KR880012735A - 탄화수소 그 제조방법 및 기구 - Google Patents

탄화수소 그 제조방법 및 기구 Download PDF

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Publication number
KR880012735A
KR880012735A KR1019880004872A KR880004872A KR880012735A KR 880012735 A KR880012735 A KR 880012735A KR 1019880004872 A KR1019880004872 A KR 1019880004872A KR 880004872 A KR880004872 A KR 880004872A KR 880012735 A KR880012735 A KR 880012735A
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South Korea
Prior art keywords
spirals
reaction zone
pbw
carbon atoms
cobalt
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KR1019880004872A
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English (en)
Inventor
오하네스 반 데어 버어트 마르덴
아벨 포스트후마 시쯔
덴 하르토그 마르크
Original Assignee
오노 알버어스
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Application filed by 오노 알버어스, 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR880012735A publication Critical patent/KR880012735A/ko

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0455Reaction conditions
    • C07C1/048Temperature controlling measures
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12Silica and alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/26Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/75Cobalt

Abstract

내용 없음

Description

탄화수소 그 제조방법 및 기구
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 각 형태가 하나 또는 그 이상의 나선을,함유하는 하나 또는 그 이상의 나선형태를 통해 흐르는 냉각제로 간접열교환시킴으로써 반응지대로부터 열을 제거시키면서 기체 혼합물을 촉매 입자를 함유하는 반응지대를 통해 보내는 것을 포함하는 수소 및 일산화탄소를 함유하는 기체 혼합물로부터 분자당 적어도 두 개의 탄소 원자를 함유하는 탄화수소를 촉매적으로 제조하는 방법.
  2. 제 1항에 있어서, 냉각제가 둘 또는 그 이상의 동심 나선형태를 통해 흐르는 방법.
  3. 제 2항에 있어서, 인접한 나선 형태가 스크루 방향이 서로서로 반대방향인 방법
  4. 제 2항 또는 제3항에 있어서, 중심으로부터 보다 먼 거리에 위치하는 나선 형태에 증가하는 수의 나선의 사용되는 방법.
  5. 제 4항에 있어서, 나선들이 본질적으로 같은 길이를 갖는 방법.
  6. 제 1항 내지 제5항중 어느 한 항에 있어서, 합성 기체 공급물이 분자당 적어도 5개의 탄소원자, 바람직하기로는 적어도 10개의 탄소원자를 탄화수소로 전환되는 방법.
  7. 제 1항 내지 제6항중 어느 한항에 있어서, 100-500℃의 온도, 1-200바아 abs의 총 압력 및 200-20,000m3(S.T.P) 기체 공급물/m3반응지대/h의 공간 속도에서 수행되는 방법.
  8. 제 1항 내지 제7항중 어느 한 항에 있어서, 실리카, 알루미나 또는 실리카-알루미나 담체 100pbw당, 지르코늄, 티타늄 및 크롬에 의해 형성된 군으로부터 선택된 적어도 하나의 다른 금속 0.1-100pbw 및 코발트 3-60pbw를 포함하는 촉매를 사용하는 방법.
  9. 제 1항 내지 제8항중 어느 한 항의 방법에 따라 제조되는 탄화수소.
  10. 기체 공급물 유입수단 및 생성물 유출수단을 갖고 있으며, 고정된 촉매 베드를 포함하는 반응구역을 에워싸고 있는 하우징을 포함하는 것으로, 반응구역이 공급물 유입수단 및 유출수단과 통하며, 이 구역내에 하나 또는 그 이상의 나선형으로 감긴 튜브 또는 튜브 다발이 설치되어 있는, 제1항 내지 제8항중 어느 한항에 따른 방법을 수행하는데 사용되는 기구.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880004872A 1987-04-29 1988-04-27 탄화수소 그 제조방법 및 기구 KR880012735A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8710170 1987-04-29
GB8710170A GB2204055B (en) 1987-04-29 1987-04-29 Process for the preparation of hydrocarbons

Publications (1)

Publication Number Publication Date
KR880012735A true KR880012735A (ko) 1988-11-28

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880004872A KR880012735A (ko) 1987-04-29 1988-04-27 탄화수소 그 제조방법 및 기구

Country Status (15)

Country Link
JP (1) JPS63295517A (ko)
KR (1) KR880012735A (ko)
CN (1) CN1014398B (ko)
AU (1) AU608833B2 (ko)
BR (1) BR8802016A (ko)
CA (1) CA1323636C (ko)
DE (1) DE3814263A1 (ko)
GB (1) GB2204055B (ko)
IN (1) IN171332B (ko)
IT (1) IT1219250B (ko)
MY (1) MY103517A (ko)
NO (1) NO177492C (ko)
NZ (1) NZ224389A (ko)
SG (1) SG40092G (ko)
ZA (1) ZA882985B (ko)

Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
GB8810006D0 (en) * 1988-04-27 1988-06-02 Shell Int Research Process for preparation of ethylene oxide
US5286455A (en) * 1990-06-18 1994-02-15 Shell Oil Company Process for the preparation of hydrocarbons
WO1994012274A1 (en) * 1992-11-20 1994-06-09 Shell Internationale Research Maatschappij B.V. Reactor and process for highly exothermic or endothermic reactions
EP1060788A1 (en) * 1999-06-15 2000-12-20 Methanol Casale S.A. Isothermal catalytic reactor for exothermic or endothermic heterogeneous reactions
IT1319549B1 (it) * 2000-12-14 2003-10-20 Methanol Casale Sa Reattore per l'effettuazione di reazioni eterogenee esotermiche oendotermiche
US7232848B2 (en) 2002-09-09 2007-06-19 Conocophillips Company Gas agitated multiphase reactor with stationary catalyst solid phase
CN1293027C (zh) * 2002-10-08 2007-01-03 碳氢技术公司 一种使用骨架铁催化剂由合成气制备烃产物的浆态相工艺过程
CN101307245B (zh) * 2008-05-19 2012-08-22 中国科学院山西煤炭化学研究所 一种利用固定床装置进行费托合成反应的工艺及设备
JP5615838B2 (ja) * 2008-12-16 2014-10-29 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー フィッシャートロプシュ法における高速停止
EP2496515B1 (en) 2009-11-06 2020-08-12 Auburn University Microfibrous media for optimizing and controlling highly exothermic and highly endothermic reactions/processes
CN103007853A (zh) * 2011-09-23 2013-04-03 中国科学院大连化学物理研究所 碳化硅微通道反应器及其在烃类裂解制低碳烯烃中的应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB648317A (en) * 1944-10-11 1951-01-03 Standard Oil Co Improvements in or relating to a process of synthesizing hydrocarbons
GB615381A (en) * 1946-08-06 1949-01-05 Standard Oil Dev Co An improved process for the catalytic synthesis of hydrocarbons
GB631682A (en) * 1947-02-28 1949-11-08 Standard Oil Dev Co An improved process for the synthesis of hydrocarbons
GB671490A (en) * 1948-12-04 1952-05-07 Standard Oil Dev Co Synthesis of hydrocarbons
GB678211A (en) * 1949-05-02 1952-08-27 John Burnard Harding Improvements in and relating to the conducting of chemical processes and apparatus therefor
GB710339A (en) * 1949-06-16 1954-06-09 Standard Oil Dev Co Improvements in or relating to the synthesis of hydrocarbons and catalysts therefor
GB711441A (en) * 1951-02-27 1954-06-30 Standard Oil Co Improvements in or relating to method and apparatus for effecting hydrocarbon conversion with aluminium halide complex catalyst
NL7704656A (nl) * 1977-04-28 1978-10-31 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
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DE3414717A1 (de) * 1984-04-18 1985-10-31 Linde Ag, 6200 Wiesbaden Verfahren und reaktor zur durchfuehrung exothermer katalytischer reaktionen

Also Published As

Publication number Publication date
IT1219250B (it) 1990-05-03
NZ224389A (en) 1990-12-21
CA1323636C (en) 1993-10-26
NO177492C (no) 1995-10-04
NO177492B (no) 1995-06-19
GB2204055B (en) 1992-01-02
CN1014398B (zh) 1991-10-23
JPS63295517A (ja) 1988-12-01
GB8710170D0 (en) 1987-06-03
DE3814263A1 (de) 1988-11-10
ZA882985B (en) 1988-10-28
NO881834D0 (no) 1988-04-27
NO881834L (no) 1988-10-31
GB2204055A (en) 1988-11-02
BR8802016A (pt) 1988-11-29
AU1519388A (en) 1988-11-03
SG40092G (en) 1992-06-12
CN88102563A (zh) 1988-12-14
MY103517A (en) 1993-07-31
AU608833B2 (en) 1991-04-18
IN171332B (ko) 1992-09-19
IT8867394A0 (it) 1988-04-27

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