KR880014049A - 칩 저항성 피복물품 및 칩 저항성을 제공하는 방법 - Google Patents

칩 저항성 피복물품 및 칩 저항성을 제공하는 방법 Download PDF

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KR880014049A
KR880014049A KR1019880005655A KR880005655A KR880014049A KR 880014049 A KR880014049 A KR 880014049A KR 1019880005655 A KR1019880005655 A KR 1019880005655A KR 880005655 A KR880005655 A KR 880005655A KR 880014049 A KR880014049 A KR 880014049A
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coating
carboxyl
modified epoxy
diene
functional
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KR1019880005655A
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KR920003412B1 (ko
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미셸 기어리 데니스
허셸 페티트 쥬니어 폴
케이 비처 수전
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원본 미기재
피이피이지이 인더스트리이즈 인코포레이티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

칩 저항성 피복물품 및 칩 저항성을 제공하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (25)

  1. 금속 기판; 및 금속 기판상에 처리된 폴리에폭사이드 수지 및 디엔-함유 중합체의 총중량을 기준으로, 관능기로-말단된 디엔-함유 중합체 약 5-35 중량% 및 폴리에폭사이드 수지로부터 유도된 탄성공증합체-개질에폭시(관능기는 에폭시와 반응성이 있으며, 카르복실, 페놀, 히드록실, 에폭시, 아미노 및 멀캅탄으로 이루어진 군으로부터 선택된다) 및 적어도 2.0의 카르복실 관능가를 가지며, 카르복실-관능성 폴리에스테르 수지, 카르복실-관능성 아크릴 중합체, 다카르복실산, 폴리카르복실산 또는 그의 혼합물로 이루어진 군으로부터 선택되는 가르복실 관능성 물질의 상호 반응된 혼합물을 포함하는 피복층, 및 탄성 공중합체-개질 에폭시 함유 피복층과 다른 조성을 갖는 적어도 하나의 부가적인 피복층을 포함하는, 칩 저항성 복합 피복물을 갖는 피복물품.
  2. 제 1 항에 있어서, 복합 피복물이 금속 기판상에 처리된 전착 하도층 및 하도층상의 탄성 공중합체-개질 에폭시 함유 피복층을 포함하는 피복 물품.
  3. 제 2 항에 있어서, 복합 피복물이 탄성공중합체-개질 에폭시 함유 피복층상에 적어도 상도가 포함되어 있는 피복물품.
  4. 제 1 항에 있어서, 복합 피복물이 금속 기판상에 처리된 탄성 공중합체-개질 에폭시 함유피복층 및 탄성공중합체-개질 에폭시함유 피복층 상의 적어도 하나의 상도층을 포함하는 피복물품.
  5. 제 1 항에 있어서, 관능기로-말단된 디엔-함유 중합체가 B가 C4-C10디엔, C4-C10디엔 및 비닐방향족 단량체, C4-C10디엔 및 비닐 니트릴, C4-C10디엔, 비닐 니트릴 및 일반식 CH2=CR-COOR1(여기에서 R은 수소 또는 C1-C4알킬 라디칼이고, R1은 수소 또는 C1-C10알킬 라디칼이다)의 아크릴레이트, 또는 C4-C10디엔, 비닐 니트릴 및 비닐 방향족 단량체로 이루어진 군으로부터 선택된 물질로부터 중합된 골격이고 X가 카르복실, 페놀, 에폭시, 히드록실, 아미노 또는 멀캅틴으로 이루어진 군으로부터 선택된 관능기를 나타내는, 일반식 X-B-X를 갖는 피복물품.
  6. 제 5 항에 있어서, 디엔-함유 중합체의 디엔이 부타디엔인 피복물품.
  7. 제 1 항에 있어서, 관능기로-말단된 디엔-함유 중합체가 폴리부타디엔, 폴리이소프로렌, 부타디엔-아크릴로니트릴 공중합체, 부타디엔-스티렌 중합체, 부타디엔-아크릴로니트릴-아크릴 산 공중합체, 또는 부타디엔-스티렌-아크릴로니트릴 중합체로 이루어진 군으로부터 선택되는 피복물품.
  8. 제 7 항에 있어서, 관능기가 카르복실인 피복물품.
  9. 제 8 항에 있어서, 카르복실-말단디엔-함유중합체가 부타디엔-아크릴로니트릴 중합체인 피복물품.
  10. 제 7 항에 있어서, 카로복실-관능성 물질이 2.0-약 6.0의 카르복실-관능기를 갖는 피복물품.
  11. 제 8 항에 있어서, 탄성공중합체-개질 에폭시대 카르복실-관능성 물질의 당량비가 에폭시대 카르복실 당량을 기준으로 약 0.5 : 1-약 1.5 : 1인 피복물품.
  12. 제 7 항에 있어서, 폴리에폭사이드수지가 글리콜의 폴리글리시딜 에테르, 폴리글리콜의 폴리글리시딜에테르, 및 폴리페놀의 폴리글리시딜 에테르로 이루어진 군으로부터 선택된 피복물품.
  13. 제12항에 있어서, 탄성공중합체-개질에폭시가 카르복실-말단 부타디엔-아크릴로니트릴 공중합체 약 10-30 중량% 및 폴리에폭사이드수지 약 70-90 중량%의 반응생성물을 포함하는 피복물품.
  14. 제13항에 있어서, 폴리에폭사이드가 비스페놀 A의 디글리시딜 에테르이고 카르복실-관능성 물질이 카르복실-관능성 폴리에스테르수지인 피복물품.
  15. 제 1 항에 있어서, 탄성공중합체-개질 에폭시 함유 피복층이 약 2-15mils 두께인 피복물품.
  16. 제 1 항에 있어서, 금속 기판이 스틸 및 알루미늄으로 이루어진 군으로부터 선택된 피복물품.
  17. 제 1 항에 있어서, 금속 기판이 인화된 스틸인 피복물품.
  18. 탄성공중합체-개질 에폭시함유 피복물과 다른 조성물 갖는 적어도 하나의 부가적인 피복층과 조합되어 (a)폴리에폭사이드수지 및 디엔-함유 중합체의 총중량을 기준으로 관능기로-말단된 디엔-함유 중합체 약 5-약 35 중량% 및 폴리에폭사이드수지로부터 유도된 탄성공중합체-개질 에폭시(관능기는 에폭시와 반응성이 있으며, 카르복실, 페놀, 히드록실, 에폭시, 아미노 및 멀캅탄으로 이루어진 군으로부터 선택된다.) 및 (b)적어도 2.0의 카르복실-관능가를 가지며, 카르복실-관능성 폴리에스테르 수지, 카르복실-관능성 아클리 중합체, 디카르복실산, 폴리카르복실산 또는 이들의 혼합물로 이루어진 군으로부터 선택된 카르복실-관능성 물질의 상호반응성 열경화성 혼합물을 포함하는 피복층을 이용하는 것(피복층의 조합은 금속 기판위에 처리됨)을 포함하는, 적어도 두개의 다른 피복층을 그위에 갖는 피복된 금속 기판에 칩 저항성을 제공하는 방법.
  19. 제18항에 있어서, 탄성공중합체-개질 에폭시함유 피복층을 미립분말 피복조성물로서 적용시키는 방법.
  20. 제19항에 있어서, 탄성 공중합체-개질 에폭시함유 피복층을 금속 기판위에 전착된 하도를 갖는 금속기판상에 적용시키는 방법.
  21. 제20항에 있어서, 탄성공중합체-개질 에폭시함유 피복층위에 상도층을 적용시키는것을 포함하는 방법.
  22. 제19항에 있어서, 탄성공중합체-개질 에폭시함유 피복물을 금속 기판상에 적용시키고 상도 층을 탄성 공중합체-개질 에폭시 피복물상에 적용시키는 방법.
  23. 제19항에 있어서, 복합 피복물이 금속 기판상에 처리된 전착 하도층 및 하도층위에 탄성공중합체-개질 에폭시 함유 피복층을 포함하는 방법.
  24. 제19항에 있어서, 복합 피복물이 금속 기판상에 처리된 탄성공중합체-개질 에폭시 함유피복층 및 탄성공중합체-개질 에폭시 함유 피복층상에 적어도 하나의 상도층을 포함하는 방법.
  25. 제19항에 있어서, 관능기로-말단된 디엔-함유 중합체가 카르복실-관능성 부타디엔-아크릴로니트릴 중합체인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880005655A 1987-05-14 1988-05-13 칩 저항성 피복 물품 KR920003412B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/049,368 US4804581A (en) 1987-05-14 1987-05-14 Chip resistant coatings
US049368 1987-05-14
US49,368 1987-05-14

Publications (2)

Publication Number Publication Date
KR880014049A true KR880014049A (ko) 1988-12-22
KR920003412B1 KR920003412B1 (ko) 1992-04-30

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Country Status (8)

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US (1) US4804581A (ko)
EP (1) EP0292771B1 (ko)
JP (1) JPH0628940B2 (ko)
KR (1) KR920003412B1 (ko)
CA (1) CA1325928C (ko)
DE (1) DE3879760T2 (ko)
ES (1) ES2040287T3 (ko)
MX (1) MX167228B (ko)

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ES2040287T3 (es) 1993-10-16
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KR920003412B1 (ko) 1992-04-30
MX167228B (es) 1993-03-05
US4804581A (en) 1989-02-14
CA1325928C (en) 1994-01-11
JPH0628940B2 (ja) 1994-04-20
DE3879760T2 (de) 1993-10-21
EP0292771B1 (en) 1993-03-31
EP0292771A2 (en) 1988-11-30
JPS63302033A (ja) 1988-12-08

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