KR900006298A - 테트라히드로 피리미딘 화합물 및 그것의 제조방법 - Google Patents

테트라히드로 피리미딘 화합물 및 그것의 제조방법 Download PDF

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KR900006298A
KR900006298A KR1019890015332A KR890015332A KR900006298A KR 900006298 A KR900006298 A KR 900006298A KR 1019890015332 A KR1019890015332 A KR 1019890015332A KR 890015332 A KR890015332 A KR 890015332A KR 900006298 A KR900006298 A KR 900006298A
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compound
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salt
formula
chloro
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KR1019890015332A
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KR0135974B1 (ko
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히데키 우네메
이사오 미나미다
노리코 히구치
데쓰오 오카우치
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우메모토 요시마사
다케다 야쿠힝 코교 가부시기가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/06—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

내용 없음

Description

테트라히드로 피리미딘 화합물 및 그것의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 활성성분으로서 하기식 I의 테트라히드로 피리미딘 화합물 또는 그것의 염의 살균 유효량 및 농약허용담체를 포함하는 해충구제 조성물.
    (상기식에서, R1,R2,R3및 R4는 동일하거나 상이하며, 독립적으로 수소원자, 치환 가능한 탄화수소기 또는 치환가능한 헤테로시클릭기이며 X는 전자를 끄는 기이다.)
  2. 하기식 Ⅱ의 테트라히드로 피리미딘 화합물 또는 그것의 염.
    (상기식에서, R1a,R2,R3a및 R4는 동일하거나 상이하며, 독립적으로 수소원자, 치환가능한 탄화수소기 또는 치환가능한 헤테로시클릭기이이다; R1a및 R3a중 최소한 하나는 일반식-(CH2)n-R5식에서 R5는 치환가능한 헤테로시클릭시 또는 치환된 탄화수소기; n은 0 또는 1이다)기이고 X는 전자를 끄는 기이다.
  3. 제2항에 있어서, R5가 할로피리딜기 또는 할로티아졸릴기인 테트라히드로 피리미딘화합물 또는 그것의 염.
  4. 제2항에 있어서, 하기식 Ⅲ으로 표현되는 테트라히드로 피리미딘 화합물.
    상기식에서, R1d및 R3d중 하나는 R5b-CH2-(식에서, R5b는 할로피리딜 또는 할로티아졸릴기이다)이고 다른 하나는 H 또는 C1-C3알킬기, R2d는 H 또는 C1-C3알킬기 그리고 R4d는 C7-10아랄킬기이다.
  5. 제4항에 있어서, R1d가 6-브로모 또는 클로로-3-피리딜메틸, 2-클로로-5-티아졸릴 메틸 또는 C1-3알킬기인 화합물.
  6. 제4항에 있어서, R3d가 6-브로모 또는 클로로-3-피리딜 메틸기인 화합물.
  7. 제4항에 있어서, R1d가 3-피리딜 메틸기인 화합물.
  8. 제4항에 있어서, R1d가 메틸기인 화합물.
  9. 제4항에 있어서, R2d가 H인 화합물.
  10. 제4항에 있어서, R4d가 C7-10아릴킬기인 화합물.
  11. 제4항에 있어서, R3d또는 R4d가 메틸기인 화합물.
  12. 제4항에 있어서, R4d가 벤질기인 화합물.
  13. 제4항에 있어서, 1-벤질-3-(6-클로로-3-피리딜메틸)-4-메틸아미노-5-니트로-1,2,3,6-테트라히드로 피리미딘인 화합물.
  14. 제4항에 있어서, 1,3-디메틸-4-(2-클로로-5-티아졸릴메틸)아미노-5-니트로-1,2,3,6-테트라히드로피리미딘인 화합물.
  15. 제1항에 있어서, 상기 테트라히드로피리미딘 화합물 또는 염이 제2항 또는 제4항에 의한 화합물인 해충 구제 조성물.
  16. 일반식 V의 화합물 또는 그것의 염을 일반식 Ⅵ의 아민 또는 그것의 염 및 포름알데히드와 반응시킴으로써 일반식 Ⅵ의 테트라히드로피리미딘 화합물을 제조하는 방법.
    (상기식에서, R1a,R2,R3a및 R4및 X는 제2항에 정의한 것과 동일하다.)
  17. 일반식 Ⅷ의 화합물 또는 그것의 염을 일반식 Ⅸ의 아민 화합물 또는 그것의 염과 반응시킴으로써 일반식 Ⅶ의 테트라히드로피리미딘 화합물 또는 그것의 염을 제조하는 방법.
    상기식에서, R1a,R2,R3a및 R4및 X는 제2항에 정의한 것과 동일하고 R6는 저급알킬기이다).
  18. 해충을 구제하는 조성물의 제조에 있어서 제2항에 의한 화합물 또는 그것의 염의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890015332A 1988-10-26 1989-10-25 테트라히드로피리미딘 화합물, 이의 제조 방법 및 이를 함유하는 해충 방제 조성물 KR0135974B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP63-270064 1988-10-26
JP27006488 1988-10-26
JP18431289 1989-07-17
JP1-184312 1989-07-17

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KR900006298A true KR900006298A (ko) 1990-05-07
KR0135974B1 KR0135974B1 (ko) 1998-04-25

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US (1) US5084459A (ko)
EP (1) EP0366085B1 (ko)
KR (1) KR0135974B1 (ko)
CN (2) CN1031265C (ko)
AT (1) ATE136890T1 (ko)
BR (1) BR8905476A (ko)
CA (1) CA2001497A1 (ko)
DE (1) DE68926278T2 (ko)
ES (1) ES2085857T3 (ko)
HU (1) HU206953B (ko)
IE (1) IE73205B1 (ko)
IL (1) IL92065A0 (ko)
IN (1) IN170284B (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0407594A4 (en) * 1988-10-31 1991-09-25 Nippon Soda Co., Ltd. Novel tetrahydropyrimidine derivatives, process for their preparation and insecticides containing same as active ingredients
JP3023794B2 (ja) * 1989-05-17 2000-03-21 日本バイエルアグロケム株式会社 殺虫性ニトロ置換ヘテロ環式化合物
US5219869A (en) * 1989-05-17 1993-06-15 Nihon Bayer Agrochem K.K. Nitro-substituted heterocyclic compounds
US5180833A (en) * 1990-03-16 1993-01-19 Takeda Chemical Industries, Ltd. Process for the preparation of chlorothiazole derivatives
IE911168A1 (en) * 1990-04-13 1991-10-23 Takeda Chemical Industries Ltd Novel intermediates for preparing guanidine derivatives,¹their preparation and use
DE4204919A1 (de) * 1992-02-19 1993-08-26 Bayer Ag Verfahren zur herstellung von 2-chlor-5-alkylaminomethyl-pyridinen
DE4401635A1 (de) * 1994-01-21 1995-07-27 Bayer Ag Substituierte 1,2,3,4-Tetrahydro-5-nitro-pyrimidine
DE4423353A1 (de) * 1994-07-04 1996-01-11 Bayer Ag Verfahren zur Herstellung N-acylierter 2-Chlor-5-aminomethylpyridine
DE4437137A1 (de) * 1994-10-18 1996-04-25 Hoechst Schering Agrevo Gmbh Substituierte Cycloalkylamino- und -alkoxy-Heterocyclen, Verfahren zu ihrer Herstellung und ihre Verwendung als Schädlingsbekämpfungsmittel
EP0791583B1 (en) * 1995-09-08 2001-04-18 Nippon Soda Co., Ltd. Process for producing 3-(aminomethyl)-6-chloropyridines
KR200256816Y1 (ko) 2001-09-05 2001-12-24 유태우 손가락용 지압구
US7176268B2 (en) * 2003-12-05 2007-02-13 Bausch & Lomb Incorporated Prepolymers for improved surface modification of contact lenses
WO2010126580A1 (en) * 2009-04-27 2010-11-04 Dow Agrosciences, Llc Insecticidal pyridine compounds
CN102344439B (zh) * 2011-08-19 2014-04-09 上海师范大学 含氨基酸二元醇单酯的顺式烯啶虫胺类似物、其制备及应用
CN105820112A (zh) * 2016-06-06 2016-08-03 山东福尔有限公司 一种2-氯-5-三氟甲基吡啶的制备方法
ES2919280T3 (es) 2017-05-04 2022-07-22 Bayer Cropscience Ag Derivados de 2-{[2-(feniloximetil)piridin-5-il]oxi}-etanamina y compuestos relacionados como pesticidas, por ejemplo para la protección de plantas
CN116806837B (zh) * 2023-07-03 2024-01-23 山东福瑞达生物科技有限公司 四氢嘧啶在降低虫害对禾本科植物侵害上的应用

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Publication number Priority date Publication date Assignee Title
IL57416A (en) * 1978-05-30 1983-03-31 Smith Kline French Lab Nitro compounds,processes for preparing them and compositions containing them
DE3638121A1 (de) * 1986-05-30 1987-12-03 Bayer Ag 1,2,3,6-tetrahydro-5-nitro-pyrimidin-derivate
EP0407594A4 (en) * 1988-10-31 1991-09-25 Nippon Soda Co., Ltd. Novel tetrahydropyrimidine derivatives, process for their preparation and insecticides containing same as active ingredients
GB8908868D0 (en) * 1989-04-19 1989-06-07 Shell Int Research A process for the preparation of acyl ureas
JPH0317066A (ja) * 1989-06-14 1991-01-25 Nippon Tokushu Noyaku Seizo Kk ５―ニトロ―テトラヒドロピリミジン類及び農業用殺虫剤

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CN1102828A (zh) 1995-05-24
US5084459A (en) 1992-01-28
IN170284B (ko) 1992-03-07
IE73205B1 (en) 1997-05-07
DE68926278T2 (de) 1996-11-14
EP0366085A2 (en) 1990-05-02
HUT53489A (en) 1990-11-28
EP0366085A3 (en) 1990-11-28
HU895441D0 (en) 1990-01-28
EP0366085B1 (en) 1996-04-17
IL92065A0 (en) 1990-07-12
ES2085857T3 (es) 1996-06-16
CN1042149A (zh) 1990-05-16
CN1031265C (zh) 1996-03-13
BR8905476A (pt) 1990-05-29
KR0135974B1 (ko) 1998-04-25
CA2001497A1 (en) 1990-04-26
DE68926278D1 (de) 1996-05-23
HU206953B (en) 1993-03-01
IE893445L (en) 1990-04-26
ATE136890T1 (de) 1996-05-15

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