KR850700284A - 가압 수형원자로의 오염 제거방법 - Google Patents
가압 수형원자로의 오염 제거방법Info
- Publication number
- KR850700284A KR850700284A KR1019850700286A KR850700286A KR850700284A KR 850700284 A KR850700284 A KR 850700284A KR 1019850700286 A KR1019850700286 A KR 1019850700286A KR 850700286 A KR850700286 A KR 850700286A KR 850700284 A KR850700284 A KR 850700284A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- ozone
- decontamination
- concentration
- less
- Prior art date
Links
- 238000005202 decontamination Methods 0.000 title claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims 5
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims 8
- 238000000034 method Methods 0.000 claims 7
- 239000007800 oxidant agent Substances 0.000 claims 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims 5
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims 4
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 3
- 230000002378 acidificating effect Effects 0.000 claims 3
- 230000003647 oxidation Effects 0.000 claims 3
- 238000007254 oxidation reaction Methods 0.000 claims 3
- 230000001590 oxidative effect Effects 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 2
- 238000005260 corrosion Methods 0.000 claims 2
- 230000007797 corrosion Effects 0.000 claims 2
- 230000003588 decontaminative effect Effects 0.000 claims 2
- 238000004090 dissolution Methods 0.000 claims 2
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 239000012047 saturated solution Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/001—Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
- G21F9/002—Decontamination of the surface of objects with chemical or electrochemical processes
- G21F9/004—Decontamination of the surface of objects with chemical or electrochemical processes of metallic surfaces
Landscapes
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- High Energy & Nuclear Physics (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Detergent Compositions (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 가압 수형원자로의 일차계 표면으로부터 방사성 핵종으로 오염된 산-불용성 부식생성물을 오염 제거시키는 방법, 특히 오염된 표면을 산용액 중에서 산화제와 접촉시키고 산화에 의해 산용해성으로 만든 부식 생성물을 용해시킴으로써 크롬-니켈-철 합금으로부터 신화크롬(III)을 오염 제게시키는 방법에 있어서, pH7 이하이고 질산세륨, 크롬산 및 오존을 오염제거가 얻어지도록 하는 농도로 포함하는 물-기제의 산화제로 산화를 수행하는 것을 특징으로 하는 오염 제거방법.
- 제1항에 있어서, 산화제는 포화용액 및 분산된 형태로 질산세륨과 크롬산 및 오존의 산성수용액인 것을 특징으로 하는 오염 제거방법.
- 제1항에 있어서, 산화제는 2-상 오존가스-수성 혼합물인데, 여기서 기체상의 오존은 질산세륨과 크롬산의 산 수용액에 분산되어 있는것을 특징으로 하는 오염 제거방법.
- 제1항에 내지 제3항중 어느 하나에 있어서, 산화 및 용해는 하나의 같은 단계로 수행되는 것을 특징으로 하는 오염 제거방법.
- 제1항 내지 제4항중 어느 하나에 있어서, 산화 및 용해는 약 60℃ 이하의 온도, 바람직하게는 약 25℃ 이하 그리고 특히 바람직하게는 약 20℃ 이하의 온도에서 수행되는 것을 특징으로 하는 오염 제거방법.
- 제1항 내지 제5항중 어느 아나에 있어서, 물-기제의 산화제는 질산으로 산성으로 만드는 것을 특징으로 하는 오염 제거방법.
- 제6항에 있어서, 물-기제의 산화제는 pH 값이 약 1인 산성으로 만드는 것을 특징으로 하는 오염 제거방법.
- 제1항 내지 제7항중 어느 하나에 있어서, 질산세륨의 농도는 0.01-50g/l, 바람직하게는 0.5-2g/l이고 크롬산의 농도는 0.01-50g/l, 바람직하게는 0.05-0.2g/l이고, 오존의 농도는 0.001-1g/l, 바람직하게는 0.005-0.015g/l인 것을 특징으로 하는 오염 제거방법.※참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8401336-6 | 1984-03-09 | ||
SE8401336A SE451915B (sv) | 1984-03-09 | 1984-03-09 | Forfarande for dekontaminering av tryckvattenreaktorer |
PCT/SE1985/000052 WO1985004279A1 (en) | 1984-03-09 | 1985-02-05 | Decontamination of pressurized water reactors |
Publications (1)
Publication Number | Publication Date |
---|---|
KR850700284A true KR850700284A (ko) | 1985-12-26 |
Family
ID=20355083
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850700286A KR850700284A (ko) | 1984-03-09 | 1985-02-05 | 가압 수형원자로의 오염 제거방법 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4704235A (ko) |
EP (1) | EP0174317B1 (ko) |
JP (1) | JPS61501338A (ko) |
KR (1) | KR850700284A (ko) |
DE (1) | DE3566591D1 (ko) |
ES (1) | ES8700784A1 (ko) |
SE (1) | SE451915B (ko) |
WO (1) | WO1985004279A1 (ko) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4913849A (en) * | 1988-07-07 | 1990-04-03 | Aamir Husain | Process for pretreatment of chromium-rich oxide surfaces prior to decontamination |
SE465142B (sv) * | 1988-08-11 | 1991-07-29 | Studsvik Ab | Foerfarande foer dekontaminering av korrosionsprodukter i kaernkraftsreaktorer |
US4812243A (en) * | 1988-10-06 | 1989-03-14 | Zimpro/Passavant Inc. | Process for treating caustic cyanide metal wastes |
FR2666523A1 (fr) * | 1990-09-12 | 1992-03-13 | Framatome Sa | Appareil de travail au laser, notamment pour la decontamination d'une conduite d'un reacteur nucleaire. |
US5035840A (en) * | 1990-10-01 | 1991-07-30 | Chemical Waste Management, Inc. | Process for cleaning trace metals from EDTA |
US5205999A (en) * | 1991-09-18 | 1993-04-27 | British Nuclear Fuels Plc | Actinide dissolution |
EP0575612B1 (en) * | 1991-12-24 | 1997-09-10 | Sovmestnoe Sovetsko-Kanadskoe Predpriyatie " Compomet Cantec" | Method for obtaining composite sorbents |
FR2687005B1 (fr) * | 1992-02-03 | 1994-10-21 | Framatome Sa | Procede et installation de decontamination de la partie primaire d'un generateur de vapeur usage d'un reacteur nucleaire a eau ordinaire sous pression. |
FR2706217A1 (fr) * | 1993-06-08 | 1994-12-16 | Framatome Sa | Procédé de remise en état d'un échangeur de chaleur de centrale nucléaire, notamment d'un échangeur de chaleur de circuit auxiliaire de refroidissement d'un réacteur nucléaire à l'arrêt. |
US5489735A (en) * | 1994-01-24 | 1996-02-06 | D'muhala; Thomas F. | Decontamination composition for removing norms and method utilizing the same |
US5473648A (en) * | 1994-04-18 | 1995-12-05 | General Electric Company | Decontamination process |
US5640703A (en) * | 1994-04-18 | 1997-06-17 | British Nuclear Fuels Plc | Treatment of solid wastes |
FR2730641B1 (fr) * | 1995-02-20 | 1997-03-14 | Commissariat Energie Atomique | Mousse de decontamination a l'ozone, et procede de decontamination utilisant cette mousse |
US5591270A (en) * | 1995-07-31 | 1997-01-07 | Corpex Technologies, Inc. | Lead oxide removal method |
US5678232A (en) * | 1995-07-31 | 1997-10-14 | Corpex Technologies, Inc. | Lead decontamination method |
US5724668A (en) * | 1995-11-07 | 1998-03-03 | Electronic Power Research Institute | Method for decontamination of nuclear plant components |
US5814204A (en) * | 1996-10-11 | 1998-09-29 | Corpex Technologies, Inc. | Electrolytic decontamination processes |
US6147274A (en) * | 1996-11-05 | 2000-11-14 | Electric Power Research Insitute | Method for decontamination of nuclear plant components |
US5805654A (en) * | 1997-04-08 | 1998-09-08 | Wood; Christopher J. | Regenerative LOMI decontamination process |
US5901368A (en) * | 1997-06-04 | 1999-05-04 | Electric Power Research Institute | Radiolysis-assisted decontamination process |
BE1011754A3 (fr) * | 1998-02-20 | 1999-12-07 | En Nucleaire Etabilissement D | Procede et installation de decontamination de surfaces metalliques. |
DE19818772C2 (de) * | 1998-04-27 | 2000-05-31 | Siemens Ag | Verfahren zum Abbau der Radioaktivität eines Metallteiles |
FR2792763B1 (fr) | 1999-04-26 | 2004-05-28 | Commissariat Energie Atomique | Procede de decontamination radioactive d'une paroi en acier et dispositif de decontamination radioactive |
EP1054413B1 (en) | 1999-05-13 | 2013-07-17 | Kabushiki Kaisha Toshiba | Method of chemically decontaminating components of radioactive material handling facility and system for carrying out the same |
JP2003098294A (ja) * | 2001-09-27 | 2003-04-03 | Hitachi Ltd | オゾンを用いた除染方法及びその装置 |
CN100577893C (zh) * | 2005-12-23 | 2010-01-06 | 中国辐射防护研究院 | 一种去除金属表面放射性污染的电解去污方法 |
US20100072059A1 (en) * | 2008-09-25 | 2010-03-25 | Peters Michael J | Electrolytic System and Method for Enhanced Radiological, Nuclear, and Industrial Decontamination |
DE102010028457A1 (de) * | 2010-04-30 | 2011-11-03 | Areva Np Gmbh | Verfahren zur Oberflächen-Dekontamination |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3803295A (en) * | 1972-03-06 | 1974-04-09 | Atomic Energy Commission | Method for removing iodine from nitric acid |
US3873362A (en) * | 1973-05-29 | 1975-03-25 | Halliburton Co | Process for cleaning radioactively contaminated metal surfaces |
CH619807A5 (ko) * | 1976-04-07 | 1980-10-15 | Foerderung Forschung Gmbh | |
US4172786A (en) * | 1978-09-29 | 1979-10-30 | Nasa | Ozonation of cooling tower waters |
US4287002A (en) * | 1979-04-09 | 1981-09-01 | Atomic Energy Of Canada Ltd. | Nuclear reactor decontamination |
US4437999A (en) * | 1981-08-31 | 1984-03-20 | Gram Research & Development Co. | Method of treating contaminated insoluble organic solid material |
SE435329B (sv) * | 1983-02-09 | 1984-09-17 | Studsvik Energiteknik Ab | Dekontaminering av tryckvattenreaktorer |
CA1229480A (en) * | 1983-07-12 | 1987-11-24 | Alexander P. Murray | Ozone oxidation of deposits in cooling systems of nuclear reactors |
-
1984
- 1984-03-09 SE SE8401336A patent/SE451915B/sv not_active IP Right Cessation
-
1985
- 1985-02-05 EP EP85900825A patent/EP0174317B1/en not_active Expired
- 1985-02-05 WO PCT/SE1985/000052 patent/WO1985004279A1/en active IP Right Grant
- 1985-02-05 US US06/789,958 patent/US4704235A/en not_active Expired - Lifetime
- 1985-02-05 KR KR1019850700286A patent/KR850700284A/ko not_active Application Discontinuation
- 1985-02-05 JP JP60500671A patent/JPS61501338A/ja active Granted
- 1985-02-05 DE DE8585900825T patent/DE3566591D1/de not_active Expired
- 1985-02-25 ES ES540671A patent/ES8700784A1/es not_active Expired
Also Published As
Publication number | Publication date |
---|---|
SE451915B (sv) | 1987-11-02 |
US4704235A (en) | 1987-11-03 |
JPH0549080B2 (ko) | 1993-07-23 |
ES8700784A1 (es) | 1986-10-16 |
DE3566591D1 (en) | 1989-01-05 |
WO1985004279A1 (en) | 1985-09-26 |
SE8401336D0 (sv) | 1984-03-09 |
SE8401336L (sv) | 1985-09-10 |
EP0174317A1 (en) | 1986-03-19 |
EP0174317B1 (en) | 1988-11-30 |
JPS61501338A (ja) | 1986-07-03 |
ES540671A0 (es) | 1986-10-16 |
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Legal Events
Date | Code | Title | Description |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |