KR890002358A - 개시제로서 이온 염료 화합물을 함유하는 방사선-경화성 잉크 및 피복조성물 - Google Patents

개시제로서 이온 염료 화합물을 함유하는 방사선-경화성 잉크 및 피복조성물 Download PDF

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KR890002358A
KR890002358A KR1019880009383A KR880009383A KR890002358A KR 890002358 A KR890002358 A KR 890002358A KR 1019880009383 A KR1019880009383 A KR 1019880009383A KR 880009383 A KR880009383 A KR 880009383A KR 890002358 A KR890002358 A KR 890002358A
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dye
compound
counterion
composition
reactive
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KR1019880009383A
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씨. 애드에어 폴
조셉 무어 마이클
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로라인 제이. 프란시스
더 미드 코포레이션
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Publication of KR890002358A publication Critical patent/KR890002358A/ko

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00—Diaryl- or thriarylmethane dyes
    • C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/10—Amino derivatives of triarylmethanes
    • C09B11/22—Amino derivatives of triarylmethanes containing OH groups bound to an aryl nucleus and their ethers and esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B17/00—Azine dyes
    • C09B17/02—Azine dyes of the benzene series
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B21/00—Thiazine dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/04—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups one >CH- group, e.g. cyanines, isocyanines, pseudocyanines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/06—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups three >CH- groups, e.g. carbocyanines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/08—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups more than three >CH- groups, e.g. polycarbocyanines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/08—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups more than three >CH- groups, e.g. polycarbocyanines
    • C09B23/086—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups more than three >CH- groups, e.g. polycarbocyanines more than five >CH- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Polymerisation Methods In General (AREA)
  • Coloring (AREA)

Abstract

내용 없음

Description

개시제로서 이온 염료 화합물을 함유하는 방사선-경화성 잉크 및 피복조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 화학방사선을 흡수할 수 있으며, 유리 라디칼 중합반응을 개시하는 유리 라디킬을 생성시키거나 중합성 또는 가교결합성 화합물을 가교결합시킬 수 있는 이온염료-반응성 반대이온 화합물, 유리 라디칼 첨가 중합성 또는 가교결합성 화합물 및 착색제를 포함하는 방사선-경화성 조성물.
  2. 제1항에 있어서, 상기 이온 염료-반응성 반대이온 화합물이 노출단계전에는 안정한 비-가변성 화합물로 존재하는 조성물.
  3. 제2항에 있어서, 상기 이온염료-반응성 반대이온 화합물을 광에 노출시킴에 따라, 전자가 상기 염료로부터 상기 반대이온으로 전달되거나 상기 반대이온으로부터 상기 염료로 전달되고 상기 전자 전달속도가 조절된 확산속도보다 큰 조성물.
  4. 제3항에 있어서, 상기 이온염료-반응성 반대이온 화합물이 다음 일반식(Ⅰ)을 갖는 조성물.
    (Ⅰ)
    상기식에서, D+는 양이온 염료이고, R1,R2,R3및 R4는 각각 독립적으로 알킬, 아릴, 알크아릴, 알릴, 아르알킬, 알케닐, 알키닐, 지환족그룹 및 포화 또는 불포화된 헤테로사이클릭 그룹으로 이루어지는 그룹으로부터 선택된다.
  5. 제4항에 있어서, 상기 양이온 염료가 시아닌 염료인 조성물.
  6. 제1항에 있어서, 상기 화합물이 음이온 염료 화합물인 조성물.
  7. 제6항에 있어서, 상기 음이온 염료가 크산텐 및 옥소놀 염료는 이루어지는 그룹중에서 선택되는 조성물.
  8. 제1항에 있어서, 상기 중합성 또는 가교결합성 화합물이 에틸렌계 불포화화합물인 조성물.
  9. 제6항에 있어서, 상기 이온염료-반응성 반대 이온화합물이 음이온 염료-요오도늄 이온 착물 또는 음이온 염료-피릴륨이온 착물인 조성물.
  10. 제9항에 있어서, 상기 염료가 크산텐 염료인 조성물.
  11. 화학방사선을 흡수할 수 있고, 유리라디칼 중합반응을 개시하는 유리라디칼을 생성시키거나 중합성 또는 가교결합성 화합물을 가교결합시킬 수 있는 이온염료-반응성 반대이온 화합물, 유리라디칼 첨가중합성 또는 가교결합성화합물 및 착색제를 포함하는 방사선-경화성 잉크조성물을 기질상에 피복시키거나 인쇄시키고 ; 상기 피복되거나 인쇄된 기질을 화학방사선에 노출시키는 단계를 포함하는 피복 또는 인쇄법.
  12. 제11항에 있어서, 상기 이온염료-반응성 반대이온 화합물이 노출 단계전에는 안정한 비-가변성 화합물로 존재하는 방법.
  13. 제12항에 있어서, 상기 이온염료-반응성 반대이온 화합물을 방사선에 노출시킴에 따라 전자가 상기 염료로부터 상기 반대이온으로 전달되거나 상기 반대이온으로부터 상기 염료로 전달되며 상기 전자전달 속도가 조절된 확산속도보다 큰 방법.
  14. 제13항에 있어서, 상기 이온염료-반응성 반대이온 화합물이 일반식(Ⅰ)을 갖는 방법.
    (Ⅰ)
    상기식에서, D+는 양이온 염료이고, R1,R2,R3및 R4는 각각 독립적으로 알킬, 아릴, 알크아릴, 알릴, 아르알킬, 알케닐, 알키닐, 지환족그룹 및 포화 또는 불포화된 헤테로사이클릭 그룹으로 이루어지는 그룹으로부터 선택된다.
  15. 제14항에 있어서, 상기 양이온 염료가 시아닌 염료인 방법.
  16. 제11항에 있어서, 상기 이온염료-반응성 반대 이온화합물이 음이온 염료착물인 방법.
  17. 제16항에 있어서, 상기 음이온 염료가 크산텐 염료인 방법.
  18. 제11항에 있어서, 상기 중합성 또는 가교결합성 화합물이 에틸렌계 불포화 화합물인 방법.
  19. 제16항에 있어서, 상기 이온염료-반응성 반대이온화합물이 음이온 염료-요오도늄 이온화합물 또는 음이온염료-피릴륨이온 화합물인 방법.
  20. 제19항에 있어서, 상기 염료가 크산텐 염료인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880009383A 1987-07-27 1988-07-26 개시제로서 이온 염료 화합물을 함유하는 방사선-경화성 잉크 및 피복조성물 KR890002358A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/077,911 US4751102A (en) 1987-07-27 1987-07-27 Radiation-curable ink and coating compositions containing ionic dye compounds as initiators
US077.911 1987-07-27

Publications (1)

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KR890002358A true KR890002358A (ko) 1989-04-10

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KR1019880009383A KR890002358A (ko) 1987-07-27 1988-07-26 개시제로서 이온 염료 화합물을 함유하는 방사선-경화성 잉크 및 피복조성물

Country Status (6)

Country Link
US (1) US4751102A (ko)
EP (1) EP0301769A3 (ko)
JP (1) JPS6460606A (ko)
KR (1) KR890002358A (ko)
CN (1) CN1036976A (ko)
DK (1) DK417888A (ko)

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