KR870006093A - α-올레핀 중합용 고체촉매성분 및 그 제조방법 - Google Patents

α-올레핀 중합용 고체촉매성분 및 그 제조방법 Download PDF

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Publication number
KR870006093A
KR870006093A KR860010404A KR860010404A KR870006093A KR 870006093 A KR870006093 A KR 870006093A KR 860010404 A KR860010404 A KR 860010404A KR 860010404 A KR860010404 A KR 860010404A KR 870006093 A KR870006093 A KR 870006093A
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South Korea
Prior art keywords
reaction
olefin polymerization
catalyst component
solid catalyst
manufacturing
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KR860010404A
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English (en)
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KR910004484B1 (ko
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히로시 시미즈
아끼히로 사이또오
도시히로 우와이
마사미 다찌바나
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노기 사다오
짓소 가부시끼가이샤
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Publication of KR870006093A publication Critical patent/KR870006093A/ko
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Publication of KR910004484B1 publication Critical patent/KR910004484B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908—Containing catalyst of specified particle size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909—Polymerization characterized by particle size of product

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

α－올레핀 중합용 고체 촉매성분 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
본 발명에 따른 α－올레핀 중합용 촉매를 사용하여 프로필렌을 중합시켜 수득된 중합체 입자의 절단면의 확대도(현미경 사진을 스켓치한 것)
1 : 절단면
2 : 속이 빈 부분
3 : 외면

Claims (4)

  1. 4염화티탄에 대해, 교반소요동력 250kw/m3이하의 교반하에서 유기알루미늄 화합물(A )과 전자공여체(B1)의 반응 생성물(Ⅰ)을, 0 내지 70℃에서 1 내지 10시간 첨가하여 반응시켜 수득된 고체 생성물(Ⅱ)에, 다시 전자공여체(B2) 및 전자수용체(E)를 반응시켜 고체 생성물(Ⅲ)으로 하는 것을 특징으로 하는 α－올레핀 중합용 고체 촉매성분의 제조방법.
  2. 제1항에 있어서, 불활성 용매로 희석된 4염화티탄을 사용하는 제조방법.
  3. 제1항에 있어서, 반응 생성물(Ⅰ)의 첨가가 끝난 후의 반응혼합물을 첨가시의 온도 및 교반조건하에서 0.5 내지 3시간 유지한 후, 다시 50 내지 90℃에서 5분 내지 3시간 교반하는 제조방법.
  4. 제1항에 있어서, 유기알루미늄 화합물(A) 1몰에 대해, 1 내지 4몰의 전자공여체를 0.5 내지 3ℓ의 불활성 용매의 존재하에 －10 내지 50℃에서 30초 내지 5시간 반응시켜 수득한 반응생성물(Ⅰ)을 사용하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860010404A 1985-12-05 1986-12-05 α-올레핀 중합용 고체 촉매성분 및 그 제조방법 KR910004484B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP60273649A JPS62209104A (ja) 1985-12-05 1985-12-05 α−オレフイン重合用固体触媒成分及びその製造方法
JP273649 1985-12-05

Publications (2)

Publication Number Publication Date
KR870006093A true KR870006093A (ko) 1987-07-09
KR910004484B1 KR910004484B1 (ko) 1991-06-29

Family

ID=17530627

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860010404A KR910004484B1 (ko) 1985-12-05 1986-12-05 α-올레핀 중합용 고체 촉매성분 및 그 제조방법

Country Status (12)

Country Link
US (1) US4724225A (ko)
EP (1) EP0229413B1 (ko)
JP (1) JPS62209104A (ko)
KR (1) KR910004484B1 (ko)
CN (1) CN1010782B (ko)
AU (1) AU594990B2 (ko)
BR (1) BR8606106A (ko)
CA (1) CA1283396C (ko)
CS (1) CS269990B2 (ko)
DE (1) DE3678134D1 (ko)
HU (1) HU204861B (ko)
MX (1) MX168632B (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2591602B1 (fr) * 1985-12-18 1988-02-26 Atochem Procede de traitement de catalyseurs spheriques de polymerisation des olefines. application du catalyseur obtenu a la polymerisation des olefines.
US5231119A (en) * 1990-04-27 1993-07-27 Himont Incorporated Crystalline olefin polymers and copolymers in the form of spherical particles at high porosity
JP3016880B2 (ja) * 1991-02-01 2000-03-06 三菱化学株式会社 フィルム成形用高結晶性ポリプロピレン
ATE291059T1 (de) 1992-11-13 2005-04-15 Cryovac Inc Wärmeschrumpfbare, durch single-site-katalyse hergestellte copolymere enthaltende folien.
JP3471099B2 (ja) * 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法
US6533988B2 (en) 1995-05-02 2003-03-18 Borealis Technology Oy Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology
CZ34998A3 (cs) * 1997-02-17 1999-08-11 Pcd Polymere Gesellschaft M. B. H. Způsob přípravy pevného nosiče pro katalyzátory polymerace olefinů
JP2004509201A (ja) 2000-09-15 2004-03-25 バセルテック　ユーエスエイ　インコーポレイテッド オレフィンポリマーに対する添加物の押出成形されていない分散体および濃縮物
CN113845613B (zh) * 2021-09-29 2023-01-06 天津华聚化工科技有限公司 一种高纯度超高分子量聚乙烯树脂及其生产工艺
CN115260490B (zh) * 2022-08-18 2023-07-25 井冈山大学 一种电子给体-受体二维共轭有机框架材料及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS591723B2 (ja) * 1980-01-17 1984-01-13 チッソ株式会社 α−オレフイン重合体を製造する方法
JPS5928573B2 (ja) * 1980-02-05 1984-07-13 チッソ株式会社 α−オレフイン重合体の製造方法
JPS6023764B2 (ja) * 1980-02-27 1985-06-10 チッソ株式会社 α−オレフイン重合体を製造する方法
JPS5823806A (ja) * 1981-08-04 1983-02-12 Chisso Corp α−オレフイン重合体を製造する方法
JPS5817104A (ja) * 1981-07-23 1983-02-01 Chisso Corp α−オレフイン重合体の製造方法
CA1185400A (en) * 1981-07-23 1985-04-09 Akihiro Sato PROCESS FOR PRODUCING .alpha.-OLEFIN POLYMERS
JPH0672166B2 (ja) * 1984-07-06 1994-09-14 チッソ株式会社 α―オレフィン重合用固体触媒成分およびその製造法

Also Published As

Publication number Publication date
AU594990B2 (en) 1990-03-22
US4724225A (en) 1988-02-09
CN1010782B (zh) 1990-12-12
CA1283396C (en) 1991-04-23
CS269990B2 (en) 1990-05-14
AU6575686A (en) 1987-06-11
CS895586A2 (en) 1989-09-12
HUT44585A (en) 1988-03-28
BR8606106A (pt) 1987-09-15
KR910004484B1 (ko) 1991-06-29
MX168632B (es) 1993-06-02
JPS62209104A (ja) 1987-09-14
HU204861B (en) 1992-02-28
EP0229413A1 (en) 1987-07-22
CN86108794A (zh) 1987-07-29
EP0229413B1 (en) 1991-03-13
DE3678134D1 (de) 1991-04-18

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