KR900000298A - 옥소 합성의 생성물에서 로듐의 분리 및 회수하는 방법 - Google Patents

옥소 합성의 생성물에서 로듐의 분리 및 회수하는 방법 Download PDF

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KR900000298A
KR900000298A KR1019890007110A KR890007110A KR900000298A KR 900000298 A KR900000298 A KR 900000298A KR 1019890007110 A KR1019890007110 A KR 1019890007110A KR 890007110 A KR890007110 A KR 890007110A KR 900000298 A KR900000298 A KR 900000298A
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degrees
group
distillation residue
rhodium
represent
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KR1019890007110A
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KR910009582B1 (ko
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라페 페터
벡스텐 루드거
쿠피에스 디에터
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라이첼트, 콘골
훽스트 악티엔 게젤샤프트 베르크 루흐르 헤미에
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/381—Phosphines, e.g. compounds with the formula PRnH3-n, with n = 0-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Steroid Compounds (AREA)

Abstract

내용 없음

Description

옥소 합성의 생성물에서 로듐의 분리 및 회수하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 옥소합성 생성물의 증류잔사로부터 로듐을 분리 및 회수하는 방법에 있어서, 증류잔사를 먼저 산화제와 반응시킨 다음, 일산화탄소 또는 일산화탄소 분리 화합물 존재하에 로듐과 수용성착화합물을 형성하는 제제의 수용액과 반응시킴을 특징으로 하는 로듐의 분리 및 회수방법.
  2. 제1항에 있어서, 증류잔사를 산소 또는 산소 함유기체로 처리함을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 증류잔사물 20-200도, 특히 50-150도, 바람직하게는 80-120도에서 산하체로 처리함을 특징으로 하는 방법.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 산화제어 의한 처리가 0.1-5MPa 압력에서 일어남을 특징으로 하는 방법.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 착화제가 하기 일반식의 유기 포스핀임을 특징으로 하는 방법.
    (상기식에서 Ar1, Ar2, Ar3는 각각 페닐 또는 나프틸기이고 Y1, Y2, Y3는 각각 탄소원자수 1-4의 직쇄 또는 분지쇄 알콕쇄기, 탄소연자수 1-4의 직쇄 또는 분지쇄 알콕시기, 할로겐 원자 OH, CN, N02또는 R1R2N기
    (식중에서 R1과 R2는 각각 탄소원자수 1-4의 직쇄 또는 분지쇄 알킬기를 표시함)이며, X1, X2및 X3는 각각 카르복실레이드(COO-) 및/또는 술포네이트(SO3-)기이며, m1, m2, m3는 같거나 다른 0-3의 정수이고 적어도 하나의 숫자 m1, m2, 또는 m3는 1이상이며, n1, n2, n3는 0-5의 같거나 다른 정수이다.
  6. 제5항에 있어서, Ar1, Ar2, Ar3가 각각 페닐기를 표시하고, X1, X2, X3가 각각 술포네이트기를 표시하고 m1, m2, m3가 각각 또는 1의 수를 표시하고, m1, m2및 m3의 합이 1, 2 또는 3임을 특징으로 하는 방법.
  7. 제1항 내지 제6항중 어느 한 항에 있어서, 산화제로 처리한 증류잔사를 50-160도, 바람직하게는 90-130도 온도 및 10-40MPa, 바람직하게는 10-30MPa 입력에서 일산화탄소 및 수용성 착화합물 형성제제와 반응시킴을 특징으로 하는 방법.
  8. 제1항 내지 제7항중 어느 한 항에 있어서, 산화된 증류잔사를 50-160도, 바람직하게는 90-130도에서 일산화탄소 분리 화합물로서의 포름알데히드 및 수용성 착화합물 형성 제제로 처리함을 특징으로 하는 방법.
  9. 제8항에 있어서, 포름 알데히드를 수용액으로서 사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890007110A 1988-06-30 1989-05-27 옥소 합성의 생성물에서 모듐의 분리 및 회수하는 방법 KR910009582B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3822037A DE3822037A1 (de) 1988-06-30 1988-06-30 Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
DEP3822037.7 1988-06-30
DEP3822037,7 1988-06-30

Publications (2)

Publication Number Publication Date
KR900000298A true KR900000298A (ko) 1990-01-30
KR910009582B1 KR910009582B1 (ko) 1991-11-21

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KR1019890007110A KR910009582B1 (ko) 1988-06-30 1989-05-27 옥소 합성의 생성물에서 모듐의 분리 및 회수하는 방법

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Country Link
EP (1) EP0348833B1 (ko)
JP (1) JPH0725555B2 (ko)
KR (1) KR910009582B1 (ko)
AT (1) ATE79096T1 (ko)
AU (1) AU614634B2 (ko)
DE (2) DE3822037A1 (ko)
ES (1) ES2035447T3 (ko)
HU (1) HU202453B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010100200A (ko) * 2000-03-15 2001-11-14 김충경 필기용 지워지는 수성잉크

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3934824A1 (de) * 1989-10-19 1991-04-25 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese
DE4025074A1 (de) * 1990-08-08 1992-02-13 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese
DE4135049A1 (de) * 1991-10-24 1993-05-06 Hoechst Ag, 6230 Frankfurt, De Verfahren zur rueckgewinnung von rhodium aus den reaktionsprodukten der oxosynthese
DE4228724A1 (de) * 1992-08-28 1994-03-03 Hoechst Ag Verfahren zur Wiedergewinnung von Rhodium aus den Destillationsrückständen von Produkten der Oxosynthese
KR0134494B1 (ko) * 1993-10-20 1998-04-20 성재갑 하이드리도카르보닐트리스(트리오가노포스포러스)로듐의 제조방법
FR2765215B1 (fr) * 1997-06-27 1999-08-27 Rhodia Chimie Sa Procede de decoloration d'un produit, notamment d'une huile silicone, comprenant des residus catalytiques colores
DE10005084C1 (de) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Verfahren zur Wiedergewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
DE2448005C2 (de) * 1974-10-09 1983-10-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen
US4196096A (en) * 1979-02-12 1980-04-01 Eastman Kodak Company Process for regeneration of rhodium hydroformylation catalysts
JPS5850234B2 (ja) * 1980-10-23 1983-11-09 三菱化学株式会社 第８族貴金属固体錯体の取得方法
US4400547A (en) * 1981-04-10 1983-08-23 Eastman Kodak Company Hydroformylation process utilizing an unmodified rhodium catalyst and the stabilization and regeneration thereof
DE3347406A1 (de) * 1983-12-29 1985-07-11 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
DE3411034A1 (de) * 1984-03-26 1985-09-26 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
DE3443474A1 (de) * 1984-11-29 1986-05-28 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010100200A (ko) * 2000-03-15 2001-11-14 김충경 필기용 지워지는 수성잉크

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JPH0725555B2 (ja) 1995-03-22
ES2035447T3 (es) 1993-04-16
AU3716789A (en) 1990-01-04
HUT50729A (en) 1990-03-28
DE3822037A1 (de) 1990-01-04
EP0348833B1 (de) 1992-08-05
AU614634B2 (en) 1991-09-05
JPH0248419A (ja) 1990-02-19
DE58901976D1 (de) 1992-09-10
KR910009582B1 (ko) 1991-11-21
ATE79096T1 (de) 1992-08-15
HU202453B (en) 1991-03-28
EP0348833A3 (en) 1990-07-04
EP0348833A2 (de) 1990-01-03

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