KR900001600A - 산화티탄 및 산화티탄 기재 물품의 제조방법 - Google Patents
산화티탄 및 산화티탄 기재 물품의 제조방법 Download PDFInfo
- Publication number
- KR900001600A KR900001600A KR1019890009312A KR890009312A KR900001600A KR 900001600 A KR900001600 A KR 900001600A KR 1019890009312 A KR1019890009312 A KR 1019890009312A KR 890009312 A KR890009312 A KR 890009312A KR 900001600 A KR900001600 A KR 900001600A
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- Prior art keywords
- diphosphonate
- acid
- titanium oxide
- titanium
- acids
- Prior art date
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 title claims 11
- 238000004519 manufacturing process Methods 0.000 title claims 4
- 238000000034 method Methods 0.000 claims 13
- 239000002253 acid Substances 0.000 claims 12
- 150000007513 acids Chemical class 0.000 claims 7
- 150000001875 compounds Chemical class 0.000 claims 7
- -1 for example Chemical class 0.000 claims 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 238000000465 moulding Methods 0.000 claims 4
- 150000003609 titanium compounds Chemical class 0.000 claims 4
- 125000003277 amino group Chemical group 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- 239000010936 titanium Substances 0.000 claims 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 235000001014 amino acid Nutrition 0.000 claims 2
- 229940024606 amino acid Drugs 0.000 claims 2
- 150000001413 amino acids Chemical class 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 230000007062 hydrolysis Effects 0.000 claims 2
- 238000006460 hydrolysis reaction Methods 0.000 claims 2
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 239000000047 product Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 claims 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims 1
- 239000004475 Arginine Substances 0.000 claims 1
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 claims 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- PMMYEEVYMWASQN-DMTCNVIQSA-N Hydroxyproline Chemical compound O[C@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-DMTCNVIQSA-N 0.000 claims 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 claims 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims 1
- ZDXPYRJPNDTMRX-VKHMYHEASA-N L-glutamine Chemical compound OC(=O)[C@@H](N)CCC(N)=O ZDXPYRJPNDTMRX-VKHMYHEASA-N 0.000 claims 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 claims 1
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 claims 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims 1
- 239000004472 Lysine Substances 0.000 claims 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 claims 1
- 239000004473 Threonine Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000004703 alkoxides Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 235000009582 asparagine Nutrition 0.000 claims 1
- 229960001230 asparagine Drugs 0.000 claims 1
- 235000003704 aspartic acid Nutrition 0.000 claims 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims 1
- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 claims 1
- XQRLCLUYWUNEEH-UHFFFAOYSA-L diphosphonate(2-) Chemical compound [O-]P(=O)OP([O-])=O XQRLCLUYWUNEEH-UHFFFAOYSA-L 0.000 claims 1
- PMMYEEVYMWASQN-UHFFFAOYSA-N dl-hydroxyproline Natural products OC1C[NH2+]C(C([O-])=O)C1 PMMYEEVYMWASQN-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 239000000174 gluconic acid Substances 0.000 claims 1
- 235000012208 gluconic acid Nutrition 0.000 claims 1
- 235000013922 glutamic acid Nutrition 0.000 claims 1
- 239000004220 glutamic acid Substances 0.000 claims 1
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 claims 1
- 235000004554 glutamine Nutrition 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229960002591 hydroxyproline Drugs 0.000 claims 1
- 239000001630 malic acid Substances 0.000 claims 1
- 235000011090 malic acid Nutrition 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- HJZKOAYDRQLPME-UHFFFAOYSA-N oxidronic acid Chemical compound OP(=O)(O)C(O)P(O)(O)=O HJZKOAYDRQLPME-UHFFFAOYSA-N 0.000 claims 1
- 229960004230 oxidronic acid Drugs 0.000 claims 1
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- FGMPLJWBKKVCDB-UHFFFAOYSA-N trans-L-hydroxy-proline Natural products ON1CCCC1C(O)=O FGMPLJWBKKVCDB-UHFFFAOYSA-N 0.000 claims 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical group [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
- C01G23/0536—Producing by wet processes, e.g. hydrolysing titanium salts by hydrolysing chloride-containing salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/21—Attrition-index or crushing strength of granulates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따라 수득환 산화티탄을 X선 회절법으로 분석한 스펙트럼.
Claims (16)
- 가수분해가 하나 이상의 카르복시기 및 하나 이상의 히드록시기 및/또는 아민기를 포함하는 산, 두 개 이상의 카르복시기 및 하나 이상의 히드록시기 및/또는 아민기를 포함하는 산 및 상기 산기의 염, 하기식의 유기인산을 포함하는 산으로 구성되는 군중에서 선택되는 하나 이상의 화합물(I)의 존재하에서 실시됨을 특징으로 하는, 티탄화합물을 가수분해한후 수득된 침전물을 회수하는 것으로 이루어지는 성형할 수 있는 산화티탄의 제조방법 :식중, n 및 m은 1 내지 6의 정수이며, p는 0 내지 5의 정수이며, R1, R2, R3는 동일 또는 상이하며, 히드록시기, 아미노기, 아랄킬기,아릴기, 알킬기 또는 수소를 나타낸다.
- 제1항에 있어서, 첨가된 산화합물이 치환되거나 되지 않는 탄화수소쇄로 된 화합물임을 특징으로 하는 제조방법.
- 제1항에 있어서, 산화합물이 지방족 탄화수소쇄로된 화합물임을 특징으로 하는 제조방법.
- 제2 또는 3항에 있어서, 탄화수소쇄가 1 내지 15탄소원자를 포함함을 특징으로 하는 제조방법.
- 제4항에 있어서, 탄화수소쇄가 1 내지 10탄소원자를 포함함을 특징으로 하는 제조방법.
- 제1 내지 5항중 어느 한항에 있어서, 첨가된 산화합물이 하기의 것을 포함하는 군중에서 선택됨을 특징으로 하는 제조방법 : -예를들어, 말산, 시트르산 및 타르트론산 같은 히드록시폴리카르복실산, 특히 히드록시디-또는 히드록시트리카르복실산, -예를들어, 글루코헵톤산 및 글루콘산 같은(폴리히드록시)모노카르복실산, -예를들어, 타르타르산 같은 폴리(히드록시카르복실)산, -예를들어, 아스파르트산, 아스파라긴, 글루탐산 및 글루타민 같은 디카르복실 아미노산 및 그에 상응하는 아미드, -예를들어, 리신, 세린, 티로신, 히드록시프롤린, 트레오닌 및 아르기닌 같은 수산화된 또는 되지 않은 모노카르복실 아미노산, -메틸렌 아미노트리포스포네이트, 메틸렌 에틸렌디아미노테트라포스포네이트, 메틸렌 트리에틸렌테르라아미노헥사포스포네이트, 메틸렌 테트라에틸렌펜타아미노헵타포스포네이트, 메틸렌 펜타에틸렌헥사-아미노옥타포스포네이트, -메틸렌, 1,1'-에틸렌, 1,2-에틸렌, 1,1'프로필렌, 1,3-프로필렌, 1,6-헥사메틸렌 디포스포네이트, 2,4-디히드록시펜타메틸렌-2,4-디포스포네이트, 2,5-디히드록시헥사메틸렌-2,5-디포스포네이트; 2,3-디히드록시부틸렌-2,3-디포스포네이트 ; 1-히드록시벤질-1,1'-디포스포네이트 ; 1-아미노에틸렌-1,1'-디포스포네이트 ; 히드록시메틸렌 디포스포네이트 ; 1-히드록시에틸렌-1,1'디포스포네이트 ; 1-히드록시프로필렌-1,1'-디포스포네이트;1-히드록시부틸렌-1,1'--디포스포네이트; 1-히드록시헥사메틸렌-1,1'-디포스포네이트.
- 제1 내지 6항중 어느 한항에 있어서, 티탄화합물이 티탄할로겐화물, 옥시할로겐화물, 질산염 및 알콕시화물을 포함하는 군중에서 선택됨을 특징으로 하는 제조방법.
- 제7항에 있어서, 티탄화합물이 티탄옥시클로라이드임을 특징으로 하는 제조방법.
- 제1 내지 8항중 어느 한 항에 있어서, 가수분해되는 용액이 티탄으로 표현해서 0.1 내지 1.5몰/l의 티탄화합물을 포함함을 특징으로 하는 제조방법.
- 제1 내지 9항중 어느 한 항에 있어서, 가수분해되는 용액의 산화합물의 몰농도가 0.01 내지 1몰/l, 바람직하게는 0.01 내지 0.1몰/l임을 특징으로 하는 제조방법.
- 제1 내지 10항중 어느 한항에 있어서, 가수분해는 70℃ 이상이 온도에서 실시됨을 특징으로 하는 제조방법.
- 1 내지 50%의 강열감량을 갖는 20nm를 상회하는 크기로 원소입자로 구성되고, 미약하게 결정화된 산화티탄을 수득하기 이한 제1 내지 11항중 어느 한항에 기재된 방법에 따라 분리된 형으로 수득된 산화티탄을 건조하고, 1 내지 50중량%의 첨가된 물, 0 내지 15중량%의 성형 첨가제 및 45 내지 99중량%의 건조된 산화티탄을 포함하는 혼합물을 제조하고, 상기 혼합물을 성형한 후, 경우에 따라서 수득된 산물을 건조 및 소성하는 것으로 이루어짐을 특징으로 하는 분리된 산물을 성형하는 것에 의한 산화티탄 기재 물품의 제조방법.
- 제12항에 있어서, 산화티탄이 30 내지 70nm의 평균 크기의 원소입자로 구성됨을 특징으로 하는 산화티탄기재 물품의 제조방법.
- 제12 또는 13항에 있어서, 혼합물이 압출에 의해 성형됨을 특징으로 하는 산화티탄기재 물품의 제조방법.
- 제12 내지 14항중 어느 한항에 있어서, 성형되는 혼합물이 5 내지 35중량%의 첨가된 물, 0.1 내지 10중량%의 성형첨가제, 55 내지 94.9중량%의 불량한 결정화도를 갖고/갖거나 비정질인 산화티탄 분말을 포함함을 특징으로 하는 산화티탄기재 물품의 제조방법.
- 촉매 또는 촉매 지지체용으로 사용되는, 제12 내지 15중 어느 한항에 따라 수득한 물품의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR88/08911 | 1988-07-01 | ||
| FR8808911A FR2633605B1 (fr) | 1988-07-01 | 1988-07-01 | Procede de preparation d'oxyde de titane et d'articles a base d'oxyde de titane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR900001600A true KR900001600A (ko) | 1990-02-27 |
Family
ID=9367968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890009312A KR900001600A (ko) | 1988-07-01 | 1989-06-30 | 산화티탄 및 산화티탄 기재 물품의 제조방법 |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US5045301A (ko) |
| EP (1) | EP0351270B1 (ko) |
| JP (2) | JPH07110768B2 (ko) |
| KR (1) | KR900001600A (ko) |
| CN (1) | CN1039003A (ko) |
| AT (1) | ATE116270T1 (ko) |
| BR (1) | BR8903242A (ko) |
| CA (1) | CA1340268C (ko) |
| DE (1) | DE68920217T2 (ko) |
| ES (1) | ES2065405T3 (ko) |
| FR (1) | FR2633605B1 (ko) |
| GR (1) | GR3015219T3 (ko) |
| RU (1) | RU1806091C (ko) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW244350B (ko) * | 1991-12-14 | 1995-04-01 | Hoechst Ag | |
| DE4141936C2 (de) * | 1991-12-19 | 1993-10-28 | Metallgesellschaft Ag | Verfahren zur Herstellung von aus TiO¶2¶ bestehenden Pellets |
| US5362908A (en) * | 1993-03-10 | 1994-11-08 | Amoco Corporation | Catalyst and method for purifying crude terephthalic acid, isophthalic acid or naphthalene dicarboxylic acid |
| EP0649816B1 (en) * | 1993-10-22 | 1998-07-15 | Ishihara Sangyo Kaisha, Ltd. | Dendrite or asteroidal titanium dioxide micro-particles and process for producing the same |
| US5484757A (en) * | 1994-06-02 | 1996-01-16 | Norton Chemical Process Products Corp. | Titania-based catalyst carriers |
| DE69603580T2 (de) * | 1995-03-02 | 2000-05-04 | Univ Technologies Int | Photokatalysator und verfahren zur herstellung |
| FR2744914B1 (fr) * | 1996-02-15 | 1998-03-20 | Rhone Poulenc Chimie | Dispersion de dioxyde de titane, poudre a base de dioxyde de titane, leur utilisation dans les formulations cosmetiques |
| US6740312B2 (en) | 1996-02-15 | 2004-05-25 | Rhodia Chimie | Titanium dioxide particles |
| FR2750693B1 (fr) * | 1996-07-08 | 1998-10-16 | Rhone Poulenc Chimie | Dispersion de dioxyde de titane, poudre a base de dioxyde de titane, leur utilisation dans les formulations cosmetiques |
| CN1078181C (zh) * | 1997-11-14 | 2002-01-23 | 中国科学院化工冶金研究所 | 制备纳米级金红石型二氧化钛的方法 |
| FR2784605B1 (fr) * | 1998-10-20 | 2001-01-19 | Centre Nat Rech Scient | Materiau constitue par des particules metalliques et par des particules d'oxyde ultrafines |
| DE19923625A1 (de) * | 1999-05-22 | 2000-11-23 | Henkel Kgaa | Redispergierbare Metalloxide und -hydroxide mit Teilchengrößen im Nanometerbereich |
| DE10124600A1 (de) * | 2001-05-21 | 2002-11-28 | Basf Ag | Ni/Ti02-Hydrierkatalysator |
| EP1598324A1 (en) * | 2004-05-15 | 2005-11-23 | Osada Giken Co., Ltd. | Method for manufacturing shaped titanium oxide |
| US7144840B2 (en) * | 2004-07-22 | 2006-12-05 | Hong Kong University Of Science And Technology | TiO2 material and the coating methods thereof |
| US7326399B2 (en) * | 2005-04-15 | 2008-02-05 | Headwaters Technology Innovation, Llc | Titanium dioxide nanoparticles and nanoparticle suspensions and methods of making the same |
| FR2948748B1 (fr) | 2009-07-31 | 2011-07-22 | Rhodia Operations | Procede d'oxydo-reduction en boucle utilisant comme masse oxydo-reductrice une composition a base d'oxyde supporte de cerium ou de cerium, de zirconium et/ou de terre rare |
| CN102229619A (zh) * | 2011-04-26 | 2011-11-02 | 河南清水源科技股份有限公司 | 四乙烯五胺七亚甲基膦酸及其生产工艺 |
| CN110526288A (zh) * | 2014-07-02 | 2019-12-03 | 石原产业株式会社 | 氧化钛细粒及其制备方法 |
| WO2017009434A1 (en) * | 2015-07-14 | 2017-01-19 | Bp P.L.C. | Extruded titania-based materials comprising one or more acids or prepared using one or more acids |
| CN114105194B (zh) * | 2021-12-24 | 2023-10-24 | 济南裕兴化工有限责任公司 | 一种促进钛白晶型转化的方法 |
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|---|---|---|---|---|
| BE359277A (ko) * | ||||
| USRE21693E (en) * | 1941-01-14 | Preparation of pure titanium dioxide | ||
| BE424494A (ko) * | ||||
| US1914557A (en) * | 1929-02-04 | 1933-06-20 | Barrett Co | Catalyst and process of preparing the same |
| FR672002A (fr) * | 1928-03-27 | 1929-12-21 | Titanium Pigment Co Inc | Composés de titane et leur procédé de fabrication |
| GB481892A (en) * | 1936-09-18 | 1938-03-18 | Titan Co Inc | Improvements in and relating to the production of titanium dioxide pigments |
| US2113946A (en) * | 1936-11-06 | 1938-04-12 | Nat Lead Co | Preparation of pure titanium dioxide |
| FR828741A (fr) * | 1936-11-06 | 1938-05-27 | Titan Co Inc | Procédé de production de composés de titane |
| GB497694A (en) * | 1936-11-06 | 1938-12-23 | Titan Co Inc | Improvements in and relating to the decomposition of titanium salt solutions by hydrolytic precipitation |
| FR813757A (fr) * | 1936-11-19 | 1937-06-08 | Titan Co Inc | Procédé de fabrication de pigments à l'oxyde de titane et produits en résultant |
| US2290922A (en) * | 1940-04-06 | 1942-07-28 | Sherwin Williams Co | Preparation of titanium oxide |
| US2519389A (en) * | 1948-07-12 | 1950-08-22 | Max J Mayer | Seed for production of titanium dioxide and process of making same |
| DE1792798C3 (de) * | 1964-10-15 | 1978-09-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung leicht dispergierbarer Pigmente |
| DE2214775C3 (de) * | 1972-03-25 | 1975-08-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Polybutylenterephthalat |
| SU481633A1 (ru) * | 1973-05-08 | 1975-08-25 | Предприятие П/Я Г-4855 | Способ осветлени растворов серно кислого титана |
| SU662502A1 (ru) * | 1973-10-03 | 1979-05-15 | Zelentsov Vyacheslav V | Способ получени двуокиси титана |
| JPS5851909B2 (ja) * | 1975-07-31 | 1983-11-18 | 三菱化学株式会社 | 酸化チタン成型物の製造法 |
| GB1541928A (en) * | 1975-12-23 | 1979-03-14 | Sakai Chemical Industry Co | Production of shaped catalysts or carriers comprising titanium oxide |
| JPS5835932B2 (ja) * | 1976-09-22 | 1983-08-05 | ユ−オ−ピ−・インコ−ポレ−テツド | アルミナ押出し粒子の製造法 |
| JPS5813499B2 (ja) * | 1976-09-24 | 1983-03-14 | 石原産業株式会社 | 水和酸化チタンの製造方法 |
| SU715476A1 (ru) * | 1978-01-13 | 1980-02-15 | Предприятие П/Я Г-4855 | Способ получени стабильной зародышевой суспензии |
| FR2481145A1 (fr) * | 1980-04-23 | 1981-10-30 | Rhone Poulenc Ind | Procede de fabrication de catalyseurs ou de supports de catalyseurs faconnes a base d'oxyde de titane et leurs applications a la catalyse claus |
| JPS589873A (ja) * | 1981-07-09 | 1983-01-20 | 日本ニユクリア・フユエル株式会社 | セラミツク焼結体の製造方法 |
| JPS58117259A (ja) * | 1981-12-29 | 1983-07-12 | Toho Chem Ind Co Ltd | 酸化チタン系顔料 |
| FR2551743B1 (fr) * | 1983-09-14 | 1985-10-25 | Rhone Poulenc Spec Chim | Titanate d'alcalino-terreux, son procede de preparation et son application dans des compositions ceramiques |
| JPS6183603A (ja) * | 1984-09-07 | 1986-04-28 | Agency Of Ind Science & Technol | 非晶質複合金属酸化物の製造方法 |
| FR2585973A1 (fr) * | 1985-08-06 | 1987-02-13 | Centre Nat Rech Scient | Gel monolithique et poudre d'oxydes d'elements de transition, procede de fabrication du gel et procede de preparation de couches minces de ces oxydes |
| FR2593166A1 (fr) * | 1986-01-20 | 1987-07-24 | Solvay | Procede de fabrication d'une poudre d'oxyde metallique pour materiaux ceramiques et poudre de zircone obtenue par ce procede. |
| FR2623793B1 (fr) * | 1987-11-30 | 1991-06-07 | Rhone Poulenc Chimie | Procede de preparation de granules a base d'oxyde de titane, de zirconium, ou de cerium et produits ainsi obtenus |
| DE68917766T2 (de) * | 1988-03-30 | 1994-12-22 | Rhone Poulenc Chimie | Verfahren zur Herstellung von Titanoxid. |
-
1988
- 1988-07-01 FR FR8808911A patent/FR2633605B1/fr not_active Expired - Lifetime
-
1989
- 1989-06-26 DE DE68920217T patent/DE68920217T2/de not_active Expired - Fee Related
- 1989-06-26 EP EP89401799A patent/EP0351270B1/fr not_active Expired - Lifetime
- 1989-06-26 ES ES89401799T patent/ES2065405T3/es not_active Expired - Lifetime
- 1989-06-26 AT AT89401799T patent/ATE116270T1/de not_active IP Right Cessation
- 1989-06-30 US US07/373,450 patent/US5045301A/en not_active Expired - Lifetime
- 1989-06-30 BR BR898903242A patent/BR8903242A/pt unknown
- 1989-06-30 CA CA000604574A patent/CA1340268C/fr not_active Expired - Fee Related
- 1989-06-30 RU SU4614382A patent/RU1806091C/ru active
- 1989-06-30 CN CN89104395A patent/CN1039003A/zh active Pending
- 1989-06-30 KR KR1019890009312A patent/KR900001600A/ko not_active Application Discontinuation
- 1989-06-30 JP JP1167179A patent/JPH07110768B2/ja not_active Expired - Fee Related
-
1990
- 1990-09-04 US US07/577,130 patent/US5100858A/en not_active Expired - Lifetime
-
1995
- 1995-02-28 GR GR950400423T patent/GR3015219T3/el unknown
- 1995-05-01 JP JP7128788A patent/JP2655134B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07110768B2 (ja) | 1995-11-29 |
| RU1806091C (ru) | 1993-03-30 |
| US5100858A (en) | 1992-03-31 |
| CA1340268C (fr) | 1998-12-15 |
| EP0351270B1 (fr) | 1994-12-28 |
| JP2655134B2 (ja) | 1997-09-17 |
| BR8903242A (pt) | 1990-02-13 |
| DE68920217D1 (de) | 1995-02-09 |
| CN1039003A (zh) | 1990-01-24 |
| FR2633605A1 (fr) | 1990-01-05 |
| ES2065405T3 (es) | 1995-02-16 |
| JPH0255221A (ja) | 1990-02-23 |
| GR3015219T3 (en) | 1995-05-31 |
| DE68920217T2 (de) | 1995-05-24 |
| JPH08157217A (ja) | 1996-06-18 |
| ATE116270T1 (de) | 1995-01-15 |
| EP0351270A1 (fr) | 1990-01-17 |
| FR2633605B1 (fr) | 1991-07-12 |
| US5045301A (en) | 1991-09-03 |
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