KR850007623A - 플루오로화학약품 뷰렐조성물로 구성되는 섬유 후가공제 - Google Patents
플루오로화학약품 뷰렐조성물로 구성되는 섬유 후가공제 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
- C07C275/58—Y being a hetero atom
- C07C275/62—Y being a nitrogen atom, e.g. biuret
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
- Y10T442/2172—Also specified as oil repellent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
- Y10T442/2189—Fluorocarbon containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2221—Coating or impregnation is specified as water proof
- Y10T442/2246—Nitrogen containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2262—Coating or impregnation is oil repellent but not oil or stain release
- Y10T442/227—Fluorocarbon containing
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
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Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (29)
- 적어도 3개가 완전히 불화된 말단탄소를 지닌 하나 또는 그 이상의 일가 플루오로알리파틱기와, 최소한 하나의 산 또는 아미노부를 지닌 하나 또는 그 이상의 유기기와, 하나 또는 그 이상의 뷰레트부를 함유하는 유기용액 또는 수성유탁액인 플루오로화학약품 뷰레트조성물에서 상기의 기들은 헤테로 원자를 함유하는 그룹 또는 유기결합그룹에 의해 뷰레트부에 결합되어 있으며 이러한 조성물과 플루오로화학약품 뷰레트의 염이 함유되어 있는 것을 특징으로 하는 섬유 후가공제.
- 제1항에 있어서, 최소한 3개가 완전히 불화된 탄소를 지닌 하나 또는 그 이상의 일가 플루오로알리파틱기와 하나 또는 그 이상의 폴리(옥시알킬렌)부를 함유하는 플루오로알리파틱기 함유 폴리(옥시알킬렌)에 있어서, 상기의 기와 부들은 헤테로원자 함유 그룹 또는 유기결합 그룹에 의해 함께 결합되어 있는 것을 특징으로 하는 섬유후가공제.
- 제1항의 섬유후가공제로 처리하여 섬유물질에 방유성, 방수성, 방오성을 부여하는 것을 특징으로 하는 방법.
- 제1항의 섬유후가공제로 코팅한 방유성 및 방수성을 지닌 것을 특징으로 하는 섬유물질.
- 섬유를 제1항의 섬유후가공제와 접촉시킨 후 섬유상에 존재하는 상기의 액성조성물을 건조시키는 단계를 포함하여 섬유물질에 영구적인 방유성, 방수성, 방오성이 만들어지도록 하는 것을 특징으로 하는 방법.
- 제1항에 있어서, 상술된 풀루오로 화학약품 뷰레트은 하기식 또는 그 염으로 나타내는 것을 특징으로 하는 섬유 후가공제.
-
- 상기 식에서, 각각의 R1은 서로 같거나 서로 다르며, 이것은 최소한 하나의 R1이 유기기임을 조건으로 할때 말단일가 유기기와 수소에서 선택된 것이며, 이 유기기는 알킬기, 시클로알킬기, 아릴기와 이것의 조합물에서 선택된 것이며 R1은 최소한 하나의 플루오로 알리파틱기(Rf)를 포함하여 최소한 하나의 R1은 최소한 하나의 산 또는 아미노부를 함유하는 상기의 유기기이다.
- 제6항에 있어서, 상기의 뷰레트은 하기식으로 나타내는 것을 특징으로 하는 섬유후가공제.
-
- 상기식에서, B는인 뷰레트부이며; R2은 알킬, 시클로알킬, 아릴기와 이것들의 조합물에서 선택된 일가의 말단유기기로서 각각의 R2는 서로 같거나 또는 다르며, 최소한 하나의 R2또는 A가 최소한 하나의 플루오로알리파틱기(Rf)를 함유할 때 A는 이기의 유기결합그룹이며, X는 O, S 또는 NR3로서 여기서 R3는 수소 또는 저급알킬 그룹이며; R6는 1 내지 4 탄소수의 저급알킬그룹, 수소, 7 내지 13탄소수의 알알킬그룹에서 선택된 것이며, E는 프로톤산 또는 알킬화제에서 유도된 음이온이며, a는 0 또는 1, p는 0 또는 1, m은 0,1 또는 2이다.
- 제7항에 있어서, 상기의 R2는 n이 6 내지 12인 CnF2n+1이며; A는 -(-CH2-)6, -C6H3(CH3)-에서 선택된 것이며; X는 -O-또는 -NH-이며; Q는 b가 1 내지 6이며 R3가 1 내지 4 탄소수의 알킬그룹인 -(CH2-)b, -SO2NR3(CH2)|b-이며; p,m,a가 0인 것을 특징으로 하는 섬유후가공제.
- 제7항에 있어서, 상기의 R2는 n이 6 내지 12인 CnF2n+1이며; A는 -(-CH2-)6, -C6H3(CH3)-에서 선택된 것이며; X는 -O-또는 -NH-이며; Q는 b가 1 내지 6이며 R3가 1 내지 4 탄소수의 알킬그룹인 -(CH2-)b, -SO2NR3(CH2)|b-이며; E가 프로톤산에서 유도된 음이온이거나 또는 포름산, 글리콜산, 아세트산, 디에틸설페이트, 염화알킬에서 선택된 알킬화제이며; p는 0; m도 0; a는 1인 것을 특징으로 하는 섬유후가공제.
- 제7항에 있어서, R2는
-
- 으로 나타내지며, 여기서 Rf는 n이 6 내지 12인 CnF2n+1이며; A는 -(-CH|2-)6, -C6H3(CH3)-에서 선택된 것이며; R은 b가 1 내지 6-(CH2-)b,이며; Q는 b가 1 내지 6탄소수의 저급알킬이며; p는 0 또는 1이며; m은 1 또는 2이며; a는 0인것을 특징으로 하는 섬유후가공제.
- 제1항에 있어서, 상기의뷰레트은 하기식
-
- 으로 나타내는 것을 특징으로 하는 섬유후가공제.
- 상기식에서, B는인 뷰레트부이며; R2는 알킬기, 시클로알킬기, 아릴기, 이것들의 조합물에서 선택된 말단일가유기기인데 각각의 R2는 서로 같거나 또는 서로 다르며; R4는 일가 또는 다가의 유기기이며; 최소한 하나의 R2또는 A가 최소한 하나의 플루오로 알리파틱기(Rf)를 함유할 때 A는 이가의 유기그룹이며; X는 O,S 또는 NR3인데, 여기서 R3는 수소 또는 저급알킬기이며, Q는 헤테로원자를 함유하는 그룹 또는 이가의 결합그룹이며; G는 COOM1/v, SO3M1/OSO3M1/v,PO(OM/1v)2, OPO(OM1/v)에서 선택된 음이온 말단그룹인데, 여기서 M은 수소 또는 양이온, V는 M의 원자가, X는 1이며; y는 x+y가 1 내지 4임을 조건으로 할때 1 내지 4의 정수이다.
- 제11항에 있어서, 상기의 G는 COOM, SO3M에서 선택된 것이며, 여기서 M은 NH4, R3가 1 내지 4탄소수의 알킬그룹을 지닌 N(R3)3H, N(CH2CH|2OH)3H, Na,K에서 선택된 것이며;
- R2는 -A-NHCO-X-R[-X-CONH-A-B(-A-NHCO-X-Q-Rf)2]|2
- 로 나타낼 수 있는데 여기서 R은 -CH2(C2H5)(-CH2-)2, -CH(CH2-)2에서 선택되었으며; Rf는 n이 6 내지 12인 CnF2n+1이며; A는 -(-CH2)6, C6H6(CH3)-에서 선택된 것이며; R4는 y가 2일 때 -(CH3)C(CH2)2-이며 R4는 y가 1일 때 b가 1 내지 6인 -(-CH2-)b이며 X는 -O- 또는 -NH-이며; Q는 b가 1 내지 6인 -(-CH2-)b, -SO2NR3(CH|2)b-에서 선택된 것으로 여기서 R3는 1 내지 4 탄소수의 알킬그룹이며; P는 0 또는 1, X는 1인 것을 특징으로 하는 섬유후가공제.
- 제1항에 있어서, 상기의 뷰레트은 하기식
-
- 으로 나타내는 것을 특징으로 하는 섬유후가공제.
- 상기식에서, B는인 뷰레트부이며; R2는 알킬기, 시클로알킬기, 아릴기, 이것들의 조합물에서 선택된 말단 일가유기기인데, 각각의 R2는 서로 같거나 또는 서로 다르며; R4는 일가 또는 다가의 유기기이며; 최소한 하나의 R2또는 A가 최소한 하나의 플루오로 알리파틱기를 함유할 때 A는 이가의 유리그룹이며; G는 COOM1/v,SO3M1/v, OSO3M1/|v, PO(OM1/v)2, OPO(OM1/v)2에서 선택된 음이온 말단그룹으로서, 여기서 M은 수소 또는 양이온부이여, V는 M의 원자가이며, n은 1 또는 2이며, x+y가 1 내지 4의 정수일 때 x는 1, y는 1 내지 4의 정수이다.
- 제13항에 있어서, 상기의 G는 M이 H, N(C2H5)3H, K, Na에서 선택된 -CO2M, -SO3M에서 선택된 것이며; R2는-A-NHCO-X-Q-Rf, -R-X-CONH-A-B[-A-NHCO-X-A-B(-A-NHCO-X-Q-Rf)2]인데, 여기서 Rf는 n이 6 내지 12인 CnF2n+1이며; Q는 b가 1 내지 6이며 R3가 1 내지 4 탄소수를 갖는 알킬 그룹인 -(-CH2-)b, SO2NR|3(CH2)b-에서 선택된 것이며; A는 -(-CH2-)6, -C6H3(CH3)-에서 선택된 것이며; R4는 b가 1 내지 6인 -(-CH2-)b이며, X는 -O-, -NH- 이며; R은 b가 1 내지 6인 -(-CH2-)b이며, x는 1, y는 1인 것을 특징으로 하는 섬유후가공제.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US595,901 | 1984-04-02 | ||
US06/595,901 US4668406A (en) | 1984-04-02 | 1984-04-02 | Fluorochemical biuret compositions and fibrous substrates treated therewith |
Publications (2)
Publication Number | Publication Date |
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KR850007623A true KR850007623A (ko) | 1985-12-07 |
KR910004720B1 KR910004720B1 (ko) | 1991-07-10 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019850002217A KR910004720B1 (ko) | 1984-04-02 | 1985-04-02 | 플루오로화학약품 부렡 및 그로 구성되는 섬유 후가공제 |
Country Status (8)
Country | Link |
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US (2) | US4668406A (ko) |
EP (1) | EP0157611B1 (ko) |
JP (1) | JPS60224668A (ko) |
KR (1) | KR910004720B1 (ko) |
AU (1) | AU576353B2 (ko) |
CA (1) | CA1242739A (ko) |
DE (1) | DE3587649T2 (ko) |
ZA (1) | ZA852045B (ko) |
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DE3737753A1 (de) * | 1987-11-06 | 1989-06-15 | Pfersee Chem Fab | Waessriges ausruestungsmittel und verfahren zur weichen hydrophob/oleophob-behandlung von fasermaterialien |
US4925707A (en) * | 1987-12-21 | 1990-05-15 | E. I. Du Pont De Nemours And Company | Treatment of carpets |
US5045387A (en) * | 1989-07-28 | 1991-09-03 | Hercules Incorporated | Rewettable polyolefin fiber and corresponding nonwovens |
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JPH03193975A (ja) * | 1989-12-22 | 1991-08-23 | Minnesota Mining & Mfg Co <3M> | 撥水撥油処理剤 |
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US5580645A (en) * | 1989-12-29 | 1996-12-03 | E. I. Du Pont De Nemours And Company | Substrates treated with polyfluoro nitrogen-containing organic compounds |
US5509939A (en) * | 1989-12-29 | 1996-04-23 | E. I. Du Pont De Nemours And Company | Soil-release process |
US5159105A (en) * | 1990-02-28 | 1992-10-27 | Minnesota Mining And Manufacturing Company | Higher pentafluorosulfanyl-fluoroaliphatic carbonyl and sulfonyl fluorides, and derivatives |
US5153046A (en) * | 1990-05-24 | 1992-10-06 | E. I. Du Pont De Nemours And Company | Fluorochemical composition for imparting antisoiling protection and lubricity to textile fibers |
US5084306A (en) * | 1990-10-23 | 1992-01-28 | Monsanto Company | Process for coating fabrics with fluorochemicals |
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-
1984
- 1984-04-02 US US06/595,901 patent/US4668406A/en not_active Expired - Lifetime
-
1985
- 1985-03-19 ZA ZA852045A patent/ZA852045B/xx unknown
- 1985-03-22 AU AU40254/85A patent/AU576353B2/en not_active Ceased
- 1985-03-25 CA CA000477351A patent/CA1242739A/en not_active Expired
- 1985-03-29 EP EP85302213A patent/EP0157611B1/en not_active Expired - Lifetime
- 1985-03-29 DE DE3587649T patent/DE3587649T2/de not_active Expired - Fee Related
- 1985-04-01 JP JP60068891A patent/JPS60224668A/ja active Pending
- 1985-04-02 KR KR1019850002217A patent/KR910004720B1/ko not_active IP Right Cessation
-
1987
- 1987-02-18 US US07/016,138 patent/US4748267A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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JPS60224668A (ja) | 1985-11-09 |
AU4025485A (en) | 1985-10-10 |
EP0157611B1 (en) | 1993-11-10 |
US4748267A (en) | 1988-05-31 |
DE3587649T2 (de) | 1994-05-19 |
CA1242739A (en) | 1988-10-04 |
ZA852045B (en) | 1986-10-29 |
KR910004720B1 (ko) | 1991-07-10 |
US4668406A (en) | 1987-05-26 |
EP0157611A1 (en) | 1985-10-09 |
AU576353B2 (en) | 1988-08-25 |
DE3587649D1 (de) | 1993-12-16 |
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