KR840000966B1 - 격막에 의한 가스 분리방법 - Google Patents
격막에 의한 가스 분리방법 Download PDFInfo
- Publication number
- KR840000966B1 KR840000966B1 KR7900821A KR790000821A KR840000966B1 KR 840000966 B1 KR840000966 B1 KR 840000966B1 KR 7900821 A KR7900821 A KR 7900821A KR 790000821 A KR790000821 A KR 790000821A KR 840000966 B1 KR840000966 B1 KR 840000966B1
- Authority
- KR
- South Korea
- Prior art keywords
- gas
- permeate
- ammonia
- stage
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000926 separation method Methods 0.000 title abstract description 36
- 239000012528 membrane Substances 0.000 claims abstract description 73
- 238000000034 method Methods 0.000 claims abstract description 44
- 239000012466 permeate Substances 0.000 claims description 199
- 239000000203 mixture Substances 0.000 claims description 30
- 230000035699 permeability Effects 0.000 claims description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 363
- 229910021529 ammonia Inorganic materials 0.000 abstract description 182
- 238000003786 synthesis reaction Methods 0.000 abstract description 142
- 230000015572 biosynthetic process Effects 0.000 abstract description 129
- 230000008569 process Effects 0.000 abstract description 30
- 238000004064 recycling Methods 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 266
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 81
- 239000001257 hydrogen Substances 0.000 description 67
- 229910052739 hydrogen Inorganic materials 0.000 description 67
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 62
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 48
- 229910052757 nitrogen Inorganic materials 0.000 description 41
- 239000002994 raw material Substances 0.000 description 34
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 229910001868 water Inorganic materials 0.000 description 19
- 241000196324 Embryophyta Species 0.000 description 15
- 229910052786 argon Inorganic materials 0.000 description 15
- 239000000835 fiber Substances 0.000 description 15
- 239000000356 contaminant Substances 0.000 description 12
- 238000011084 recovery Methods 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 7
- 230000006835 compression Effects 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 239000012495 reaction gas Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000001311 chemical methods and process Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000008246 gaseous mixture Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002407 reforming Methods 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000001223 reverse osmosis Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- QYTBWVFCSVDTEC-UHFFFAOYSA-N azane;iron Chemical compound N.[Fe] QYTBWVFCSVDTEC-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229940113088 dimethylacetamide Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007430 reference method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
- C01C1/0476—Purge gas treatment, e.g. for removal of inert gases or recovery of H2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/225—Multiple stage diffusion
- B01D53/226—Multiple stage diffusion in serial connexion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US888103 | 1978-03-20 | ||
US888105 | 1978-03-20 | ||
US05/888,105 US4180388A (en) | 1978-03-20 | 1978-03-20 | Processes |
US05/888,103 US4180552A (en) | 1978-03-20 | 1978-03-20 | Process for hydrogen recovery from ammonia purge gases |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830000538A KR830000538A (ko) | 1983-04-16 |
KR840000966B1 true KR840000966B1 (ko) | 1984-07-02 |
Family
ID=27128872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR7900821A Expired KR840000966B1 (ko) | 1978-03-20 | 1979-03-19 | 격막에 의한 가스 분리방법 |
Country Status (14)
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4367135A (en) * | 1981-03-12 | 1983-01-04 | Monsanto Company | Processes |
US4362613A (en) * | 1981-03-13 | 1982-12-07 | Monsanto Company | Hydrocracking processes having an enhanced efficiency of hydrogen utilization |
EP0075431A1 (en) * | 1981-09-17 | 1983-03-30 | Monsanto Company | Method of separating one gas from a mixture of gases |
JPS5990613A (ja) * | 1982-07-29 | 1984-05-25 | リンデ・アクチエンゲゼルシヤフト | ガス混合物の分離方法及び装置 |
WO1990007372A1 (en) * | 1986-10-27 | 1990-07-12 | Richard Alan Sauer | Process for membrane separation of gas mixtures |
US4758250A (en) * | 1987-06-01 | 1988-07-19 | Air Products And Chemicals, Inc. | Ammonia separation using ion exchange polymeric membranes and sorbents |
US4762535A (en) * | 1987-06-02 | 1988-08-09 | Air Products And Chemicals, Inc. | Ammonia separation using semipermeable membranes |
DE4010603A1 (de) * | 1989-04-05 | 1990-10-11 | Piesteritz Agrochemie | Verfahren zur stofflichen nutzung von produktentspannungsgas |
DE4010602A1 (de) * | 1989-04-05 | 1990-10-11 | Piesteritz Agrochemie | Verfahren zur stofflichen nutzung von restgasen aus einer edelgasanlage |
FR2731163B1 (fr) * | 1995-03-03 | 1997-06-20 | Air Liquide | Procede et installation de separation d'un melange gazeux par permeation |
JP2008247654A (ja) * | 2007-03-29 | 2008-10-16 | Hiroshima Univ | アンモニアの分離方法、製造方法、及び気体分離膜 |
JP7031214B2 (ja) * | 2017-10-13 | 2022-03-08 | 宇部興産株式会社 | ヘリウム富化ガスの製造方法及びガス分離システム |
IT202100028049A1 (it) * | 2021-11-04 | 2023-05-04 | Nuovo Pignone Tecnologie Srl | Impianto e metodo per la sintesi di ammoniaca |
JPWO2024117237A1 (enrdf_load_stackoverflow) * | 2022-12-02 | 2024-06-06 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3657113A (en) | 1970-02-03 | 1972-04-18 | Mobil Oil Corp | Separating fluids with selective membranes |
JPS5610089B2 (enrdf_load_stackoverflow) * | 1973-07-31 | 1981-03-05 | ||
JPS5297684A (en) * | 1976-02-12 | 1977-08-16 | Mitsubishi Electric Corp | Semiconductor element |
JPS52114576A (en) * | 1976-03-24 | 1977-09-26 | Toshiba Corp | Gas separator |
-
1979
- 1979-03-16 NL NLAANVRAGE7902101,A patent/NL182796C/xx not_active IP Right Cessation
- 1979-03-19 TR TR2079479A patent/TR20794A/xx unknown
- 1979-03-19 RO RO104954A patent/RO84536B/ro unknown
- 1979-03-19 DD DD79211653A patent/DD142299A5/de unknown
- 1979-03-19 RO RO7996952A patent/RO78306A/ro unknown
- 1979-03-19 BR BR7901688A patent/BR7901688A/pt unknown
- 1979-03-19 PL PL1979214236A patent/PL123383B1/pl unknown
- 1979-03-19 DE DE19792953814 patent/DE2953814A1/de active Pending
- 1979-03-19 FR FR7906906A patent/FR2420366B1/fr not_active Expired
- 1979-03-19 KR KR7900821A patent/KR840000966B1/ko not_active Expired
- 1979-03-19 AU AU45218/79A patent/AU517235B2/en not_active Expired
- 1979-03-19 GB GB7909629A patent/GB2016945B/en not_active Expired
- 1979-03-19 IT IT21114/79A patent/IT1113311B/it active
- 1979-03-19 JP JP54033153A patent/JPS6022966B2/ja not_active Expired
- 1979-03-19 DE DE19792910661 patent/DE2910661A1/de not_active Ceased
- 1979-03-19 CA CA323,747A patent/CA1129626A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS54130484A (en) | 1979-10-09 |
RO84536B (ro) | 1984-08-30 |
FR2420366A1 (fr) | 1979-10-19 |
KR830000538A (ko) | 1983-04-16 |
FR2420366B1 (fr) | 1985-05-31 |
NL7902101A (nl) | 1979-09-24 |
PL214236A1 (enrdf_load_stackoverflow) | 1980-02-25 |
IT1113311B (it) | 1986-01-20 |
RO78306A (ro) | 1982-04-12 |
CA1129626A (en) | 1982-08-17 |
DE2910661A1 (de) | 1979-10-18 |
IT7921114A0 (it) | 1979-03-19 |
DD142299A5 (de) | 1980-06-18 |
PL123383B1 (en) | 1982-10-30 |
RO84536A (ro) | 1984-06-21 |
NL182796C (nl) | 1988-05-16 |
DE2953814A1 (enrdf_load_stackoverflow) | 1982-09-16 |
JPS6022966B2 (ja) | 1985-06-05 |
TR20794A (tr) | 1982-08-17 |
GB2016945A (en) | 1979-10-03 |
BR7901688A (pt) | 1979-10-16 |
NL182796B (nl) | 1987-12-16 |
AU4521879A (en) | 1979-09-27 |
AU517235B2 (en) | 1981-07-16 |
GB2016945B (en) | 1982-09-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19790319 |
|
PG1605 | Publication of application before grant of patent |
Comment text: Decision on Publication of Application Patent event code: PG16051S01I Patent event date: 19840618 |
|
PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19840915 |
|
PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 19841020 Patent event code: PR07011E01D |
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PR1002 | Payment of registration fee |
Payment date: 19841020 End annual number: 3 Start annual number: 1 |
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PR1001 | Payment of annual fee |
Payment date: 19870514 Start annual number: 4 End annual number: 4 |
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PR1001 | Payment of annual fee |
Payment date: 19880130 Start annual number: 5 End annual number: 5 |
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PR1001 | Payment of annual fee |
Payment date: 19890519 Start annual number: 6 End annual number: 6 |
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PR1001 | Payment of annual fee |
Payment date: 19900521 Start annual number: 7 End annual number: 7 |
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PR1001 | Payment of annual fee |
Payment date: 19910524 Start annual number: 8 End annual number: 8 |
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PR1001 | Payment of annual fee |
Payment date: 19920625 Start annual number: 9 End annual number: 9 |
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PR1001 | Payment of annual fee |
Payment date: 19930623 Start annual number: 10 End annual number: 10 |
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PC1801 | Expiration of term |