KR830008723A - 인산염 함유 촉매용 담체 - Google Patents

인산염 함유 촉매용 담체 Download PDF

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Publication number
KR830008723A
KR830008723A KR1019820000311A KR820000311A KR830008723A KR 830008723 A KR830008723 A KR 830008723A KR 1019820000311 A KR1019820000311 A KR 1019820000311A KR 820000311 A KR820000311 A KR 820000311A KR 830008723 A KR830008723 A KR 830008723A
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South Korea
Prior art keywords
catalyst
carrier
phosphate
component
silica
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KR1019820000311A
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English (en)
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KR860000483B1 (ko
Inventor
다니엘 쉘리아
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티·진 딜라 헌티
앳슈랜드 오일 인코포레이팃드
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/185Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/16Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

인산염 함유 촉매용 담체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 담체와 촉매로 조성되는 2성분 촉매계에 있어서, 불활성 담체와 인산염 함유 성분의 액상 용매 슬러리형을 시성키고, 용매의 증발을 행하여 무수상태의 괴체(덩어리)를 형성시킨 다음 소성시킴을 특징으로 하여 인산염 함유 촉매와 인산염 농후 처리한 불활성 담체를 물리적 혼합시켜 성되는 2성분 촉계.
  2. 제1항에 있어서, 상기 불활성 담체가 실리카, 티타니아 또는 지르코니아임을 특징으로 하는 촉매계.
  3. 제1항에 있어서, 상기 액상 용매가 물이고,상기 인함유 화합물이 인산임을 특징으로 하는 촉매계.
  4. 제1항에 있어서, 상기 인산염 함유 촉매가 철-인산염 촉매임을 특징으로 하는 촉매계.
  5. 제4항에 있어서, 상기 불활성 담체가 실리카임을 특징으로 하는 촉매계.
  6. 제4항에 있어서, 상기 인산염 함유성분이 인산이고, 상기 액상 용매가 물임을 특징으로 하는 촉매계.
  7. 제4항에 얻은, 촉매계를 이소부티르산과 산소와 함께 물리적으로 접촉시킴을 특징으로 하여 메타크릴산을 제조하는 방법.
  8. 촉매와 담체로 조성되는 2성분 촉매계에 있어서, 일반식 FePxMeyOz (Me는 Li,Na, K,Rb, Cs, Mg, Ca, Sr 및 Ba 중에서 선택되는 1종 이상의 금속이고, x는 0.2내지 2.0이며,y는 0.10내지 2.0이며 z는 다른 원소들과 결합되어 이들 산화상태의 산소의 상당량임)으로 표시되는 촉매(a), 및 실리카와인 함유화합물을 액상 슬러리로 혼합시키고, 액체를 증발시킨 다음, 잔존하는 고상물을 소성시킴으로써 얻어지는 실리카와인 함유 화합물로 조성되는 담체(b)를 실질적으로 무수상태 하에서 함께 혼합시킴을 특징으로 하는 촉매와 담체로 조성되는 2성분 촉매계.
  9. 불활성 물질, 인산염 성분 및 액상 용매를 함께 혼합하여 슬러리를 형성시킨 다음 건조시킴을 특징으로 하는 불활성 물질과 인산염 성분으로 조성되는 촉매담체.
  10. 제9항에 있어서, 상기 불활성 물질이 실리카임을 특징으로 하는 촉매 담체.
  11. 제9항에 있어서, 상기 인산염 성분이 인산임을 특징으로 하는 촉매 담체.
  12. 실리카와 인산을 혼합하여 수성 슬러리를 형성시키고, 건조 및 소성시킴을 특징으로 하는 실리카와 인산수용액으로 조성되는 촉매 담체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8200311A 1981-01-26 1982-01-26 인산염 함유 이성분계 촉매 KR860000483B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/228,304 US4366088A (en) 1981-01-26 1981-01-26 Support for a phosphate-containing catalyst
US228304 1981-01-26
US228,304 1994-04-15

Publications (2)

Publication Number Publication Date
KR830008723A true KR830008723A (ko) 1983-12-14
KR860000483B1 KR860000483B1 (ko) 1986-04-30

Family

ID=22856615

Family Applications (1)

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KR8200311A KR860000483B1 (ko) 1981-01-26 1982-01-26 인산염 함유 이성분계 촉매

Country Status (18)

Country Link
US (1) US4366088A (ko)
JP (1) JPS608859B2 (ko)
KR (1) KR860000483B1 (ko)
AT (1) AT383050B (ko)
AU (1) AU543329B2 (ko)
BR (1) BR8200428A (ko)
CA (1) CA1186673A (ko)
CH (1) CH653916A5 (ko)
DD (1) DD208923A5 (ko)
DE (2) DE3202291C2 (ko)
ES (2) ES8502352A1 (ko)
FR (1) FR2498475B1 (ko)
GB (1) GB2092467B (ko)
IT (1) IT1150155B (ko)
MX (1) MX156886A (ko)
NL (1) NL8200275A (ko)
PL (1) PL138040B1 (ko)
ZA (1) ZA82500B (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4609761A (en) * 1983-01-03 1986-09-02 Texaco Inc. Continuous preparation of linear polyethylenepolyamines using novel catalysts derived from titania and a trialkyl phosphate or phosphite
US4612397A (en) * 1983-01-03 1986-09-16 Texaco, Inc. Use of supported phosphate catalysts for preparation of linear polyethylenepolyamines
DE3378365D1 (en) * 1983-01-03 1988-12-08 Texaco Development Corp Regenerative process for the preparation of linear polyethylenepolyamines using a supported catalyst
US4524143A (en) * 1983-01-03 1985-06-18 Texaco Inc. Catalyst for preparation of linear polyethylenepolyamines
US4588842A (en) * 1983-01-03 1986-05-13 Texaco Inc. Catalytic preparation of linear polyethylenepolyamines
US4578519A (en) * 1983-01-03 1986-03-25 Texaco Inc. (Parent) Catalytic synthesis of linear polyethylenepolyamines (polyethylenepolyamine preparation and catalyst)
JPS59150538A (ja) * 1983-01-03 1984-08-28 テキサコ・デベロツプメント・コ−ポレ−シヨン 担持された触媒を用いた線状ポリエチレンポリアミンの製造方法
US4578518A (en) * 1983-01-03 1986-03-25 Texaco Inc. Catalytic (calcined catalyst and) preparation of linear polyethylenepolyamines (therewith)
US4555582A (en) * 1983-01-03 1985-11-26 Texaco Inc. Catalytic preparation of linear polyethylenepolyamines [with supported catalyst]
US4584406A (en) * 1983-01-03 1986-04-22 Texaco Inc. Preparation of linear polyethylenepolyamines with modified catalysts
FR2657792B1 (fr) * 1990-02-07 1992-05-15 Norsolor Sa Systeme catalytique et son application a l'oxydeshydrogenation d'acides carboxyliques satures.
FR2921361B1 (fr) * 2007-09-20 2012-10-12 Arkema France Procede de fabrication d'acroleine a partir de glycerol
WO2009127889A1 (en) * 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
EP2179981A1 (en) 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
CN114471635B (zh) * 2020-10-27 2024-01-12 中国石油化工股份有限公司 一种催化氧化催化剂及其制备方法和应用

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DE893048C (de) 1935-10-23 1953-10-12 Universal Oil Prod Co Verfahren zur Herstellung von hochaktiven festen, kalzinierten Katalysatoren
US2220430A (en) * 1938-02-21 1940-11-05 Distillers Co Yeast Ltd Catalytic dehydration of alcohols
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Also Published As

Publication number Publication date
ES509884A0 (es) 1985-01-01
IT8219318A0 (it) 1982-01-26
KR860000483B1 (ko) 1986-04-30
CA1186673A (en) 1985-05-07
NL8200275A (nl) 1982-08-16
GB2092467A (en) 1982-08-18
MX156886A (es) 1988-10-10
FR2498475A1 (fr) 1982-07-30
IT1150155B (it) 1986-12-10
JPS608859B2 (ja) 1985-03-06
PL235178A1 (en) 1983-03-28
DD208923A5 (de) 1984-04-18
DE3202291A1 (de) 1982-08-19
ATA27682A (de) 1986-10-15
GB2092467B (en) 1984-09-26
DE3202291C2 (de) 1986-03-13
AU543329B2 (en) 1985-04-18
AT383050B (de) 1987-05-11
ES8503969A1 (es) 1985-04-16
FR2498475B1 (fr) 1988-08-26
JPS57147441A (en) 1982-09-11
ES527404A0 (es) 1985-04-16
DE3246038C2 (ko) 1987-01-22
CH653916A5 (de) 1986-01-31
PL138040B1 (en) 1986-08-30
BR8200428A (pt) 1982-11-30
US4366088A (en) 1982-12-28
ZA82500B (en) 1982-12-29
ES8502352A1 (es) 1985-01-01
AU7989282A (en) 1982-09-09

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