KR890000530A - 액상 변성 에티렌성 랜돔 공중합체 및 그의 용도 - Google Patents

액상 변성 에티렌성 랜돔 공중합체 및 그의 용도 Download PDF

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Publication number
KR890000530A
KR890000530A KR1019880006821A KR880006821A KR890000530A KR 890000530 A KR890000530 A KR 890000530A KR 1019880006821 A KR1019880006821 A KR 1019880006821A KR 880006821 A KR880006821 A KR 880006821A KR 890000530 A KR890000530 A KR 890000530A
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South Korea
Prior art keywords
liquid
ethylene
copolymer
random copolymer
modified
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KR1019880006821A
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English (en)
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KR910005677B1 (ko
Inventor
도시유끼 쓰쓰이
아끼노리 도요다
노리오 가시와
Original Assignee
원본 미기재
미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤사장 다께바야시 쇼오고
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Priority claimed from JP14158487A external-priority patent/JPH07103181B2/ja
Priority claimed from JP14158587A external-priority patent/JPH0791338B2/ja
Application filed by 원본 미기재, 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤사장 다께바야시 쇼오고 filed Critical 원본 미기재
Publication of KR890000530A publication Critical patent/KR890000530A/ko
Application granted granted Critical
Publication of KR910005677B1 publication Critical patent/KR910005677B1/ko

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Abstract

내용 없음

Description

액상 변성 에티렌성 랜돔 공중합체 및 그의 용도
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Claims (33)

  1. 에티렌과 3-20 탄소원자의 알파올레핀으로 된 액상 에티렌성 랜돔 공중합체의 에폭시화 생성물과 에티렌과 3-20 탄소원자의 알파올레핀으로 된 액상 에티렌성 랜돔 공중합체의 수산화 생성물로부터 선택된 액상 변성 에티렌성 랜돔 공중합체로서, 여기서, (i) 액상변성 에티렌성 랜돔 공중합체는 10-85몰 %의 에티렌 성분 함량과 15-90몰 %의 알파올레핀 성분 함량을 가지며, (ii) 액상 변성 에티렌성 랜돔 공중합체의13C-NMR 스펙트럼내에서, 공중합체의 주쇄내의 두 인접한 tert-탄소원자들간의 메티렌쇄를 기준으로하여β 및 βΤ들이 관측되지 않으며, (iii) 액상 변성 에티렌성 랜돔 공중합체는 증기압 오스모메터(Osmometer)로 측정하여 200-10,000의 수평균 분자량(Mn)을 갖고 있으며, (iv) 액상 변성 에티렌성 랜돔 공중합체가 에폭시화 생성물일 경우, 그내의 각 에폭시기는 액상 에티렌성 랜돔 공중합체의 공중합체쇄의 말단에 의치되며, 또한 에폭시 그룹들의 함량은 액상 에폭시화 에티렌성 랜돔 공중합체 100g당 0.01-0.5몰이며, 그리고, 액상 변성 에티렌성 랜돔 공중합체가 수산화 생성물일 경우, 그내의 각 수산기는 에티렌이나 알파올레핀으로부터 유도된 탄소원자에 결합되며 또한 액상 에티렌성 랜돔 공중합체의 중합체쇄 말단에 위치되며, 또한 수산기의 함량은 액상 수산화 에티렌성 랜돔 공중합체 100g당 0.01-1몰인 액상 변성 에티렌성 랜돔 공중합체.
  2. 제 1 항에서, 액상 에폭시화 에치렌성 랜돔 공중합체로된 액상 변성 에티렌성 랜돔 공중합체.
  3. 제 2 항에서, 20-80몰 %의 에티렌 성분 함량 및 20-80몰 %의 알파올레핀 성분 함량과, 증기합 오스모메터로 측정하여 300-8,000의 수평균 분자량과, 공중합체 100g당 0.015-0.3몰의 에폭시기 함량을 갖는 액상 변성 에티렌성 랜돔 공중합체
  4. 제 2 항에 있어서, 30-70몰 %의 에티렌 성분 함량 및 30-70몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 500-5,000의 수평균 분자량과, 공중합체 100g당 0.02-0.2몰의 에폭시기 함량을 갖는 액상 변성 에티렌성 랜돔 공중합체
  5. 제 4 항에서, 알파올레핀은 피렌 또는 1-헥센인 액상 변성 에티렌성 랜돔 공중합체
  6. 재 5 항에서, 겔퍼미에이션 크로마토그라프로 측정하여 1.3-2.5의 분자량 분포를 갖는 액상 변성 에티렌성 랜돔 공중합체
  7. 제 1 항에서, 액상 수산화 에티렌성 랜돔 공중합체인 액상 변성 에티렌성 랜돔 공중합체.
  8. 제 7 항에서, 20-80몰 %의 에티렌 성분 함량 및 20-80몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 300-8,000의 수평균 분자량과, 공중합체 100g당 0.015-0.5몰의 에폭시기 함량을 갖는 액상 변성 에티렌성 랜돔 공중합체.
  9. 제 7 항에서, 30-70몰 %의 에티렌 성분 함량 및 30-70몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 500-5,000의 수평균 분자량과, 공중합체 100g당 0.02-0.4몰의 에폭시기 함량을 갖는 액상 변성 에티렌성 랜돔 공중합체.
  10. 제 9 항에서, 알파올레핀은 프로피렌 또는 1-부텐인 액상 변성 에티렌성 랜돔 공중합체.
  11. 제10항에서, 겔포미에이션 크로마토그라프로 측정하여 1.3-2.5의 분자량 분포를 갖는 액상 변성 에티렌성 공중합체.
  12. 액상 변성 에티렌성 랜돔 공중합체로 윤활유 첨가제를 구성하되, 상기 공중합체는 에티렌과 3-20 탄소원자들을 갖는 알파올레핀으로 된 액상 에티렌성 랜돔 공중합체의 에폭시화 생성물과, 에티렌과 3-20 탄소원자들을 갖는 알파올레핀으로된 액상 에티렌성 랜돔 공중합체의 수산화 생성물로부터 선택되며, 또한 여기서, (i) 액상변성 에티렌성 랜돔 공중합체는 10-85몰 %의 에티렌 성분 함량과 15-90몰 %의 알파올레핀 성분 함량을 가지며, (ii) 액상 변성 에티렌성 랜돔 공중합체의13C-NMR 스펙트럼내에서, 공중합체의 주쇄내의 두 인접한 tert-탄소원자들간의 메티렌쇄를 기준으로하여β 및 βΤ들이 관측되지 않으며, (iii) 액상 변성 에티렌성 랜돔 공중합체는 증기압 오스모메터(Osmometer)로 측정하여 200-10,000의 수평균 분자량(Mn)을 갖고 있으며, (iv) 액상 변성 에티렌성 랜돔 공중합체가 에폭시화 생성물일 경우, 그내의 각 에폭시기는 액상 에티렌성 랜돔 공중합체의 공중합체쇄의 말단에 위치되며, 또한 에폭시 그룹들의 함량은 액상 에폭시화 에티렌성 랜돔 공중합체 100g당 0.01-0.5몰이며, 그리고, 액상 변성 에티렌성 랜돔 공중합체가 수산화 생성물일 경우, 그내의 각 수산기는 에티렌이나 알파올레핀으로부터 유도된 탄소원자에 결합되며 또한 액상 에티렌성 랜돔 공중합체의 중합체쇄 말단에 위치되며, 또한 수산기의 함량은 액상 수산화 에티렌성 랜돔 공중합체 100g당 0.01-1몰인 윤활유 첨가제.
  13. 제12항에서, 액상 변성 에티렌성 랜돔 공중합체는 액상 에폭시화 에티렌성 랜돔 공중합체인 윤활유 첨가제.
  14. 제13항에서, 액상 에폭시화 에티렌성 랜돔 공중합체는 20-80몰 %의 에티렌 성분 함량 20-80몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 300-8,000의 수평균 분자량과, 공중합체 100g당 0.015-0.3몰의 에폭시기를 갖는 윤활유 첨가제.
  15. 제13항에서, 액상 에폭시화 에티렌성 랜돔 공중합체는 30-70몰 %의 에티렌 성분 함량 30-70몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 500-5,000의 수평균 분자량과, 공중합체 100g당 0.015-0.3몰의 에폭시기를 갖는 윤활유 첨가제.
  16. 제15항에서, 알파올레핀은 피로피렌 또는 1-헥센인 윤활유 첨가제.
  17. 제16항에서, 액상 에폭시화 에티렌성 랜돔 공중합체는 겔퍼미에이션 크로마토그라프로 측정하여 1.3-2.5분자량 분포를 갖는 윤활유 첨가제.
  18. 제12항에서, 액상 변성 에티렌성 랜돔 공중합체는 액상 수산화 에티렌성 랜돔 공중합체인 윤활유 첨가제.
  19. 제18항에서, 액상 수산화 에티렌성 랜돔 공중합체는 20-80몰 %의 에티렌 성분 함량 20-80몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 300-8,000의 수평균 분자량과, 공중합체 100g당 0.015-0.3몰의 에폭시기를 갖는 윤활유 첨가제.
  20. 제18항에서, 액상 수산화 에티렌성 랜돔 공중합체는 30-70몰 %의 에티렌 성분 함량 30-70몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 500-5,000의 수평균 분자량과, 공중합체 100g당 0.02-0.4몰의 에폭시기를 갖는 윤활유 첨가제.
  21. 제20항에서, 알파올레핀은 프로피렌 또는 1-헥센인 윤활유 첨가제.
  22. 제21항에서, 액상 수산화 에티렌성 랜돔 공중합체는 겔퍼미에이션 크로마토그라프로 측정하여 1.3-2.5의 분자량 분포를 갖는 윤활유 첨가제.
  23. 액상 변성 에티렌성 랜돔 공중합체로 페인트 첨가제를 구성하되, 상기 공중합체는 에티렌과 3-20 탄소원자들을 갖는 알파올레핀으로된 액상 에티렌성 랜돔 공중합체의 에폭시화 생성물과, 에티렌과 3-20 탄소원자들을 갖는 알파올레핀으로된 액상 에티렌성 랜돔 공중합체의 수산화 생성물로부터 선택되며, 또한 (i) 액상변성 에티렌성 랜돔 공중합체는 10-85몰 %의 에티렌 성분 함량과 15-90몰 %의 알파올레핀 성분 함량을 가지며, (ii) 액상 변성 에티렌성 랜돔 공중합체의13C-NMR 스펙트럼내에서, 공중합체의 주쇄내의 두 인접한 tert-탄소원자들간의 메티렌쇄를 기준으로하여β 및 βΤ들이 관측되지 않으며, (iii) 액상 변성 에티렌성 랜돔 공중합체는 증기압 오스모메터(Osmometer)로 측정하여 200-10,000의 수평균 분자량(Mn)을 갖고 있으며, (iv) 액상 변성 에티렌성 랜돔 공중합체가 에폭시화 생성물일 경우, 그내의 각 에폭시기는 액상 에티렌성 랜돔 공중합체의 공중합체쇄의 말단에 위치되며, 또한 에폭시 그룹들의 함량은 액상 에폭시화 에티렌성 랜돔 공중합체 100g당 0.01-0.5몰이며, 그리고, 액상 변성 에티렌성 랜돔 공중합체가 수산화 생성물일 경우, 그내의 각 수산기는 에티렌이나 알파올레핀으로부터 유도된 탄소원자에 결합되며 또한 액상 에티렌성 랜돔 공중합체의 중합체쇄 말단에 위치되며, 또한 수산기의 함량은 액상 수산화 에티렌성 랜돔 공중합체 100g당 0.01-1몰인 윤활유 첨가제.
  24. 제23항에서, 액상 변성 에티렌성 랜돔 공중합체는 액상 에폭시화 에티렌성 랜돔 공중합체인 페인트 첨가제.
  25. 제24항에서, 액상 에폭시화 에티렌성 랜돔 공중합테는 20-80몰 %의 에티렌 성분 함량 및 20-80몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 300-8,000의 수평균 분자량과, 공중합체 100g당 0.015-0.3몰의 에폭시기 함량을 갖는 페인트 첨가제.
  26. 제24항에서, 액상 에폭시화 에티렌성 랜돔 공중합테는 30-70몰 %의 에티렌 성분 함량 및 30-70몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 500-5,000의 수평균 분자량과, 공중합체 100g당 0.02-0.2몰의 에폭시기 함량을 갖는 페인트 첨가제.
  27. 제26항에서, 알파올레핀은 프로피렌 또는 1-헥센인 페인트 첨가제.
  28. 제27항에서, 액상 에폭시화 에티렌성 랜돔 공중합체는 켈퍼미에이션 크로마토그라프로 측정하여 1.3-2.5의 분자량 분포를 갖는 페인트 첨가제.
  29. 제23항에서, 액상 변성 에티렌성 랜돔 공중합체는 액상 수산화 에티렌성 랜돔 공중합체인 페인트 첨가제.
  30. 제29항에서, 액상 수산화 에티렌성 랜돔 공중합테는 20-80몰 %의 에티렌 성분 함량 및 20-80몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 300-8,000의 수평균 분자량과, 공중합체 100g당 0.015-0.3몰의 에폭시기 함량을 갖는 페인트 첨가제.
  31. 제29항에서, 액상 수산화 에티렌성 랜돔 공중합테는 30-70몰 %의 에티렌 성분 함량 및 30-70몰 %의 알파올레핀 성분 함량과, 증기압 오스모메터로 측정하여 500-5,000의 수평균 분자량과, 공중합체 100g당 0.02-0.4몰의 에폭시기 함량을 갖는 페인트 첨가제.
  32. 제31항에서, 알파올레핀은 프로피렌 또는 1-헥센인 페인트 첨가제.
  33. 제32항에서, 액상 수산화 에티렌성 랜돔 공중합체는 겔퍼미에이션 크로마토그라프로 측정하여 1.3-2.5의 분자량 분포를 갖는 페인트 첨가제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880006821A 1987-06-08 1988-06-08 액상변성 에티렌성 랜돔 공중합체 및 그의 용도 KR910005677B1 (ko)

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JP62-141584 1987-06-08
JP141584 1987-06-08
JP14158487A JPH07103181B2 (ja) 1987-06-08 1987-06-08 液状ヒドロキシル化変性エチレン系ランダム共重合体およびその用途
JP141585 1987-06-08
JP14158587A JPH0791338B2 (ja) 1987-06-08 1987-06-08 液状エポキシ化変性エチレン系ランダム共重合体およびその用途

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CN1071441A (zh) 1993-04-28
US4981605A (en) 1991-01-01
DE3880893T2 (de) 1993-12-23
EP0295026A2 (en) 1988-12-14
KR910005677B1 (ko) 1991-08-01
CA1302002C (en) 1992-05-26
CN1042640C (zh) 1999-03-24
DE3880893D1 (de) 1993-06-17
CN1031236A (zh) 1989-02-22
EP0295026B1 (en) 1993-05-12
CN1023815C (zh) 1994-02-16

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