KR840000274A - 바나듐/인 혼합산화물 촉매의 제조방법 - Google Patents

바나듐/인 혼합산화물 촉매의 제조방법 Download PDF

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Publication number
KR840000274A
KR840000274A KR1019820003414A KR820003414A KR840000274A KR 840000274 A KR840000274 A KR 840000274A KR 1019820003414 A KR1019820003414 A KR 1019820003414A KR 820003414 A KR820003414 A KR 820003414A KR 840000274 A KR840000274 A KR 840000274A
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South Korea
Prior art keywords
phosphoric acid
vanadium
compound
process according
reaction
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KR1019820003414A
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English (en)
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알페르스 하인쯔-외르겐
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하인쯔-게르트 뮬러, 요하임 그렘
바이엘 아크티엔 게젤샤프트
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Application filed by 하인쯔-게르트 뮬러, 요하임 그렘, 바이엘 아크티엔 게젤샤프트 filed Critical 하인쯔-게르트 뮬러, 요하임 그렘
Publication of KR840000274A publication Critical patent/KR840000274A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

바나듐/인 혼합산화물 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 바나듐(V)화합물을 인산 및/또는 인산을 형성하는 화합물과 임의로 물 존재하에 가열하면서 반응시키고 계속하여 반응후에 수득된 생성물을 임의로 촉진제 존재하에 상승된 온도에서 환원력을 갖는 유기용매 및/또는 희석제로 처리함을 특징으로 하여 바나듐/인혼합 산화물 촉매를 제조하는 방법.
  2. 제1항에 있어서, 사용되는 바나듐(V)화합물이 바나듐 펜톡사이드, 암모늄 바나데이트 및/또는 나트륨 바나데이트 임이 특징인 방법.
  3. 제1항 및 2항에 있어서, 사용되는 인산을 형성하는 화합물이 포스포러스 펜톡사이드, m-인산 및/또는 폴리인산임이 특징인 방법.
  4. 제1항 내지 3항에 있어서, 바나듐(V)화합물과 인산 및/또는 인산을 형성하는 화합물과의 반응을 80내지 180℃에서 수행함이 특징인 방법.
  5. 제1항 내지 4항에 있어서, 반응후에 수득된 생성물을 계속 처리하는 과정을 80내지 200℃에서 수행함이 특징인 방법.
  6. 제1항 내지 5항에 있어서, 사용되는 유기용매 및/또는 희석제가 탄소, 산소 및 수소를 포함하면서 분자내의 탄소수가 1내지 10인 극성 화합물임이 특징인 방법.
  7. 제1항 내지 6항에 있어서, 사용되는 유기용매 및/또는 희석제가 탄소수 1내지 10의 지방족, 지환족 또는 아르지방족, 포화 또는 불포화 알콜, 알데히드, 케톤, 산 및/또는 에스테르임이 특징인 방법.
  8. 제1항 내지 7항에 있어서, 사용되는 촉매 촉진제가 멘델레프의 원소 주기율 표의 1족, 2족, 7족 및/또는 8족 아족 원소임이 특징인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019820003414A 1981-07-31 1982-07-30 바나듐/인 혼합산화물 촉매의 제조방법 KR840000274A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19813130343 DE3130343A1 (de) 1981-07-31 1981-07-31 Vanadium/phosphor-mischoxid-katalysator, verfahren zu dessen herstellung sowie dessen verwendung
DE3130343.9 1981-07-31

Publications (1)

Publication Number Publication Date
KR840000274A true KR840000274A (ko) 1984-02-18

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ID=6138261

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019820003414A KR840000274A (ko) 1981-07-31 1982-07-30 바나듐/인 혼합산화물 촉매의 제조방법

Country Status (7)

Country Link
US (1) US4784981A (ko)
EP (1) EP0071140B1 (ko)
JP (1) JPS5830341A (ko)
KR (1) KR840000274A (ko)
CS (1) CS229939B2 (ko)
DE (2) DE3130343A1 (ko)
ES (1) ES8305596A1 (ko)

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US4510258A (en) * 1983-08-17 1985-04-09 The Lummus Company Catalysts containing mixed oxides of vanadium and phosphorus
US5019545A (en) * 1988-07-28 1991-05-28 Amoco Corporation Process for manufacture of maleic anhydride catalysts
US4973569A (en) * 1988-11-01 1990-11-27 The Dow Chemical Company Preparation of group VB metal phosphate catalysts therefor
US4965235A (en) * 1989-05-15 1990-10-23 Amoco Corporation Maleic anhydride catalysts and process for their manufacture
KR950006529B1 (ko) * 1990-03-13 1995-06-16 가부시끼가이샤 닛뽄 쇼꾸바이 메타크릴산의 제조방법
DE4129642C2 (de) * 1990-09-07 1998-07-02 Nippon Catalytic Chem Ind Verfahren zur Herstellung von Methacrylsäure und/oder niederen Alkylestern von Methacrylsäure
US5137860A (en) * 1991-06-27 1992-08-11 Monsanto Company Process for the transformation of vanadium/phosphorus mixed oxide catalyst precursors into active catalysts for the production of maleic anhydride
US5275996A (en) * 1992-05-22 1994-01-04 Monsanto Company Phosphorous/vanadium oxide catalyst and process of preparation thereof
US5364824A (en) * 1992-12-08 1994-11-15 Huntsman Specialty Chemicals Corporation Catalysis for the production of maleic anhydride containing vanadium-phosphorus oxide with selected promoter elements
JP3603331B2 (ja) * 1994-06-30 2004-12-22 住友化学株式会社 Ｃ４−ｌｐｇを用いる含酸素化合物の製造法
US5641722A (en) * 1994-09-15 1997-06-24 Huntsman Petrochemical Corporation High performance VPO catalyst and process of preparation thereof
DE19840224C2 (de) * 1998-09-03 2002-09-12 Consortium Elektrochem Ind Verfahren zur Herstellung von Katalysatoren für die Synthese von Maleinsäureanhydrid durch Gasphasenoxidation
DE102005035978A1 (de) * 2005-07-28 2007-02-01 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE102007012724A1 (de) * 2007-03-16 2008-09-18 Basf Se Polynäres Metalloxidphosphat
DE102007012722A1 (de) * 2007-03-16 2008-09-18 Basf Se Polynäres Metall-Vanadiumoxidphosphat
DE102007012725A1 (de) * 2007-03-16 2008-09-18 Basf Se Polynäres Metalloxidphosphat
DE102007012723A1 (de) * 2007-03-16 2008-09-18 Basf Se Polynäres Vanadylpyrophosphat
DE102008025834A1 (de) 2008-05-29 2009-12-03 Bayer Technology Services Gmbh Verfahren zur Herstellung von Maleinsäureanhydrid
US9573119B2 (en) 2011-09-16 2017-02-21 Eastman Chemical Company Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8993801B2 (en) 2011-09-16 2015-03-31 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8883672B2 (en) 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8765629B2 (en) 2011-09-16 2014-07-01 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids

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US4225465A (en) * 1978-05-02 1980-09-30 Standard Oil Company (Ohio) Production of maleic anhydride from four-carbon hydrocarbons using catalysts prepared by hydrothermal techniques
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Also Published As

Publication number Publication date
EP0071140B1 (de) 1986-04-09
US4784981A (en) 1988-11-15
ES514575A0 (es) 1983-04-16
DE3130343A1 (de) 1983-02-17
EP0071140A3 (en) 1984-04-25
JPS5830341A (ja) 1983-02-22
DE3270396D1 (en) 1986-05-15
JPH0262303B2 (ko) 1990-12-25
ES8305596A1 (es) 1983-04-16
CS229939B2 (en) 1984-07-16
EP0071140A2 (de) 1983-02-09

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