%의 양으로 존재하는 세척 조성물.
제8항에 있어서, 상기 조성물이 액체이고 불활성 희석제가 물인 세척 조성물.
제8항에 있어서, 상기 조성물이 분말이고 불활성 황산나트륨, 염화나트륨 및 붕산나트륨으로 구성된 군으로부터 선택된 것인 세척 조성물.
세탁물 세제로서의 용도를 갖는 청구범위 8항의 세척 조성물.
경질 표면청정제로서의 용도를 갖는 청구범위 8항의 세척 조성물.
조성물 총중량을 기준으로 20-60%의 상기 청구범위 1,2,3또는 4항의 삼원공중합체, 및 불활성 희석제를 함유하는 물처리 조성물.
수성 시스템에서 분산제로서의 용도를 갖는 청구범위 15항의 조성물.
결각 방지제로서의 용도를 갖는 청구범위 15항의 조성물.
제15항에 있어서, 불활성 희석제가 물인 조성물.
수성 시스템에서 분산제로서의용도를 갖는 청구범위 1,2,3 또는 4항의 삼원공중합체.
결각방지제로서의 용도를 갖는 청구범위 1,2,3또는 4항의 삼원 공중합체.
15-55몰퍼센트의 제1단량체인 커텐;10-70몰퍼센트의 에틸렌계 불포화 모노카르복시산으로부터 선택된 최소한 하나의 제2단량체; 및 15-55몰퍼센트의 디카르복시산의 무수물로부터 선택된 최소한 하나의 제3단량체를 중합 단위들로서 함유하는 삼원공증합체.
제21항에 있어서, 25-50몰퍼센트의 상기 제1단량체; 15-30몰퍼센트의 상기 제2단량체; 및 20-50몰퍼센트의 상기 제3단량체를 중합 단위들로서 함유하는 삼원 공중합체.
제21항에 있어서, 35-45몰퍼센트의 상기 제1단량체;18-25몰퍼센트의 상기 제2단량체;및 35-45몰퍼센트의 상기 제3단량체를 중합 단위들로서 함유하는 삼원공중합체.
제21항에 있어서, 상기 제1단량체가 커텐이고, 상기 제2단량체가 아크릴산이며, 상기 제3단량체가 무수말레산인 삼원공중합체.
※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019920001177A 1991-02-01 1992-01-28 생분해성 삼원공중합체, 및 그를 함유하는 조성물 KR920016486A (ko)

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US649,631 1991-02-01
US07/649,631 US5191048A (en) 1991-02-01 1991-02-01 Biodegradable free-radical addition polymers

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US (1) US5191048A (ko)
EP (1) EP0497611B1 (ko)
JP (1) JP2675707B2 (ko)
KR (1) KR920016486A (ko)
AT (1) ATE161858T1 (ko)
AU (1) AU660166B2 (ko)
BR (1) BR9200257A (ko)
CA (1) CA2059675A1 (ko)
DE (1) DE69223819T2 (ko)
ES (1) ES2113409T3 (ko)
IE (1) IE920293A1 (ko)
MX (1) MX9200363A (ko)
NZ (1) NZ241462A (ko)
ZA (1) ZA92699B (ko)

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EP0497611B1 (en) 1998-01-07
ES2113409T3 (es) 1998-05-01
AU660166B2 (en) 1995-06-15
ZA92699B (en) 1992-09-30
AU1057892A (en) 1992-08-06
IE920293A1 (en) 1992-08-12
MX9200363A (es) 1992-08-01
BR9200257A (pt) 1992-10-06
EP0497611A1 (en) 1992-08-05
DE69223819T2 (de) 1998-08-06
JPH04311706A (ja) 1992-11-04
JP2675707B2 (ja) 1997-11-12
NZ241462A (en) 1994-02-25
DE69223819D1 (de) 1998-02-12
CA2059675A1 (en) 1992-08-02
ATE161858T1 (de) 1998-01-15
US5191048A (en) 1993-03-02

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