KR850005472A - 가교결합가능 유기 중합체 조성물 - Google Patents
가교결합가능 유기 중합체 조성물 Download PDFInfo
- Publication number
- KR850005472A KR850005472A KR1019850000025A KR850000025A KR850005472A KR 850005472 A KR850005472 A KR 850005472A KR 1019850000025 A KR1019850000025 A KR 1019850000025A KR 850000025 A KR850000025 A KR 850000025A KR 850005472 A KR850005472 A KR 850005472A
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- Prior art keywords
- silane
- polymer
- silyl
- composition
- compound
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/59—Arsenic- or antimony-containing compounds
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Biological Depolymerization Polymers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 실릴-개질된 에틸렌(공)중합체 및 하나 이상의 X-R 그룹-함유인 안티몬 화합물 및 임의로 실란을 축합 촉매로 이루어진 가교 결합가능 조성물(상기식에서 X는 인 또는 안티몬을 나타내며, R은 수소원자이거나 탄소 또는 수소원자에 의해 원자X에 결합된 유기 치환체이고, X는 3가 또는 5가이다.)
- 제1항에 있어서, 실릴-개질된 에틸렌(공)중합체가, 에틸렌으로 이루어진 모노머 물질과, 임의로 알파-올레핀, 비닐 에스테르, 알킬 메트아크릴레이트, 불포화 니트릴 및 불포화 에테르중 하나이상을 가수분해가능 실랄그룹-함유불포화 실란 화합물과 공중합시켜 수득된 생성물인 조성물.
- 제1항에 있어서, 실릴-개질된 에틸렌(공)중합체가, 폴리에틸렌 또는 에틸렌 공중합상에 가수분해 가능 실란그룹-함유 불포화 실란 화합물을 그래프트시켜 제조한 그래프트 중합체인 조성물.
- 제1항에 있어서, 자유 라디칼 중합 개시제, 인 또는 안티몬 화합물 및 임의로 실란을 축합 촉매 존재하에, 폴리에틸렌 도는 에틸렌 공중합체 상에 불포화 실란화합물을 그래프트시켜 제조한 조성물.
- 제1항, 3항 또는 4항에 있어서, 실릴-개질된 에틸렌(공)중합체가, 알파-올레핀, 비닐 에스테르, 알킬(메트)아크릴레이트, 불포화 니트릴 및 불포화에테르 중 하나이상과 에틸렌과의 공중합체 또는 폴리에틸렌상에 실란-그래프트시켜 제조한 그래프트 중합체인 조성물.
- 제2항에 있어서, 실릴-개질된 에틸렌(공)중합체가, 자유라디칼 개시제의 존재하에 150내지 400℃ 및 500내지 4000바(bar)의 압력에서 모노머물질과 불포화 실란 화합물을 공중합시켜 제조된 것인 조성물.
- 제1항 내지 6항중 어느 하나에 있어서, 인 화합물일 유기 아인산염, 유기 포스포나이트, 유기포스핀 또는 유기 포스핀 산화물인 조성물.
- 제1항 내지 7항중 어느 하나에 있어서, 인 화합물이 디알킬 또는 트리알킬 아인산염, 바람직하게는 트리부틸 아인산염, 트리-n-헥실 아인산염, 트리-이소-옥틸아인산염, 트리-노닐 아인산염 및 디-이소-옥틸 아인산염인 조성물.
- 제1항 내지 8항중 어느 하나에 있어서, 실릴-개질된 중합체중에 존재하는 실란 그룹이 비닐 트리메톡시 실란, 비닐 트리에톡시 실란, 비닐 트리스(메톡시 에톡시(실란 또는 비닐트리아세톡시 실란으로부터 유도된 것인 조성물.
- 제1항 내지 9항중 어느 하나에서 청구된 조성물을 전선 또는 케이블 상에 압출피복시키고 물, 스팀 또는 습윤공기에 노출시켜 가교결합화시킴을 특징으로하는 전선 또는 케이블의 절연방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8400149 | 1984-01-05 | ||
GB848400149A GB8400149D0 (en) | 1984-01-05 | 1984-01-05 | Polymer composition |
GB?8400149? | 1984-01-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR850005472A true KR850005472A (ko) | 1985-08-26 |
KR930007696B1 KR930007696B1 (ko) | 1993-08-18 |
Family
ID=10554562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850000025A KR930007696B1 (ko) | 1984-01-05 | 1985-01-05 | 가교결합가능한 유기 중합체 조성물 |
Country Status (9)
Country | Link |
---|---|
US (1) | US4574133A (ko) |
EP (1) | EP0149903B1 (ko) |
JP (1) | JPH0689184B2 (ko) |
KR (1) | KR930007696B1 (ko) |
AT (1) | ATE37385T1 (ko) |
CA (1) | CA1265285A (ko) |
DE (1) | DE3474155D1 (ko) |
GB (1) | GB8400149D0 (ko) |
NO (1) | NO169395C (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100715362B1 (ko) * | 2004-03-24 | 2007-05-07 | 니폰 쇼쿠바이 컴파니 리미티드 | 방열 재료용 수지 조성물 및 방열 재료 |
KR100922652B1 (ko) * | 2001-10-23 | 2009-10-19 | 넥쌍 | 실란 그래프트 중합체 기재 조성물의 압출 및 가교결합에의한 케이블 외장의 제조 방법 및 상기 방법에 의해 얻은외장을 포함하는 케이블 |
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JPS53145856A (en) * | 1977-05-26 | 1978-12-19 | Furukawa Electric Co Ltd:The | Preparation of polyethylene molding articles |
US4223071A (en) * | 1978-01-13 | 1980-09-16 | Raychem Corporation | High voltage insulating compositions containing phosphorus compounds |
JPS5839170B2 (ja) * | 1978-01-27 | 1983-08-27 | 昭和電線電纜株式会社 | 難燃性架橋成形品の製造方法 |
US4353997A (en) * | 1978-03-31 | 1982-10-12 | Union Carbide Corporation | Compositions based on water-curable, silane modified copolymers of alkylene-alkyl acrylates |
US4413066A (en) * | 1978-07-05 | 1983-11-01 | Mitsubishi Petrochemical Company, Ltd. | Crosslinkable polyethylene resin compositions |
JPS5845942B2 (ja) * | 1978-12-19 | 1983-10-13 | 古河電気工業株式会社 | シラン架橋ポリオレフイン系樹脂組成物成形体の製造方法 |
JPS5933351A (ja) * | 1982-08-18 | 1984-02-23 | Kanegafuchi Chem Ind Co Ltd | 1液組成物 |
JPS59124954A (ja) * | 1982-12-30 | 1984-07-19 | Kanegafuchi Chem Ind Co Ltd | 硬化性組成物 |
-
1984
- 1984-01-05 GB GB848400149A patent/GB8400149D0/en active Pending
- 1984-12-13 AT AT84308672T patent/ATE37385T1/de active
- 1984-12-13 DE DE8484308672T patent/DE3474155D1/de not_active Expired
- 1984-12-13 EP EP84308672A patent/EP0149903B1/en not_active Expired
- 1984-12-17 US US06/682,193 patent/US4574133A/en not_active Expired - Lifetime
-
1985
- 1985-01-03 NO NO850020A patent/NO169395C/no unknown
- 1985-01-04 CA CA000471480A patent/CA1265285A/en not_active Expired - Lifetime
- 1985-01-04 JP JP60000087A patent/JPH0689184B2/ja not_active Expired - Lifetime
- 1985-01-05 KR KR1019850000025A patent/KR930007696B1/ko not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100922652B1 (ko) * | 2001-10-23 | 2009-10-19 | 넥쌍 | 실란 그래프트 중합체 기재 조성물의 압출 및 가교결합에의한 케이블 외장의 제조 방법 및 상기 방법에 의해 얻은외장을 포함하는 케이블 |
KR100715362B1 (ko) * | 2004-03-24 | 2007-05-07 | 니폰 쇼쿠바이 컴파니 리미티드 | 방열 재료용 수지 조성물 및 방열 재료 |
Also Published As
Publication number | Publication date |
---|---|
EP0149903B1 (en) | 1988-09-21 |
CA1265285A (en) | 1990-01-30 |
GB8400149D0 (en) | 1984-02-08 |
ATE37385T1 (de) | 1988-10-15 |
EP0149903A3 (en) | 1985-08-21 |
EP0149903A2 (en) | 1985-07-31 |
JPH0689184B2 (ja) | 1994-11-09 |
DE3474155D1 (en) | 1988-10-27 |
NO850020L (no) | 1985-07-08 |
US4574133A (en) | 1986-03-04 |
JPS60215046A (ja) | 1985-10-28 |
NO169395C (no) | 1992-06-17 |
KR930007696B1 (ko) | 1993-08-18 |
NO169395B (no) | 1992-03-09 |
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