KR880006271A - 열적 활성화된 2성분 치환촉매 시스템 및 그 제조 방법 - Google Patents

열적 활성화된 2성분 치환촉매 시스템 및 그 제조 방법 Download PDF

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KR880006271A
KR880006271A KR870012242A KR870012242A KR880006271A KR 880006271 A KR880006271 A KR 880006271A KR 870012242 A KR870012242 A KR 870012242A KR 870012242 A KR870012242 A KR 870012242A KR 880006271 A KR880006271 A KR 880006271A
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reaction rate
substituted
pyridine
aluminum
rate modifier
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KR870012242A
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KR960007931B1 (ko
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리. 넬손 로렌스
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마이클 비 키한
허큘리스 인코오포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

열적 활성화된 2성분 치환촉매 시스템 및 그 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 치환 중합 촉매, 알킬 알루미늄 촉매 활성제 및 반응 속도 조절제를 사용하여 치환 중합성 시클로올레핀로 부터 성형 제품을 제조하기 위하여, 반응 속도 조절제가 불포화 시클로 아민 및 포화폴리시클로 아민으로 구성된 부류로 부터 선택되는 입체 비장애 또는 부분 비장애 친핵성 루이스 염기로 구성되는 것을 특징으로 하는 방법.
  2. 제1항에 있어서, 성형 제품을 제조하기 위하여 반응 속도 조절제가 피리딘, 2-,3- 또는 4-치환 피리딘, 2,4-또는 3,4-디-치환 피리딘, 2-치환, 2,3-디-치환 또는 2,5-디-치환 피라진, 퀴놀린, 퀴노옥살린, 1,4-디아자비시클로[2.2.2]옥탄, 헥사메틸렌 테트라아민인 것을 특징으로 하는 방법.
  3. 제2항에 있어서, 성형 제품을 제조하기 위하여 반응 속도 조절제가 피리딘, 3-에틸 피리딘, 또는 4-에틸 피리딘인 것을 특징으로 하는 방법.
  4. 제2항에 있어서, 성형 제품을 제조하기 위하여 반응 속도 조절제가 1,4-디아자비시클로[2.2.2]옥탄, 또는 헥사메틸렌 테트라아민인 것을 특징으로 하는 방법.
  5. 제3항 또는 제4항에 있어서, 성형 제품을 제조하기 위하여 알킬 알루미늄 활성 조성물이 트리알킬 알루미늄 또는 혼합된 트리알킬 알루미늄 및 디알킬 알루미늄 할라이드 활성제인 것을 특징으로 하는 방법.
  6. 제5항에 있어서 성형 제품을 제조하기 위하여 알킬 알루미늄 활성 조성물이 트리-n-옥틸 알루미늄 및 디옥틸 알루미늄 요오다이드의 혼합물인 것을 특징으로 하는 방법.
  7. 제2항에 있어서 성형 제품을 제조하기 위하여 반응 속도 조절제가 4-페닐 피리딘, 퀴놀린, 퀴노옥살린, 2,3-디메틸 또는 2,5-디메틸 피라진 또는 1,4-디아자비시클로[2.2.2]-옥탄인 것을 특징으로 하는 방법.
  8. 제7항에 있어서, 성형 제품을 제조하기 위하여 알킬알루미늄 활성 조성물이 디옥틸 알루미늄 요오다이드인 것을 특징으로 하는 방법.
  9. 알킬 알루미늄 촉매 활성제 및 반응 속도 조절제로 구성된 치환-중합성 시클로올레핀으로 부터 성형제품을 제조하기 위하여, 중합 급송 조성물이 치환 중합 촉매를 함유하고, 반응 속도 조절제가 제1항 내지 제8항중의 어느 한항에서와 같이 불포화시클로 아민 및 포화폴리시클로 아민으로 구성된 부류로 부터 선택되는 입체 비장애 또는 부분 비장애 친핵성 루이스 염기인 것을 특징으로 하는 중합 급송 조성물.
  10. 제9항에 있어서, 성형 제품을 제조하기 위하여 중합 급송 조성물을 사용하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870012242A 1986-11-03 1987-11-02 열적 활성화된 2성분 치환 촉매 시스템 및 그 제조방법 KR960007931B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US926272 1986-11-03
US06/926,272 US4727125A (en) 1986-11-03 1986-11-03 Thermally activated two component metathesis catalyst system
US926,272 1986-11-03

Publications (2)

Publication Number Publication Date
KR880006271A true KR880006271A (ko) 1988-07-22
KR960007931B1 KR960007931B1 (ko) 1996-06-17

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KR1019870012242A KR960007931B1 (ko) 1986-11-03 1987-11-02 열적 활성화된 2성분 치환 촉매 시스템 및 그 제조방법

Country Status (8)

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US (1) US4727125A (ko)
EP (1) EP0266587B1 (ko)
JP (1) JPS63122726A (ko)
KR (1) KR960007931B1 (ko)
AU (1) AU599716B2 (ko)
BR (1) BR8705801A (ko)
CA (1) CA1296133C (ko)
DE (1) DE3787345D1 (ko)

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ATE103302T1 (de) * 1987-12-31 1994-04-15 Goodrich Co B F Norbornen-gemisch mit laengerer haltbarkeitsdauer.
US4902560A (en) * 1988-06-01 1990-02-20 Hercules Incorporated Improving the physical properties of glass composite polydicyclopentadiene by heat treatment
FR2646426B2 (fr) * 1988-09-13 1991-08-16 Bp Chemicals Sa Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite
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CA2028973A1 (en) * 1989-11-01 1991-05-02 Masao Torii Method of making ring-opened polynorbornene polymers using pot life extending agents
US5066740A (en) * 1989-12-26 1991-11-19 The B. F. Goodrich Company Pyridinium metathesis catalysts for cycloolefin polymerization
EP0439650A1 (en) * 1990-01-31 1991-08-07 Hercules Incorporated Molded polymer article filled with inorganic material and production of said article
US5082909A (en) * 1990-10-12 1992-01-21 Hercules Incorporated Pure tungsten oxyphenolate complexes as DCPD polymerization catalysts
USH1388H (en) * 1992-12-23 1994-12-06 Hercules Incorporated Polyolefin polymer and method of making same
CA2112146A1 (en) * 1992-12-23 1994-06-24 Nitya P. Khasat Polydicyclopentadiene having improved stability and toughened with polymeric particles
US6433113B1 (en) 2000-12-07 2002-08-13 Zeon Corporation Ring-opening metathesis polymerization (ROMP) of cyclo-olefins with molybdenum catalysts
JP5436336B2 (ja) * 2010-05-25 2014-03-05 Ｒｉｍｔｅｃ株式会社 触媒液、配合液、ノルボルネン系樹脂成形体およびその成形方法
JP7477957B2 (ja) * 2019-10-30 2024-05-02 アキレス株式会社 難燃性シクロオレフィン系樹脂成形体製造方法

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Also Published As

Publication number Publication date
BR8705801A (pt) 1988-06-14
AU599716B2 (en) 1990-07-26
EP0266587A3 (en) 1989-01-18
CA1296133C (en) 1992-02-18
AU8058887A (en) 1988-05-05
JPS63122726A (ja) 1988-05-26
JPH0471409B2 (ko) 1992-11-13
DE3787345D1 (de) 1993-10-14
EP0266587B1 (en) 1993-09-08
KR960007931B1 (ko) 1996-06-17
US4727125A (en) 1988-02-23
EP0266587A2 (en) 1988-05-11

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