KR940005563A - 1,4-디아미노안트라퀴논-2,3-디술폰산 및 1,4-디아미논안트라퀴논-2,3-디니트릴의 제조방법 - Google Patents
1,4-디아미노안트라퀴논-2,3-디술폰산 및 1,4-디아미논안트라퀴논-2,3-디니트릴의 제조방법 Download PDFInfo
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- KR940005563A KR940005563A KR1019930012243A KR930012243A KR940005563A KR 940005563 A KR940005563 A KR 940005563A KR 1019930012243 A KR1019930012243 A KR 1019930012243A KR 930012243 A KR930012243 A KR 930012243A KR 940005563 A KR940005563 A KR 940005563A
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- South Korea
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- organic solvent
- diaminoanthraquinone
- reacting
- inert organic
- diamino
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
- C07C309/38—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems formed by at least three rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/22—Dyes with unsubstituted amino groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/16—Preparation of carboxylic acid nitriles by reaction of cyanides with lactones or compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/22—Dyes with unsubstituted amino groups
- C09B1/24—Dyes with unsubstituted amino groups sulfonated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/24—Anthracenes; Hydrogenated anthracenes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
비활성 유기 용매중에서, 1,4-디아미노-2,3-디할로안트라퀴톤(Ⅱ)을 붕산과 반응시키고, 생성된 반응 생성물(Ⅱa)을 아황산염 수용액과 더 반응시킴에 의한 1,4-디아미노안트라퀴논-2,3-디술폰산(Ⅰ)의 제조방법에 관한것이며, 여기에서 사용되는 비활성 유기 용매는 130℃ 이상의 비점 및 0.95g/㎤이하의 밀도를 갖는 비극성 용매이다.
본 발명은 또한, 상기 1,4-디아미노안트라퀴논-2,3-디술폰산(Ⅰ)을 시안화물과 반응시킴에 의한 1,4-디아미노안트라퀴논-2,3-디니트릴(Ⅲ)의 제조방법에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 비활성 유기 용매로서 130℃ 이상의 비점 및 0.95g/㎤이하의 밀도를 갖는 비극성 용매를 사용하는 포함하여, 비활성 유기 용매중에서, 1,4-디아미노-2,3-디할로안트라퀴논(Ⅱ)을 붕산과 반응시키고, 생성된 반응 생성물(Ⅱa)을 아황산염 수용액과 더 반응시킴에 의한 1,4-디아미노안트라퀴논-2,3-디술폰산(Ⅰ)의 제조방법.
- 제1항에 있어서, 사용되는 용매가 알킬벤젠 또는 알킬벤젠 혼합물임을 특징으로 하는 방법.
- 제1항에 있어서, 반응 생성물(Ⅱa)의 중간 생성물 단리없이, 생성된 반응 혼합물의 형태로 아황산염과 반응하고, 유기 용매가 상분리에 의해 제거됨을 특징으로 하는 방법.
- 제1항에 있어서, 사용되는 1,4-디아미노-2,3-디할로안트라퀴논(Ⅱ)이 1,4-디아미노-2,3-디클로로안트라퀴논 또는 1,4-디아미노-2,3-디브로모안트라퀴논임을 특징으로 하는 방법.
- 단계(a)에서 비활성 유기 용매로서 130℃ 이상의 비점 및 0.95g/㎤이하의 밀도를 갖는 비극성 용매를 사용하는 것을 포함하여, (a)비활성 유기 용매 중에서, 1,4-디아미노-2,3-디할로안트라퀴논(Ⅱ)을 붕산과 반응시키고, 생성된 반응 생성물(Ⅱa)을 아황산염 수용액과 더 반응시키고, (b)계속해서, 생성된 1,4-디아미노안트라퀴논-2,3-디술폰산(Ⅰ)을 시안화물과 반응시키는 것으로 이루어지는 1,4-디아미노안트라퀴논-2,3-디니트릴(Ⅲ)의 제조방법.
- 제5항에 있어서, 사용되는 용매가 알킬벤젠 또는 알킬벤젠 혼합물임을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4222302A DE4222302A1 (de) | 1992-07-08 | 1992-07-08 | Verfahren zur Herstellung von 1,4-Diaminoanthrachinon-2,3-disulfonsäure und 1,4-Diaminoanthrachinon-2,3-dinitril |
DEP4222302.4 | 1992-07-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940005563A true KR940005563A (ko) | 1994-03-21 |
KR100268980B1 KR100268980B1 (en) | 2000-10-16 |
Family
ID=6462681
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930012243A KR100268980B1 (en) | 1992-07-08 | 1993-07-01 | Method to produce 1,4-diaminoanthraquinone-2,3-disulphonic acid and 1,4-diaminoanthraquinone-2,3-dinitrile |
Country Status (7)
Country | Link |
---|---|
US (1) | US5386042A (ko) |
EP (1) | EP0582079B1 (ko) |
JP (1) | JPH06179647A (ko) |
KR (1) | KR100268980B1 (ko) |
CN (2) | CN1052719C (ko) |
DE (2) | DE4222302A1 (ko) |
ES (1) | ES2098596T3 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1069896C (zh) * | 1997-01-28 | 2001-08-22 | 常州市合成材料厂 | 1,4-二氨基-2,3-二氰基蒽醌的制备工艺 |
CN103242208B (zh) * | 2013-05-03 | 2015-01-07 | 盐城市瓯华化学工业有限公司 | 烟酸法制备1,4-二氨基蒽醌-2,3-二磺酸的工艺 |
CN115521636B (zh) * | 2022-10-24 | 2023-06-30 | 浙江博澳新材料股份有限公司 | 一种含双氰基耐晒型蒽醌分散染料及其制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1975386A (en) * | 1932-03-26 | 1934-10-02 | Gen Aniline Works Inc | Process of preparing 1.4-diamino-anthraquinone-2.3-disulphonic acid |
US2795593A (en) * | 1953-07-22 | 1957-06-11 | Du Pont | Process for preparing alkali metal salts of 1, 4-diamino-2, 3-anthraquinone-disulfonic acid |
DE2524748C3 (de) * | 1975-06-04 | 1980-06-04 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von 1 ^-Diaminoanthrachinon^-dinitril |
DE2846622A1 (de) * | 1978-10-26 | 1980-05-08 | Bayer Ag | Verfahren zur herstellung von 1,4-diaminoanthrachinon-2,3-disulfonsaeure |
JPS57158261A (en) * | 1981-03-26 | 1982-09-30 | Sumitomo Chem Co Ltd | Preparation of 1,4-diamino anthraquinone-2,3-disulfonic acid |
JPS58172364A (ja) * | 1982-04-02 | 1983-10-11 | Sumitomo Chem Co Ltd | 1,4−ジアミノアントラキノン−2,3−ジスルホン酸の製造方法 |
GB2185035B (en) * | 1986-01-07 | 1989-11-08 | Sumitomo Chemical Co | Process for preparing 1,4-diaminoanthraquinone-2,3-disubstituted compound |
-
1992
- 1992-07-08 DE DE4222302A patent/DE4222302A1/de not_active Withdrawn
-
1993
- 1993-06-26 EP EP93110227A patent/EP0582079B1/de not_active Expired - Lifetime
- 1993-06-26 ES ES93110227T patent/ES2098596T3/es not_active Expired - Lifetime
- 1993-06-26 DE DE59305709T patent/DE59305709D1/de not_active Expired - Fee Related
- 1993-07-01 KR KR1019930012243A patent/KR100268980B1/ko not_active IP Right Cessation
- 1993-07-07 JP JP5167815A patent/JPH06179647A/ja not_active Withdrawn
- 1993-07-08 US US08/088,740 patent/US5386042A/en not_active Expired - Fee Related
- 1993-07-08 CN CN93108509A patent/CN1052719C/zh not_active Expired - Fee Related
-
1998
- 1998-07-03 CN CN98115677A patent/CN1079392C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0582079A1 (de) | 1994-02-09 |
DE4222302A1 (de) | 1994-01-13 |
DE59305709D1 (de) | 1997-04-17 |
EP0582079B1 (de) | 1997-03-12 |
JPH06179647A (ja) | 1994-06-28 |
ES2098596T3 (es) | 1997-05-01 |
CN1052719C (zh) | 2000-05-24 |
CN1079392C (zh) | 2002-02-20 |
KR100268980B1 (en) | 2000-10-16 |
US5386042A (en) | 1995-01-31 |
CN1218798A (zh) | 1999-06-09 |
CN1085210A (zh) | 1994-04-13 |
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