KR850005850A - 나일론 블록 공중합체 조성물 및 그 제조방법 - Google Patents

나일론 블록 공중합체 조성물 및 그 제조방법 Download PDF

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Publication number
KR850005850A
KR850005850A KR1019850000719A KR850000719A KR850005850A KR 850005850 A KR850005850 A KR 850005850A KR 1019850000719 A KR1019850000719 A KR 1019850000719A KR 850000719 A KR850000719 A KR 850000719A KR 850005850 A KR850005850 A KR 850005850A
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KR
South Korea
Prior art keywords
activator
lactam
block copolymer
copolymer composition
nylon block
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KR1019850000719A
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English (en)
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KR870001410B1 (ko
Inventor
헨드리쿠스 브린쎈 코르네리스
Original Assignee
제이. 에이치. 크루이트 : 하. 베. 반 리우벤
스태미카본 베. 뷔.
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Publication of KR850005850A publication Critical patent/KR850005850A/ko
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Publication of KR870001410B1 publication Critical patent/KR870001410B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C08G69/18—Anionic polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8074—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C08G69/18—Anionic polymerisation
    • C08G69/20—Anionic polymerisation characterised by the catalysts used

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)

Abstract

내용 없음

Description

나일론 블록 공중합체 조성물 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 락탐중합 촉매와 활성화제의 존재하에 락탐중합으로 나일론 블록 공중합체 조성물을 제조함에 있어서, 사용된 활성화제가 분자량이 1500인 락탐으로 종결된 고분자 활성화제와 분자량이 750인 락탐으로 종결된 저분자 활성화제의 결합인 것을 특징으로 하는 나일론 블록 공중합체 조성물의 제조방법.
  2. 제1항에 있어서, 락탐으로 종결된 고분자 활성화제가 폴리올과 활성화제 그룹으로 포함한 화합물과의 반응 생성물인 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 저분자 활성화제가 디아실락탐 또는 N-치환된 카르바모일 락탐 화합물인 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 고분자 활성화제와 저분자 활성화제가 결합한 것을 사용하는 데 있어 고분자 활성화제의 활성화제 그룹 100개에 대하여 저분자 활성화제의 활성 화제 그룹 50-1000개가 존재하는 것을특징으로 하는 방법.
  5. 제4항에 있어서, 고분자 활성화제의 활성 화제 그룹 100개에 대하여 저분자 활성화제의 활성화제 그룹 75-250개가 존재하는 것을 특징으로 하는 방법.
  6. 제2항에 있어서, 당량이 300인 폴리올을 사용하는 것을 특징으로 하는 방법.
  7. 제6항에 있어서, 당량이 1000-5000인 폴리올을 사용하는 것을 특징으로 하는 방법.
  8. 제1항에 있어서, 2-피롤리돈, 2-피 페리돈, 카프로락탐과 라우릴 락탐으로된 그룹으로부터 하나또는 그 사상의 락탐이 중합되는 것을 특징으로 하는 방법.
  9. 제1항에 있어서, 설실시예에 기술된 것을 특징으로 하는 방법.
  10. 제1항에서 9항중 어느 한항에 있어서, 이 방법에 따라 제조된 나일론 블록 공중합체 조성물.
  11. 제10항에 있어서, 나일론 블록 공중합체 조성물이 부분적으로 또는 전체적으로된 물건.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850000719A 1984-02-09 1985-02-05 나일론 블록 공중합체 제조방법 KR870001410B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8400411A NL8400411A (nl) 1984-02-09 1984-02-09 Werkwijze voor het bereiden van een nylonblokcopolymeercompositie.
NL8400411 1984-02-09

Publications (2)

Publication Number Publication Date
KR850005850A true KR850005850A (ko) 1985-09-26
KR870001410B1 KR870001410B1 (ko) 1987-07-30

Family

ID=19843462

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850000719A KR870001410B1 (ko) 1984-02-09 1985-02-05 나일론 블록 공중합체 제조방법

Country Status (6)

Country Link
US (1) US4611052A (ko)
EP (1) EP0156129B1 (ko)
JP (1) JPS60192727A (ko)
KR (1) KR870001410B1 (ko)
DE (1) DE3564121D1 (ko)
NL (1) NL8400411A (ko)

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IT1233835B (it) * 1988-01-11 1992-04-21 Montedipe Spa Processo per la preparazione di poliammidi con migliorate proprieta' meccaniche e poliammidi cosi' ottenute.
JP6084465B2 (ja) * 2010-03-01 2017-02-22 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド 溶融加工処理可能なコポリエーテルアミドエラストマー
KR101270993B1 (ko) * 2011-08-02 2013-06-04 한국화학연구원 바이오매스 기반 2-피롤리돈을 사용한 나일론 4,6 공중합체의 제조
US9139752B2 (en) * 2011-09-28 2015-09-22 Basf Se Process for producing polyamides via anionic polymerization
BR112014007052A2 (pt) 2011-09-28 2017-03-28 Basf Se processo para produzir poliamida, poliamida, e, uso de uma poliamida
KR101441328B1 (ko) * 2012-11-23 2014-09-17 한국화학연구원 바이오매스 기반의 나일론 4,5 공중합체 및 이의 제조 방법
KR101527579B1 (ko) * 2013-03-20 2015-06-10 한국화학연구원 바이오매스 기반의 나일론 6,5 랜덤 공중합체 및 이의 제조 방법
WO2019093729A2 (ko) 2017-11-08 2019-05-16 한화케미칼 주식회사 음이온 개환 중합에 의한 폴리아마이드의 제조 방법 및 이에 의해 제조된 폴리아마이드
KR102262539B1 (ko) 2017-11-14 2021-06-08 한화솔루션 주식회사 활성화제 투입 방식 조절을 통한 폴리아마이드 제조방법 및 이에 의해 제조된 폴리아마이드
KR102275688B1 (ko) 2017-11-28 2021-07-12 한화솔루션 주식회사 말단 봉지재를 이용한 폴리아마이드의 제조 방법 및 이에 의해 제조된 폴리아마이드
KR102262504B1 (ko) 2017-11-28 2021-06-08 한화솔루션 주식회사 이중 활성기를 지닌 분자량조절제를 이용한 폴리아마이드 제조방법 및 이에 의해 제조된 폴리아마이드
KR102262531B1 (ko) 2017-11-28 2021-06-08 한화솔루션 주식회사 아마이드계-분자량조절제를 포함하는 폴리아마이드 제조방법 및 이에 의해 제조된 폴리아마이드
CN117024951B (zh) * 2023-10-10 2024-01-09 季华合越科技(佛山)有限公司 一种树脂组合物及玻璃纤维复合材料、其制备方法和应用

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US3245961A (en) * 1962-08-28 1966-04-12 Nopco Chem Co Polyureas from caprolactamblocked isocyanates
GB1067153A (en) * 1963-05-17 1967-05-03 Ici Ltd Grafted polyamides
US3511893A (en) * 1967-07-31 1970-05-12 Polymer Corp Polyamides block copolymers with caprolactam and caprylactam
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Also Published As

Publication number Publication date
KR870001410B1 (ko) 1987-07-30
JPS60192727A (ja) 1985-10-01
DE3564121D1 (en) 1988-09-08
NL8400411A (nl) 1985-09-02
US4611052A (en) 1986-09-09
EP0156129B1 (en) 1988-08-03
EP0156129A1 (en) 1985-10-02

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