KR840002843A - 다기능 음이온성 시발제(始發劑)의 제조방법 - Google Patents

다기능 음이온성 시발제(始發劑)의 제조방법 Download PDF

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KR840002843A
KR840002843A KR1019820005734A KR820005734A KR840002843A KR 840002843 A KR840002843 A KR 840002843A KR 1019820005734 A KR1019820005734 A KR 1019820005734A KR 820005734 A KR820005734 A KR 820005734A KR 840002843 A KR840002843 A KR 840002843A
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process according
carried out
alkyl
multifunctional
alkali metal
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KR1019820005734A
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로께로 아르날도 (외 2)
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원본미기재
에녹시 치미카 쏘시에떼 퍼 아찌오니
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Publication of KR840002843A publication Critical patent/KR840002843A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/87—Non-metals or inter-compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C08G69/18—Anionic polymerisation
    • C08G69/20—Anionic polymerisation characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/06—Polythioethers from cyclic thioethers
    • C08G75/08—Polythioethers from cyclic thioethers from thiiranes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

내용 없음

Description

다기능 음이온성 시발제(始發劑)의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 일반식을 갖인 다기능 음이온성 시발제
    식중에서, Me는 알카리 금속이고; n는 2-6의 특히 2-3 정수이고; R'는 알킬, 수소원자이나 아미드 그룹이며, X는 하기 구조의 2가 또는 다가 유도체이고, R는 수소, 0-18원자를 포함한 알칼리(방향족 고리에 직접 결합된 3급 탄소 원자를 갖인 것이 적당), 싸이클로알킬, 알콕시나 방향족 라디칼임.
  2. 하기 일반식을 갖인 화합물인 반응시키는 것으로 구성된 청구범위 1에서 정의된 바와 같은 음이온성 다기능 시발제의 제조방법.
    식중에서, X, R 및 n는 알카리 금속의 알킬, 하이드라이드나 아미드(MeR')와 함께 청구범위 1에서 정의된 바와 같음.
  3. R'은 알킬이고 Me는 리티움인 청구범위 2에 따른 방법.
  4. 지방족, 환상지방족, 방향족, 알킬방향족 용매나 이들의 혼합물 내에서 실시함을 특징으로 하는 청구범위 2에 따른 방법.
  5. 0℃-80℃의 온도 범위에서 실시함을 특징으로 하는 청구범위 2에 따른 방법.
  6. 아민이 존재함을 특징으로 하는 청구범위 2에 따른 방법.
  7. 아민이 알카리 금속과 함께 1:0.1-1:1의 Me/n비로 존재함을 특징으로 하는 청구범위 6에 따른 방법.
  8. 청구범위 1에서 청구한 바와 같은 다기능 음이온성 시발제를 사용하여 디엔, 비닐방향족 화합물, 아크릴과 메타이크릴 화합물의 에스테르, 니트릴이나 N,N-디치환된 아미드, 비닐 피리딘이나 비닐 퀴노린 및 이들의 유도체의 균질 중합이나 공중합 방법.
  9. 중합을 지방족, 환상 지방족, 방향족, 극성 및 비수 용매로 부터 선택한 용매내에서 실시함을 특징으로하는 청구범위 8에 따른 방법.
  10. -78℃와 관련용매의 비등점간의 온도에서 실시함을 특징으로 하는 청구범위 8이나 9에 따른 방법.
  11. 트리알킬아민, 디알킬아민, 디아릴에스테르 및 알카릴 에스테르로 부터 선택한 화합물의 존재하에서 실시함을 특징으로 하는 청구범위 8에 따른 방법.
  12. 반응을 10:1까지의 극성화합물:알카리금속비로 실시함을 특징으로 하는 청구범위 8에 따른 방법.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019820005734A 1981-12-22 1982-12-22 다기능 음이온성 시발제(始發劑)의 제조방법 KR840002843A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT25751/81A IT1195303B (it) 1981-12-22 1981-12-22 Iniziatori anionici multifunzionali e loro impiego
IT25751A/81 1981-12-22

Publications (1)

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KR840002843A true KR840002843A (ko) 1984-07-21

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Country Link
US (1) US4450259A (ko)
JP (1) JPS591507A (ko)
KR (1) KR840002843A (ko)
AU (1) AU9161982A (ko)
BE (1) BE895446A (ko)
BR (1) BR8207523A (ko)
CA (1) CA1210025A (ko)
DE (1) DE3247597A1 (ko)
ES (1) ES8405815A1 (ko)
FR (1) FR2518548B1 (ko)
GB (1) GB2112787B (ko)
IT (1) IT1195303B (ko)
NL (1) NL189042C (ko)
TR (1) TR21852A (ko)
ZA (1) ZA829251B (ko)

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US8993684B2 (en) * 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
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CN102439080A (zh) 2009-05-01 2012-05-02 阿尔比马尔公司 粒状低分子量溴化芳族聚合物组合物
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
KR101538876B1 (ko) * 2011-07-22 2015-07-22 아사히 가세이 케미칼즈 가부시키가이샤 조성물 및 중합물

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Also Published As

Publication number Publication date
ES518855A0 (es) 1984-06-16
IT1195303B (it) 1988-10-12
FR2518548B1 (fr) 1986-06-13
FR2518548A1 (fr) 1983-06-24
NL189042C (nl) 1992-12-16
GB2112787B (en) 1986-02-26
CA1210025A (en) 1986-08-19
DE3247597C2 (ko) 1987-12-23
GB2112787A (en) 1983-07-27
US4450259A (en) 1984-05-22
JPS591507A (ja) 1984-01-06
AU9161982A (en) 1983-06-30
BR8207523A (pt) 1983-10-25
DE3247597A1 (de) 1983-06-30
IT8125751A0 (it) 1981-12-22
ES8405815A1 (es) 1984-06-16
ZA829251B (en) 1983-11-30
BE895446A (fr) 1983-06-22
NL8204907A (nl) 1983-07-18
NL189042B (nl) 1992-07-16
TR21852A (tr) 1985-09-13

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