KR880011061A - (페닐에테닐) 페닐 프로피온알데히드 및 그것을 사용하는 (벤조일페일) 프로피온산의 제조방법 - Google Patents

(페닐에테닐) 페닐 프로피온알데히드 및 그것을 사용하는 (벤조일페일) 프로피온산의 제조방법 Download PDF

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KR880011061A
KR880011061A KR1019880002405A KR880002405A KR880011061A KR 880011061 A KR880011061 A KR 880011061A KR 1019880002405 A KR1019880002405 A KR 1019880002405A KR 880002405 A KR880002405 A KR 880002405A KR 880011061 A KR880011061 A KR 880011061A
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South Korea
Prior art keywords
phenylethenyl
oxidation
producing
phenyl
oil
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KR1019880002405A
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KR930010405B1 (ko
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이소오 시미즈
야스오 마쓰무라
유다까 아라이
Original Assignee
가다야마 유다까
니혼세끼유 가가꾸 가부시끼가이샤
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Publication of KR880011061A publication Critical patent/KR880011061A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/50—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/228—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde
    • C07C47/232—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/28—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings
    • C07C47/32—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/76—Unsaturated compounds containing keto groups
    • C07C59/84—Unsaturated compounds containing keto groups containing six membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

(페닐에테닐) 페닐 프로피온알데히드 및 그것을 사용하는 (벤조일페일) 프로피온산의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 하기 구조식으로 표시되는 ??-(3-(1-페닐에테닐)페닐) 프로피온알데히드.
  2. 상기식(Ⅰ)로 표시되는 α(3-(1-페닐에테닐)페닐) 프로피온알데히드를 산화하는 것을 특징으로 하는 식(Ⅱ)의 α-(3-벤조일페닐) 포로피온산의 제조방법.
  3. 제2항에 있어서, 상기 산화가, 산화촉매의 존재하의 분자상 산소에 의한 산화 또는 산화제에 의한 산화인 것을 특징으로 하는 제조방법.
  4. 제2항에 있어서, α-(3-(1-페닐에테닐)페닐) 프로피온알데히드가, 1-(3-비닐페닐)-1-페닐에틸렌을 함유하는 유분을 천이금속착체 촉매의 존재하에 일산화탄소와 수소를 반응시킴으로써 얻어지는 것을 특징으로 하는 α-(3-벤조일페닐) 프로피온산의 제조방법.
  5. 제4항에 있어서, 상기 1-(3-비닐페닐)-1-페닐에틸렌을 함유하는 유분이, 1-(3-에틸페닐)-1-페닐에탄을 함유하는 유분을 탈수소함으로써 제조되는 것을 특징으로 하는 제조방법.
  6. 제5항에 있어서, 상기 1-(3-에틸페닐)-1-페닐에탄을 함유하는 유분이, 벤젠을 에틸렌에서 알킬화 촉매에 의해 알킬화할때에, 비점 285℃ 내지 290℃(상압환산의 범위에 있는 유분으로서 회수되는 것을 특징으로 하는 제조방법.
  7. 제6항에 있어서, 상기 알킬화촉매가 루이스산 또는 푸로톤산인 것을 특징으로 하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880002405A 1987-03-12 1988-03-08 α-(3-(1-페닐에테닐)페닐)프로피온알데히드 KR930010405B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62-57098 1987-03-12
JP62057098A JPH07100678B2 (ja) 1987-03-12 1987-03-12 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法

Publications (2)

Publication Number Publication Date
KR880011061A true KR880011061A (ko) 1988-10-26
KR930010405B1 KR930010405B1 (ko) 1993-10-23

Family

ID=13046031

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019880002405A KR930010405B1 (ko) 1987-03-12 1988-03-08 α-(3-(1-페닐에테닐)페닐)프로피온알데히드
KR1019880701428A KR960002599B1 (ko) 1987-03-12 1988-03-12 디올레핀의 선택적 히드로포르밀화 방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1019880701428A KR960002599B1 (ko) 1987-03-12 1988-03-12 디올레핀의 선택적 히드로포르밀화 방법

Country Status (7)

Country Link
US (2) US4889952A (ko)
EP (2) EP0282066B1 (ko)
JP (1) JPH07100678B2 (ko)
KR (2) KR930010405B1 (ko)
CA (1) CA1304401C (ko)
DE (2) DE3871410D1 (ko)
WO (1) WO1988007033A1 (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07100678B2 (ja) * 1987-03-12 1995-11-01 日本石油化学株式会社 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法
JPS63233945A (ja) * 1987-03-23 1988-09-29 Nippon Petrochem Co Ltd ジオレフインの選択的ヒドロフオルミル化方法
CA2005845C (en) * 1988-12-21 2001-01-09 Isoo Shimizu Method for preparing a-(4-isobutylphenyl) propionic acid or its precursor
JP2782080B2 (ja) * 1989-03-06 1998-07-30 日本石油化学株式会社 α―（３―ベンゾイルフェニル）プロピオン酸誘導体の製造方法
US5175266A (en) * 1991-04-19 1992-12-29 Triplex Pharmaceutical Corporation Nucleosides and oligonucleosides with a phosphate-free internucleoside backbone and process for preparing the same
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JP2000016952A (ja) * 1998-07-01 2000-01-18 Nippon Petrochem Co Ltd 炭化水素の製造方法
US7625988B2 (en) * 2003-06-20 2009-12-01 William Marsh Rice University Flame retardant polymers having pendant groups related to bisphenol-C and monomers for synthesis thereof
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JPH07100678B2 (ja) * 1987-03-12 1995-11-01 日本石油化学株式会社 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法
JPH07100679B2 (ja) * 1987-03-12 1995-11-01 日本石油化学株式会社 α−（３−ベンゾイルフエニル）プロピオン酸またはそのエステルの製造方法
JPS63233945A (ja) * 1987-03-23 1988-09-29 Nippon Petrochem Co Ltd ジオレフインの選択的ヒドロフオルミル化方法
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Also Published As

Publication number Publication date
EP0282066A2 (en) 1988-09-14
EP0311689B1 (en) 1992-06-10
EP0311689A4 (en) 1989-07-24
JPS63225334A (ja) 1988-09-20
DE3871898D1 (de) 1992-07-16
JPH07100678B2 (ja) 1995-11-01
EP0311689A1 (en) 1989-04-19
KR930010405B1 (ko) 1993-10-23
WO1988007033A1 (en) 1988-09-22
EP0282066A3 (en) 1989-09-27
EP0282066B1 (en) 1992-05-27
KR960002599B1 (ko) 1996-02-23
KR890700564A (ko) 1989-04-25
DE3871898T2 (de) 1993-02-04
US4889952A (en) 1989-12-26
DE3871410D1 (de) 1992-07-02
CA1304401C (en) 1992-06-30
US4982007A (en) 1991-01-01

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