KR850000515A - 금속-가공유 조성물 - Google Patents

금속-가공유 조성물 Download PDF

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KR850000515A
KR850000515A KR1019840003348A KR840003348A KR850000515A KR 850000515 A KR850000515 A KR 850000515A KR 1019840003348 A KR1019840003348 A KR 1019840003348A KR 840003348 A KR840003348 A KR 840003348A KR 850000515 A KR850000515 A KR 850000515A
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South Korea
Prior art keywords
salts
group
metal
carbon atoms
acid
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KR1019840003348A
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English (en)
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KR910004944B1 (ko
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히로시 구와모도 (외 4)
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마루다 요시오 (외 1)
가오우세껭 가부시끼 가이샤
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Priority claimed from JP10654183A external-priority patent/JPS59232181A/ja
Priority claimed from JP10723983A external-priority patent/JPH0240118B2/ja
Application filed by 마루다 요시오 (외 1), 가오우세껭 가부시끼 가이샤 filed Critical 마루다 요시오 (외 1)
Publication of KR850000515A publication Critical patent/KR850000515A/ko
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Publication of KR910004944B1 publication Critical patent/KR910004944B1/ko

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Abstract

내용 없음.

Description

금속-가공유 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 필수 성분으로서 오일, 지방, 광물유 및 지방산 에스테르로 이루어진 그룹으로 부터 선택된 하나 이상의 윤활유 성분; 1,000 내지 10,000,000의 분자량을 갖고, 분자내에 질소 원자들을 함유하며, 다음 일반식(I) 내지(IX)중의 하나로 표시되는 질소-함유 모노머 또는 그 모노머의 염의 단일중합체, 또는 이 질소-함유 모노머 또는 그 모노머의 염 둘이상의 공중합체, 각각 다음 일반식(I) 내지 (IX)로 표시되는 질소-함유 모노머 또는 그의 염 하나 이상과 α,β-불포화 카복실산 및 그의 염 및 유도체, 설포-함유 비닐 화합물 및 그의 염, 아크릴로니트릴, 비닐피롤리돈, 및 2 내지 20개의 탄소원자를 갖는 지방족 올레핀으로 구성된 그룹중에서 선택된 비닐 모노머 하나 이상과의 공중합체, 에틸렌이민의 개환 중합체의 염 또는 4급 암모늄염, 지방족 디카복실산과 폴리에틸렌폴리아민 또는 디폴리옥시에틸렌알킬아민의 중축합반응 생성물의 염 또는 4급 암모늄염, 디할로알칸-폴리알킬렌폴리아민 중축합반응생성물, 에피할로하이드린-아민 중축합반응 생성물, 키토산, 녹말 또는 셀룰로즈의 염, 또는 그의 양이온-변형 생성물, 또는 알킬렌 옥사이드를 6 내지 200개의 질소원자를 갖는 폴리알킬렌이민 또는 그의 유도체에 첨가하여 수득된 5,000 내지 600,000의 분자량을 갖는 폴리에테르폴리올 또는 폴리올폴리에테르 유도체로 이루어진 그룹으로 부터 선택된 양이온성 또는 양쪽 이온성, 수용성 중합체 화합물; 및 계면활성제를 함유하는 금속-가공유 조성물.
    상기식에서, R1은 H 또는 CH3를 나타내고, R2및 R3는 각각 H 또는 1 내지 3개의 탄소원자를 갖는 알킬그룹을 나타내고, R4는 H 또는 1 내지 3개의 탄소원자를 갖는 알킬 또는 알킬올 그룹을 나타내고, m1,m2및 n1은 각각 1 내지 3의 수를 나타내고, n2는 0내지 3의 수를 나타내고, A는-0-또는 -NH-를 나타내며, 일반식(VII)에서, 피리딘 고리상의 치환 위치는 2-또는 4-위치이고, 일반식(VIII)에서, 피페리딘 고리상의 치환 위치는 2-또는 4-위치이다.
  2. 제1항에 있어서, 수용성 중합체 화합물의 분자량이 1,000 내지 1,000,000의 범위인 금속-가공유 조성물.
  3. 제1항에 있어서, 수용성 중합체 화합물 및 계면활성제의 총비율이 전체 조성물의 0.1 내지 20중량%인 금속-가공유 조성물.
  4. 필수 성분으로서 오일, 지방, 광물유 및 지방산에스테르로 이루어진 그룹으로부터 선택된 하나 이상의 윤활유 성분; 1,000 내지 10,000,000의 분자량을 갖고 그의 분자내에 질소원자들을 함유하며, 다음 일반식(I) 내지(IX)중의 하나로 표시되는 질소-함유 모노머 또는 그 모노머의 염의 단일중합체 또는 이 질소-함유 모노머 또는 그 모노머의 염 둘 이상의 공중합체, 각각 다음 일반식(I) 내지 (IX)로 표시되는 질소-함유 모노머 또는 그의 염 하나이상과 α,β-불포화 카복실산 및 그의 염 및 유도체, 설포-함유 비닐 화합물 및 그의 염, 아크릴로니트릴, 비닐피롤리돈, 및 2 내지 20개의 탄소원자를 갖는 지방족 올레핀으로 구성된 그룹중에서 선택된 비닐 모노머 하나 이상과의 공중합체, 에틸렌 이민의 개환 중합체의 염 또는 4급 암모늄염, 지방족 디카복실산과 폴리에틸렌 폴리아민 또는 디폴리옥시에틸렌알킬아민의 중축합반응 생성물의 염 또는 4급 암모늄염, 디할로알칸-폴리알킬렌 폴리아민 중축합반응생성물, 에피할로하이드린-아민 중축합반응 생성물, 키토산, 녹말 또는 셀룰로즈의 염, 또는 그의 양이온-변형 생성물, 또는 알킬렌 옥사이드를 6 내지 200개의 질소원자를 갖는 폴리알킬렌이민 또는 그의 유도체에 첨가하여 수득된, 1,000 내지 600,000의 분자량을 갖는 폴리에테르폴리올 또는 폴리올폴리에테르 유도체로 이루어진 그룹으로 부터 선택된 양이온성 또는 양쪽이온성수용성 중합체 화합물; 계면활성제; 및 극압 첨가물(extreme-pressure additive)을 함유하는 금속-가공유 조성물.
    상기식에서, R1은 H 또는 CH3를 나타내고, R2및 R3는 각자 H 또는 1 내지 3개의 탄소원자를 갖는 알킬그룹을 나타내고, R4는 H 또는 1 내지 3개의 탄소원자를 갖는 알킬 또는 알킬올 그룹을 나타내고, m1,m2및 n1은 각각 1내지 3의 수를 나타내고, m2는 0내지 3의 수를 나타내고, A는-0- 또는-NH- 를 나타내면, 일반식(VII)에서, 피리딘 고리상의 치환 위치는 2-또는 4-위치이고, 일반식(VIII)에서, 피페리딘 고리상의 치환 위치는 2-또는 4-위치이다.
  5. 제4항에 있어서, 수용성 중합체 화합물의 분자량이 1,000 내지 1,000,000의 범위인 금속-가공유 조성물.
  6. 제4항에 있어서, 질소-함유 모노머와 공중합된 α,β-불포화 카복실산이 아크릴산, 메타크릴산 또는 말레산이고; 그의 염이 알카리금속 또는 암모늄염이고; 그의 유도체가 알킬 아미드 또는 알킬 에스테르 또는 아크릴로니트릴인 금속-가공유 조성물.
  7. 제4항에 있어서, 질소-함유 모노머와 공중합된 설포-함유 비닐 화합물이 비닐설폰산, 메트알릴설폰산, 2-아크릴아미드-2-메틸프로판설폰산 또는 p-스티렌설폰산이고, 그의 염이 알카리금속 또는 암모늄염인 금속-가공유 조성물.
  8. 제4항에 있어서, 에틸렌이민의 개환 중합체의 반복 단위가 다음 일반식(XI)로 표시되는 금속-가공유 조형물.
    상기식에서, n3는 1 내지 5의 정수를 나타내고, n4는 0 내지 5의 정수를 나타낸다.
  9. 제4항에 있어서, 지방족 디카복실산과 폴리에틸렌-폴리아민의 중축합반응 생성물의 반복 단위가 다음 일반식(XII)로 표시되는 금속-가공유 조성물.
    상기식에서, R7은 이합체산 또는 1 내지 10개의 탄소원자를 갖는 알킬렌그룹의 잔기를 나타내고, R'는-CH2CH2-를 나타내고, n5는 2 내지 7의 정수를 나타낸다.
  10. 제4항에, 있어서, 지방족 디카복실산과 디폴리옥시에틸렌알킬아민의 중축합반응 생성물의 반복단위가 다음 일반식(XIII)로 표시되는 금속-가공유 조성물.
    상기식에서, R7은 일반식(XII)에서 정의한 것과 같고, R8은 1내지 8개의 탄소원자를 갖는 알킬그룹을 나타내고, R9은 H 또는 CH3를 나타내고, n6및 n7은 각각 1 내지 10의 정수를 나타낸다.
  11. 제4항에 있어서, 에피할로하이드린-중축합반응 생성물의 반복단위가 다음 일반식(XIV)로 표시되는 금속-가공유 조성물.
    상기식에서, R10내지 R12는 각각 CH3또는 C2H5를 나타내고,는 할로겐 이온을 나타낸다.
  12. 제4항에 있어서, 폴리알킬렌폴리아민이, 그의 분자내에, 각각 다음 일반식(XV)로 표시되는 적어도 5개의 잔기 [여기에서, 5개의 잔기중 적어도 하나는 다음 일반식(XVI)로 표시되는 잔기이다]를 연속적으로 함유하는 폴리에틸렌이민이고, 그의 적어도 한개의 말단에서 OH 및/또는 NH2그룹을 갖고, 6 내지 100개의 질소 원자를 함유하는 금속-가공유 조성물.
  13. 제4항에 있어서, 폴리에테르폴리올 내의 알킬렌옥사이드가 에틸렌옥사이드, 프로필렌옥사이드, 스티렌옥사이드 및 부틸렌 옥사이드로 이루어진 그룹으로 부터 선택된 하나 이상의 산화물이고, 알킬렌옥사이드의 함량이 폴리에테르폴리올의 3 내지 80중량%에 달하는 금속-가공유 조성물.
  14. 제4항에 있어서, 극압 첨가들이 인산, 아인산 및 그의 티오화합물 및 에스테르 화합물; 각각 알킬, 알킬아릴 및 아릴그룹 [여기에서, 이들은 각각 적어도 한개의 하이드록실 그룹을 함유한다]을 함유하는 모노-및 디-인산 에스테르 및 그의 티오 화합물; 각각 1 내지 8개의 탄소원자를 함유하는 알킬그룹, 알킬아릴 그룹 및 아릴 그룹을 함유하는 모노-또는 디-포스폰산 및 그의 티오화합물 및 유도체; 각각 1 내지 8개의 탄소원자를 갖는 알킬그룹, 알킬아릴그룹 및 아릴 그룹을 함유하는 모노-또는 디-포스핀산 및 그의 티오화합물 및 유도체, 하나 이상의 질소 원자를 함유하는 모노 -, 디-및 트리-포스핀산; 1 내지 8개의 탄소원자를 갖는 알킬그룹 또는 아릴 그룹을 함유하는 티오알코올; 1 내지 10개의 탄소원자를 갖는 알킬그룹, 하이드록시알킬그룹, 알킬아릴그룹 또는 하이드록시알킬아릴 그룹을 함유하는 티오카복실산, 및 그의 염; 유기아연 화합물; Ro-(S)z-Ro[여기에서, Z는 1 내지 5의 정수를 나타내고, Ro는 1 내지 8개의 탄소원자를 갖는 알킬그룹, 알킬아릴그룹, 또는 아릴그룹을 나타낸다]; 및 유기 황-함유 헤테로 사이클 화합물, 및 그의 염 및 유도체로 부터 선택된 하나 이상의 화합물인 금속-가공유 조성물.
  15. 제4항에 있어서, 수용성 중합체 화합물이 전체 조성물의 0.1 내지 20중량% 에 달하는 금속-가공유 조성물.
  16. 제4항 또는 14항에 있어서, 극압 첨가물의 비율이 전체 조성물의 0.1 내지 10중량 %의 범위인 금속 가공유 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840003348A 1983-06-14 1984-06-14 금속-가공유 조성물 KR910004944B1 (ko)

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JP10654183A JPS59232181A (ja) 1983-06-14 1983-06-14 金属加工油組成物
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JP10723983A JPH0240118B2 (ja) 1983-06-15 1983-06-15 Kinzokukakoyusoseibutsu

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