KR900009707A - 시클로올레핀의 치환중합 반응을 지연시키는 질소 화합물 - Google Patents
시클로올레핀의 치환중합 반응을 지연시키는 질소 화합물 Download PDFInfo
- Publication number
- KR900009707A KR900009707A KR1019890020034A KR890020034A KR900009707A KR 900009707 A KR900009707 A KR 900009707A KR 1019890020034 A KR1019890020034 A KR 1019890020034A KR 890020034 A KR890020034 A KR 890020034A KR 900009707 A KR900009707 A KR 900009707A
- Authority
- KR
- South Korea
- Prior art keywords
- producing
- reaction
- substituted
- cycloolefin
- group
- Prior art date
Links
- 150000001925 cycloalkenes Chemical class 0.000 title claims 4
- 238000006116 polymerization reaction Methods 0.000 title claims 3
- 238000006467 substitution reaction Methods 0.000 title claims 2
- 229910017464 nitrogen compound Inorganic materials 0.000 title 1
- 150000002830 nitrogen compounds Chemical class 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical group CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 claims 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- -1 nitrogen-containing compound Chemical class 0.000 claims 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims 1
- UTBCLIMIBBSDLG-UHFFFAOYSA-N C12=CC=CCC2C2CC2C2C1C2 Chemical compound C12=CC=CCC2C2CC2C2C1C2 UTBCLIMIBBSDLG-UHFFFAOYSA-N 0.000 claims 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 1
- 239000012190 activator Substances 0.000 claims 1
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 150000004982 aromatic amines Chemical class 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000007809 chemical reaction catalyst Substances 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000003106 haloaryl group Chemical group 0.000 claims 1
- LPAGFVYQRIESJQ-UHFFFAOYSA-N indoline Chemical compound C1=CC=C2NCCC2=C1 LPAGFVYQRIESJQ-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- XBFJAVXCNXDMBH-GEDKWGBFSA-N molport-035-785-283 Chemical compound C1[C@@H](C23)C=C[C@H]1C3[C@@H]1C[C@H]2CC1 XBFJAVXCNXDMBH-GEDKWGBFSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 229920001187 thermosetting polymer Polymers 0.000 claims 1
- 239000004634 thermosetting polymer Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 치환-중합성이며 변형된 고리형 비-공액 시클로 올레핀을 함유하는 액체반응스트림, 치환 중합 반응 촉매, 치환 중합 반응 활성제 및 감속제를 중합 반응이 발생하는 몰드에 충진하여 열경화성 중합체의 성형제품을 제조하는 방법에 있어서, 상기 반응 감속제가 하기식으로 표시되는 질소함유 화합물인 것을 특징으로 하는 제조방법.(상기식에서, (a) X는 아릴, 알카릴 또는 할로아릴기이고 Y는 알킬기이며, Z는 알킬, 아르알킬 또는 시클로알킬기이고 Y및/ 또는 Z는 수소이거나 (b) Y와 Z모두 수소가 아닐때 N,Y 및 Z는 각각 알킬기이다.)
- 제1항에 있어서 반응 감속제가 아닐린, 알킬 아릴아민 또는 아릴아민인 것을 특징으로 하는 성형 제품의 제조방법.
- 제2항에 있어서, 반응 감속제가 N-에틸 아닐린 또는 인돌린인 것을 특징으로 하는 성형 제품의 제조방법.
- 제1항 내지 제3항중 어느 한항에 있어서, 상기 시클로올레핀이 디시클로펜타디엔, 시클로펜타디엔 소중합체, 노보르넨, 노보르나디엔, 4-알킬리덴 노보르넨, 디메타노옥타히드로 나프탈렌, 디메타노헥사히드로나프탈렌 및 상기단량체의 치환 유도체로 구성된 군으로 부터 선택된 단량체 또는 상기 단량체 2종 이상의 혼합물인 것을 특징으로 하는 성형 제품의 제조방법.
- 전술한 항중 어느 한항에 있어서, 치환 반응 촉매가 알킬알루미늄, 알킬아연 또는 알킬주석 화합물인 것을 특징으로 하는 성형 제품의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US291,940 | 1988-12-30 | ||
| US07/291,940 US4883849A (en) | 1988-12-30 | 1988-12-30 | Nitrogen compounds that delay the metathesis polymerization of cycloolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR900009707A true KR900009707A (ko) | 1990-07-05 |
Family
ID=23122518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890020034A KR900009707A (ko) | 1988-12-30 | 1989-12-29 | 시클로올레핀의 치환중합 반응을 지연시키는 질소 화합물 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4883849A (ko) |
| EP (1) | EP0376199A3 (ko) |
| JP (1) | JPH02185521A (ko) |
| KR (1) | KR900009707A (ko) |
| AU (1) | AU631166B2 (ko) |
| BR (1) | BR8906862A (ko) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4933402A (en) * | 1988-12-30 | 1990-06-12 | Hercules Incorporated | Phosphorus compounds that delay the metathesis polymerization of cycloolefins |
| US5082909A (en) * | 1990-10-12 | 1992-01-21 | Hercules Incorporated | Pure tungsten oxyphenolate complexes as DCPD polymerization catalysts |
| SK278739B6 (sk) * | 1991-12-16 | 1998-02-04 | Chemopetrol | Spôsob výroby polymérov a kopolymérov cykloalkénov |
| USH1388H (en) * | 1992-12-23 | 1994-12-06 | Hercules Incorporated | Polyolefin polymer and method of making same |
| CA2112146A1 (en) * | 1992-12-23 | 1994-06-24 | Nitya P. Khasat | Polydicyclopentadiene having improved stability and toughened with polymeric particles |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070500A (ko) * | 1973-10-23 | 1975-06-11 | Nippon Oil Co Ltd | |
| JPS5825689B2 (ja) * | 1975-08-27 | 1983-05-28 | 昭和電工株式会社 | カイカンジユウゴウタイノセイゾウホウホウ |
| US4080491A (en) * | 1975-08-27 | 1978-03-21 | Showa Denko K.K. | Process of producing ring-opening polymerization products |
| US4727125A (en) * | 1986-11-03 | 1988-02-23 | Hercules Incorporated | Thermally activated two component metathesis catalyst system |
| US4822839A (en) * | 1987-11-25 | 1989-04-18 | Hercules Incorporated | Polyunsaturated hydrocarbon polymer-compatible antioxidant compositions |
| US4812543A (en) * | 1988-03-01 | 1989-03-14 | Hercules Incorporated | Co-polymer-bound amine antioxidants |
-
1988
- 1988-12-30 US US07/291,940 patent/US4883849A/en not_active Expired - Fee Related
-
1989
- 1989-11-27 JP JP1304960A patent/JPH02185521A/ja active Pending
- 1989-12-22 EP EP19890123796 patent/EP0376199A3/en not_active Ceased
- 1989-12-29 AU AU47371/89A patent/AU631166B2/en not_active Expired - Fee Related
- 1989-12-29 BR BR898906862A patent/BR8906862A/pt not_active Application Discontinuation
- 1989-12-29 KR KR1019890020034A patent/KR900009707A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU4737189A (en) | 1990-07-05 |
| US4883849A (en) | 1989-11-28 |
| BR8906862A (pt) | 1990-09-25 |
| JPH02185521A (ja) | 1990-07-19 |
| AU631166B2 (en) | 1992-11-19 |
| EP0376199A2 (en) | 1990-07-04 |
| EP0376199A3 (en) | 1990-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |