KR890017171A - 과산화 수소의 제조방법 - Google Patents

과산화 수소의 제조방법 Download PDF

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Publication number
KR890017171A
KR890017171A KR1019890006445A KR890006445A KR890017171A KR 890017171 A KR890017171 A KR 890017171A KR 1019890006445 A KR1019890006445 A KR 1019890006445A KR 890006445 A KR890006445 A KR 890006445A KR 890017171 A KR890017171 A KR 890017171A
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KR
South Korea
Prior art keywords
platinum
palladium
catalyst
hydrogen peroxide
combining
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KR1019890006445A
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English (en)
Inventor
웨인 고서 로런스
터리서 슈워르츠 조앤
Original Assignee
제임즈 제이 플린
이 아이 듀우판 디 네모아 앤드 캄파니
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Application filed by 제임즈 제이 플린, 이 아이 듀우판 디 네모아 앤드 캄파니 filed Critical 제임즈 제이 플린
Publication of KR890017171A publication Critical patent/KR890017171A/ko

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01Hydrogen peroxide
    • C01B15/029Preparation from hydrogen and oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

과산화 수소의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 알루미나 지지체를 사용할때의 Pt/(Pt+Pd)에 대한 H2O2의 중량 퍼센트를 보여준다. 제 2 도는 탄소 지지체를 사용할때의 Pt/(Pt+Pd)에 대한 H2O2의 중량 퍼센트를 보여준다. 제 3 도는 실리카 지지체를 사용할 때의 Pt/(Pt+Pd)에 대한 H2O2중량%를 보여준다.

Claims (4)

  1. 백금 대(백금+팔라듐)의 중량비가 약 0.02 내지 약 0.2의 범위가 되는 양으로 백금과 팔라듐을 사용하는 것을 특징으로 하는, H+및 Br-또는 CI-이온과 백금/팔라듐을 조합한 촉매의 존재하에, 반응 매체의 2중량% 이상으로 존재하는 유기 성분을 갖지 않는 수성 반응 매체 내에서 수소와 산소를 직접 조합하여 과산화 수소를 제조하는 방법.
  2. 제 1 항에 있어서, 백금/팔라듐을 조합한 촉매가 탄소, 실리카 및 알루미나로 구성된 군으로 부터 선택되는 지지체상에 지지되는 방법.
  3. 제 2 항에 있어서, 촉매가 백금과 팔라듐을 포함하는 예비형성된 콜로이드를 지지체와 조합함으로써 제조하는 방법.
  4. 제 2 항에 있어서, 촉매가 콜로이드 실리카 및 백금 및 팔라듐 염을 포함하는 혼합물을 분무 건조시킴으로써 제조되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890006445A 1988-05-13 1989-05-13 과산화 수소의 제조방법 KR890017171A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US193843 1988-05-13
US07/193,843 US4832938A (en) 1988-05-13 1988-05-13 Hydrogen peroxide production method using platinum/palladium catalysts

Publications (1)

Publication Number Publication Date
KR890017171A true KR890017171A (ko) 1989-12-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890006445A KR890017171A (ko) 1988-05-13 1989-05-13 과산화 수소의 제조방법

Country Status (11)

Country Link
US (1) US4832938A (ko)
EP (1) EP0342048A3 (ko)
KR (1) KR890017171A (ko)
CN (1) CN1016959B (ko)
AR (1) AR246495A1 (ko)
AU (1) AU608976B2 (ko)
BR (1) BR8902234A (ko)
CA (1) CA1312720C (ko)
NZ (1) NZ229087A (ko)
PT (1) PT90542A (ko)
TR (1) TR24229A (ko)

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US6432376B1 (en) 2000-09-05 2002-08-13 Council Of Scientific & Industrial Research Membrane process for the production of hydrogen peroxide by non-hazardous direct oxidation of hydrogen by oxygen using a novel hydrophobic composite Pd-membrane catalyst
US6448199B1 (en) 2000-09-05 2002-09-10 Council Of Scientific & Industrial Research Hydrophobic composite Pd-membrane catalyst useful for non-hazardous direct oxidation of hydrogen by oxygen to hydrogen peroxide and method of its preparation
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Also Published As

Publication number Publication date
PT90542A (pt) 1989-11-30
US4832938A (en) 1989-05-23
AU3476089A (en) 1989-11-16
AR246495A1 (es) 1994-08-31
TR24229A (tr) 1991-07-03
AU608976B2 (en) 1991-04-18
NZ229087A (en) 1990-08-28
CA1312720C (en) 1993-01-19
EP0342048A3 (en) 1990-12-12
CN1016959B (zh) 1992-06-10
EP0342048A2 (en) 1989-11-15
BR8902234A (pt) 1990-01-09
CN1037874A (zh) 1989-12-13

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