KR870007271A - 에테르 카복실레이트 세제 증강제 및 이의 제조방법 - Google Patents

에테르 카복실레이트 세제 증강제 및 이의 제조방법 Download PDF

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KR870007271A
KR870007271A KR870000722A KR870000722A KR870007271A KR 870007271 A KR870007271 A KR 870007271A KR 870000722 A KR870000722 A KR 870000722A KR 870000722 A KR870000722 A KR 870000722A KR 870007271 A KR870007271 A KR 870007271A
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tartrate
salt
acid
calcium
salts
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KR950004821B1 (ko
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딘 부쉬 로드니
스테드맨 코너 다니엘
와인 하인즈맨 스테펜
네일 맥케이 래리
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원본미기재
더 프록터 앤드 갬블 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2089—Ether acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/235—Saturated compounds containing more than one carboxyl group
    • C07C59/305—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
    • C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
    • C08G65/2624—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing aliphatic amine groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Emergency Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Endoscopes (AREA)
  • Saccharide Compounds (AREA)

Abstract

내용 없음

Description

에테르 카복실레이트 세제 증강제 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 물질을 포함한, 여러가지 증강제(builder) 물질의 용액을 적정하는 용액중의 유리 칼슘이온의 농도를 나타낸 그래프.

Claims (20)

  1. (a) 약 1 내지 99중량%의 일반식(Ⅰ)의 타르트레이트 모노 숙시네이트 성분, 및 (b) 약 1 내지 99중량%의 일반식(Ⅱ)의 타르트레이트 디숙시네이트 성분으로 구성되는, 세제 제제중에서 증강제로서 사용하기에 적절한 에테르카복실레이트 조성물.
    상기식에서, (X)는 수소 또는 염-형성 양이온이다.
  2. 제1항에 있어서, 타르트레이트 모노 숙시네이트 성분 대 타르트레이트 디숙시네이트 성분의 중량비가 약 97 : 3 내지 20 : 80인 조성물.
  3. 제2항에 있어서, 타르트레이트 모노수시네이트 및 타르트레이트 디숙시네이트성분이 그의 완전히 중화된 나트륨염, 칼륨염, 모노에탄올아민염 또는 트리에탄올아민염의 형태인 조성물.
  4. 제3항에 있어서, 타르트레이트 모노숙시네이트 성분이 조성물의 약 10 내지 98중량%를 차지하며, 타르트레이트 디숙시네이트 성분은 조성물의 약 2 내지 90중량%를 차지하고, 타르트레이트 모노숙시네이트 대 타르트레이트 디숙시네이트의 중량비는 약 95 : 5 내지 40 : 60인 조성물.
  5. 제3항에 있어서, 몰, 말레이트염, 말리에이트염, 타르트레이트염, 푸마레이트염, 칼슘염 및 상기 임의의 성분의 배합물로 구성되는 그룹중에서 선택된 약 70중량%까지의 추가의 성분을 함유하는 조성물.
  6. 제5항에 있어서, 조성물에 존재하는 타르트레이트 모노숙시네이트 및 타르트레이트 디숙시네이트의 총 몰을 기준으로 약 10몰% 이하의 칼슘을 함유하는 조성물.
  7. 제6항에 있어서, 타르트레이트 모노숙시네이트 대 타르트레이트 디숙시네이트의 중량비가 약 95 : 5 내지 40 : 60인 조성물.
  8. 하기 일반식(Ⅰ)의 타르트레이트 모노숙신산 또는 이의 염.
    상기식에서, X는 수소 또는 염-형성 양이온이다.
  9. 하기 일반식(Ⅱ)의 타르트레이트 디숙신산 또는 이의 염.
    상기식에서 X는 수소 또는 염-형성 양이온이다.
  10. (a) (ⅰ) 말레산 대 타르타르산의 몰비 약 0.5 : 1 내지 약 8 : 1의 말레산 및 타르타르산 ;
    (ⅱ) 말레산 및 타르타르산의 총 몰에 대한 칼슘의 몰비율이 1 미만이고, 칼슘 대 타르타르산의 몰비가 약 0.1 : 1 내지 2.0 : 1 범위가 되도록 하는 양의 칼슘 양이온 공급원 ; 및
    (ⅲ) 말레산 몰수＋타르타르산 몰수-칼슘 몰수에 대한 일가 양이온의 몰비가 약 2.1 : 1 내지 3.8 : 1의 범위가 되도록 하는 양의 일가 양이온의 수산화물로 이루어지는 중화제를 혼합하여 형성된 과-중화 혼합물에 상응하는, 총 약 20 내지 60중량%의 칼슘 및 말레산과 타르타르산의 일가 양이온 염으로 구성되는 수성 반응 혼합물을 형성시키고,
    (b) 상기 수성 반응 혼합물을
    (ⅰ) 하기 일반식(Ⅰ)의 타르트레이트 모노숙시네이트 및
    (ⅱ) 하기 일반식(Ⅱ)의 타르트레이트 디숙시네이트의 반응 생성 혼합물을 형성하기에 충분한 시간동안 약 20 내지 120℃의 온도에서 유지시키고,
    (c) 상기 반응 생성 혼합물의 칼슘 함량을, 칼슘 대 타르트레이트 숙시네이트 반응 생성물의 몰비가 약 1 : 10 미만이 되도록 감소시킴을 특징으로 하는, 세제 증강제로서 유용한 에테르 카복실레이트의 배합물의 제조방법.
    상기식에서 X는 염-형성 양이온이다.
  11. 제10항에 있어서, 반응혼합물이 말레산 및 타르타르산의 상기 염을 약 40 내지 55중량%로 함유하는 방법.
  12. 제11항에 있어서,
    (a) 말레산염이 나트륨 및 칼륨 말리에이트로부터 선택되며 ;
    (b) 타르타르산 염이 나트륨 및 칼륨 타르트레이트로부터 선택되고 ;
    (c) 칼슘 양이온이 수산화칼슘에 의해 제공되며 ;
    (d) 일가 양이온-함유 중화제가 수산화나트륨, 수산화칼륨 및 수산화암모늄으로부터 선택되는 방법.
  13. 제12항에 있어서, 말레산 염 및 타르타르산염 반응물이 반응혼합물 자체내에서 형성되는 방법.
  14. 제12항에 있어서,
    (a) 반응혼합물의 형성에 사용된 말레산 대 타르타르산의 몰비가 약 0.9 : 1 내지 1.2 : 1이며 ;
    (b) 반응혼합물의 형성에 사용된 칼슘 양이온 대 타르타르산의 몰비가 약 0.8 : 1 내지 1.5 : 1인 방법.
  15. 제12항에 있어서, 칼슘 대 타르트레이트 숙시네이트 반응생성물의 몰비를 반응혼합물에 알칼리금속 카보네이트, 알칼리금속 비카보네이트 및 이의 혼합물로부터 선택된 침전화제를 가함으로써, 약 1 : 20 미만으로 감소시키는 방법.
  16. 제12항에 있어서, 수성 반응 혼합물을 약 50 내지 80℃의 온도에서 약 0.5 내지 10시간동안 유지시키는 방법.
  17. 약 0.5 내지 98중량%의 계면활성제와,
    (a) 하기 일반식(Ⅰ)의 타르트레이트 모노숙신산 또는 이의 염,
    (b) 하기 일반식(Ⅰ)의 타르트레이트 디숙신산 또는 이의 염, 및
    (c) 타르트레이트 모노숙신산 또는 염 대 타르트레이트 디숙신산 또는 염의 중량비가 약 97 : 3 내지 20 : 80인, 타르트레이트 모노숙신산 또는 염과 타르트레이트 디숙신산 또는 염의 배합물로 구성되는 그룹 중에서 선택된 약 2 내지 99.5중량%의 증강제 성분으로 이루어지는 세제조성물.
    상기식에서 X는 수소 또는 염-형성 양이온이다.
  18. 제17항에 있어서, 추가의 세제증강제, 킬레이트화제, 효소직물 증백제 및 광택제, 거품조절제, 용매, 굴수제(hydrotropes), 표백제, 표백전구체, 완충제, 오물제거/재침착방지제, 오물이탈제, 직물연화제, 방향제, 용매, 유백제 및 상기 추가성분의 배합물로 구성되는 그룹으로부터 선택된 추가의 성분 약 5 내지 95중량%을 함유하는 세제조성물.
  19. (A) (ⅰ) 하기 일반식(Ⅰ)의 타르트레이트 모노숙신산 또는 이의 염 ;
    (ⅱ) 하기 일반식(Ⅱ)의 타르트레이트 디숙신산 또는 이의 염 ; 및
    (ⅲ) 타르트레이트 모노숙신산 또는 염 대 타르트레이트 디숙신산 또는 염의 중량비가 약 97 : 3 내지 20 : 80인 타르트레이트 모노숙신산 또는 염과 타르트레이트 디숙신산 또는 염의 배합물로 구성되는 그룹으로부터 선택된, 약 2 내지 99.5중량%의 증강제 성분,
    (B) 계면활성제, 추가의 세제증강제, 킬레이트화제, 효소, 직물 증백제 및 광택제, 거품조절제, 용매, 골수제, 표백제, 표백 전구체, 완충제, 오물 제거/재침착 방지제, 오물 이탈제, 직물 연화제, 방향제, 착색제, 유백제 및 상기 세탁보조제의 배합물로 구성되는 그룹중에서 선택된, 약 0.5 내지 98중량%의 세탁보조제로 이루어지는 세탁용 부가조성물.
    상기식에서 X는 수소 또는 염-형성 양이온이다.
  20. 제19항에 있어서,
    (A) 증강제 성분이 나트륨 타르트레이트 모노숙시네이트 및 나트륨 타르트레이트 디숙시네이트의 배합물로 이루어지며 ;
    (B) 세탁 보조제가 계면활성제, 표백제, 표백 전구체, 효소 및 이들 세탁 보조제의 배합물로부터 선택되는 세탁용 부가 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870000722A 1986-01-30 1987-01-30 에테르 카복실레이트 세제 증강제 및 이의 제조방법 KR950004821B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/823,909 US4663071A (en) 1986-01-30 1986-01-30 Ether carboxylate detergent builders and process for their preparation
US823909 1986-01-30
US823,909 1986-01-30

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KR870007271A true KR870007271A (ko) 1987-08-18
KR950004821B1 KR950004821B1 (ko) 1995-05-13

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US (1) US4663071A (ko)
EP (1) EP0232114B1 (ko)
JP (1) JPS62253693A (ko)
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CN (1) CN1008635B (ko)
AT (1) ATE62505T1 (ko)
AU (1) AU581608B2 (ko)
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IE (1) IE870233L (ko)
MX (1) MX165540B (ko)
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AU6815087A (en) 1987-08-06
DK47487D0 (da) 1987-01-29
EP0232114A3 (en) 1987-12-02
GB8701824D0 (en) 1987-03-04
FI870420A (fi) 1987-07-31
PH23097A (en) 1989-04-10
US4663071A (en) 1987-05-05
ATE62505T1 (de) 1991-04-15
EP0232114B1 (en) 1991-04-10
CN1008635B (zh) 1990-07-04
FI870420A0 (fi) 1987-01-30
CA1293419C (en) 1991-12-24
KR950004821B1 (ko) 1995-05-13
MX165540B (es) 1992-11-19
IE870233L (en) 1987-07-30
HK18193A (en) 1993-03-12
CN87101893A (zh) 1987-09-16
GB2185981B (en) 1990-03-14
JPS62253693A (ja) 1987-11-05
DE3769161D1 (de) 1991-05-16
AU581608B2 (en) 1989-02-23
DK47487A (da) 1987-07-31
US4663071B1 (ko) 1992-04-07
GB2185981A (en) 1987-08-05
GR3001754T3 (en) 1992-11-23
SG120992G (en) 1993-01-29
DK30694A (da) 1994-03-16
EP0232114A2 (en) 1987-08-12

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