MX166331B - Compuestos de fosforo que retardan la polimerizacion por metatesis de cicloolefinas - Google Patents

Compuestos de fosforo que retardan la polimerizacion por metatesis de cicloolefinas

Info

Publication number
MX166331B
MX166331B MX018921A MX1892189A MX166331B MX 166331 B MX166331 B MX 166331B MX 018921 A MX018921 A MX 018921A MX 1892189 A MX1892189 A MX 1892189A MX 166331 B MX166331 B MX 166331B
Authority
MX
Mexico
Prior art keywords
polymerization
metatesis
cyclloolefin
delaying
phosphorus compounds
Prior art date
Application number
MX018921A
Other languages
English (en)
Inventor
Albert Shelton Matlack
Original Assignee
Hercules Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules Inc filed Critical Hercules Inc
Publication of MX166331B publication Critical patent/MX166331B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La presente invención se refiere a un procedimiento para preparar artículos moldeados poliméricos termoreducibles, en donde una corriente de reacción líquida que comprende una cicloolefina no conjugada de anillo esforzado polimerizable con metatésis, un catalizador de polimerización por metatésis, un activador que se selecciona del grupo que consiste de compuestos de alquilaluminio, alquilzinc y alquilestaño, y un moderador de régimen de reacción se cargan en un molde en donde la polimerización se lleva acabo, está caracterizado porque el moderador de régimen de reacción comprende: (X-)(Y-)(Z-)PW en donde X, Y y Z representan grupos alquilo, cicloalquilo, alicíclico, arilo, aralquilo, alcarilo, alcoxi, alquiltio, ariloxi, ariltio, o tiofeno, y W representa oxígeno, azufre o nada.
MX018921A 1988-12-30 1989-12-27 Compuestos de fosforo que retardan la polimerizacion por metatesis de cicloolefinas MX166331B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/292,147 US4933402A (en) 1988-12-30 1988-12-30 Phosphorus compounds that delay the metathesis polymerization of cycloolefins

Publications (1)

Publication Number Publication Date
MX166331B true MX166331B (es) 1992-12-29

Family

ID=23123434

Family Applications (1)

Application Number Title Priority Date Filing Date
MX018921A MX166331B (es) 1988-12-30 1989-12-27 Compuestos de fosforo que retardan la polimerizacion por metatesis de cicloolefinas

Country Status (7)

Country Link
US (1) US4933402A (es)
EP (1) EP0376198A3 (es)
JP (1) JP2771289B2 (es)
KR (1) KR0159762B1 (es)
AU (1) AU616830B2 (es)
BR (1) BR8906864A (es)
MX (1) MX166331B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5082909A (en) * 1990-10-12 1992-01-21 Hercules Incorporated Pure tungsten oxyphenolate complexes as DCPD polymerization catalysts
EP0575007A2 (en) * 1992-06-18 1993-12-22 Shell Internationale Researchmaatschappij B.V. Bulk polymerization of norbornene derivatives
USH1388H (en) * 1992-12-23 1994-12-06 Hercules Incorporated Polyolefin polymer and method of making same
CA2112146A1 (en) * 1992-12-23 1994-06-24 Nitya P. Khasat Polydicyclopentadiene having improved stability and toughened with polymeric particles
US5410004A (en) * 1994-01-24 1995-04-25 Arizona Chemical Company Thermal polymerization of dicyclopentadiene
US5998326A (en) 1997-05-23 1999-12-07 Ciba Specialty Chemicals Corp. Two-component catalyst for ROMP
US7745573B2 (en) * 2006-02-17 2010-06-29 Polychip Pharmaceuticals Pty Ltd. Conotoxin analogues and methods for synthesis of intramolecular dicarba bridge-containing peptides
EP1984385A4 (en) * 2006-02-17 2012-03-28 Univ Monash PROCESS FOR SYNTHESIS OF DICARBABRICES IN ORGANIC COMPOUNDS
US7538190B2 (en) * 2006-02-17 2009-05-26 Polychip Pharmaceuticals Pty Ltd Methods for the synthesis of two or more dicarba bridges in organic compounds
FR3088641B1 (fr) 2018-11-16 2021-11-19 Demeta Procede de metathese d'olefines utilisant un catalyseur en presence d'un activateur et d'un agent retardateur

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2106301A1 (de) * 1971-02-10 1972-08-17 Bayer Verfahren zur Polymerisation von Cycloalkenen
JPS50160400A (es) * 1974-06-19 1975-12-25
JPS51111300A (en) * 1975-03-26 1976-10-01 Hitachi Chem Co Ltd Preparation of thermoplastic resins
JPS5825689B2 (ja) * 1975-08-27 1983-05-28 昭和電工株式会社 カイカンジユウゴウタイノセイゾウホウホウ
US4080491A (en) * 1975-08-27 1978-03-21 Showa Denko K.K. Process of producing ring-opening polymerization products
JPS5233000A (en) * 1975-09-10 1977-03-12 Hitachi Chem Co Ltd Process for preparing thermoplastic resins
JPS5245696A (en) * 1975-10-08 1977-04-11 Japan Synthetic Rubber Co Ltd Preparation of copolymer with norornene derivative
JPS5487800A (en) * 1977-12-26 1979-07-12 Japan Synthetic Rubber Co Ltd Preparation of thermoplastic resin having improved heat resistance
US4727125A (en) * 1986-11-03 1988-02-23 Hercules Incorporated Thermally activated two component metathesis catalyst system
EP0280247A3 (en) * 1987-02-27 1989-07-19 Hercules Incorporated Metathesis polymerization
US4822839A (en) * 1987-11-25 1989-04-18 Hercules Incorporated Polyunsaturated hydrocarbon polymer-compatible antioxidant compositions
US4812543A (en) * 1988-03-01 1989-03-14 Hercules Incorporated Co-polymer-bound amine antioxidants
US4883849A (en) * 1988-12-30 1989-11-28 Hercules Incorporated Nitrogen compounds that delay the metathesis polymerization of cycloolefins

Also Published As

Publication number Publication date
KR910011909A (ko) 1991-08-07
EP0376198A2 (en) 1990-07-04
AU4737089A (en) 1990-07-05
BR8906864A (pt) 1990-09-25
KR0159762B1 (ko) 1999-01-15
US4933402A (en) 1990-06-12
EP0376198A3 (en) 1990-12-05
JP2771289B2 (ja) 1998-07-02
JPH02215827A (ja) 1990-08-28
AU616830B2 (en) 1991-11-07

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