ES8307703A1 - Procedimiento para la preparacion de acido metacrilico. - Google Patents
Procedimiento para la preparacion de acido metacrilico.Info
- Publication number
- ES8307703A1 ES8307703A1 ES517285A ES517285A ES8307703A1 ES 8307703 A1 ES8307703 A1 ES 8307703A1 ES 517285 A ES517285 A ES 517285A ES 517285 A ES517285 A ES 517285A ES 8307703 A1 ES8307703 A1 ES 8307703A1
- Authority
- ES
- Spain
- Prior art keywords
- carrier
- methacrylic acid
- catalyst
- production
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA PREPARACION DE ACIDO METACRILICO. SE EFECTUA UNA DESHIDRATACION OXIDATIVA DE ACIDO ISOBUTIRICO EN LA FASE VAPOR A TEMPERATURAS POR ENCIMA DE 300 C EN UN CATALIZADOR EN BASE A LOS ELEMENTOS MOLIBDENO, VANADIO, FOSFORO Y OXIGENO. SE EMPLEA UN CATALIZADOR OBTENIDO POR IMPREGNACION DE UN SOPORTE CON UNA POROSIDAD DE 10 A 80% Y UNA SUPERFICIE INTERIOR POR DEBAJO DE 1 QM/G CON UNA SOLUCION ACUOSA HOMOGENEA DE LOS COMPONENTES ACTIVOS DEL CATALIZADOR. EL CATALIZADOR CONTIENE PREDOMINANTEMENTE CARBURO DE SILICIO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19813145091 DE3145091A1 (de) | 1981-11-13 | 1981-11-13 | Verfahren zur herstellung von methacrylsaeure |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8307703A1 true ES8307703A1 (es) | 1983-08-16 |
ES517285A0 ES517285A0 (es) | 1983-08-16 |
Family
ID=6146304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES517285A Granted ES517285A0 (es) | 1981-11-13 | 1982-11-11 | Procedimiento para la preparacion de acido metacrilico. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0079491B1 (es) |
JP (1) | JPS5896040A (es) |
CA (1) | CA1194014A (es) |
DE (2) | DE3145091A1 (es) |
ES (1) | ES517285A0 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3248600A1 (de) * | 1982-12-30 | 1984-07-12 | Röhm GmbH, 6100 Darmstadt | Verwendung von mo-v-cu-p-katalysatoren zur oxydehydrierung von isobuttersaeure oder deren estern |
DE3626256A1 (de) * | 1986-08-02 | 1988-02-11 | Roehm Gmbh | Heteropolymolybdat-gemische und ihre verwendung als katalysatoren |
DE3626255A1 (de) * | 1986-08-02 | 1988-02-11 | Roehm Gmbh | Regenerativ-katalytische oxidehydrierung von isobuttersaeure oder deren estern |
ES2023965B3 (es) * | 1987-03-17 | 1992-02-16 | Roehm Gmbh | Estabilizacion de actividad y reactivado de catalizadores de heteropoliacidos |
DE3710784A1 (de) * | 1987-03-31 | 1988-10-13 | Roehm Gmbh | Heteropolysaeure-oxidations-katalysatoren mit verbessertem langzeit-aktivitaets-verhalten |
DE3732106A1 (de) * | 1987-09-24 | 1989-04-06 | Roehm Gmbh | Verfahren zur oxydehydrierung von isobuttersaeure |
GB2228696B (en) * | 1987-10-07 | 1991-09-04 | Hitachi Metals Ltd | Die casting cylinder |
DE4113423A1 (de) * | 1991-04-25 | 1992-10-29 | Roehm Gmbh | Mit makroporen durchsetzter oxidationskatalysator |
US8178718B2 (en) * | 2007-02-05 | 2012-05-15 | Saudi Basic Industries Corporation | Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52138499A (en) * | 1976-05-17 | 1977-11-18 | Mitsubishi Chem Ind Ltd | Production of heteropolyacid |
FR2362108A1 (fr) * | 1976-08-18 | 1978-03-17 | Mitsubishi Chem Ind | Perfectionnements a la preparation de l'acide methacrylique |
DE2849715A1 (de) * | 1978-11-16 | 1980-05-29 | Hoechst Ag | Traegerkatalysator und verfahren zu seiner herstellung |
JPS5637050A (en) * | 1979-09-04 | 1981-04-10 | Ube Ind Ltd | Preparation of catalyst for preparing unsaturated acid |
DE3161102D1 (en) * | 1980-08-28 | 1983-11-10 | Roehm Gmbh | Process for the oxidizing dehydrogenation of isobutyric acid to methacrylic acid |
US4307247A (en) * | 1980-09-05 | 1981-12-22 | Standard Oil Company | Process for the production of unsaturated acids and esters |
US4314075A (en) * | 1980-09-05 | 1982-02-02 | The Standard Oil Company | Process for the production of olefinic acids and esters |
-
1981
- 1981-11-13 DE DE19813145091 patent/DE3145091A1/de not_active Withdrawn
-
1982
- 1982-10-26 DE DE8282109859T patent/DE3264684D1/de not_active Expired
- 1982-10-26 EP EP82109859A patent/EP0079491B1/de not_active Expired
- 1982-11-11 ES ES517285A patent/ES517285A0/es active Granted
- 1982-11-12 JP JP57197852A patent/JPS5896040A/ja active Granted
- 1982-11-12 CA CA000415415A patent/CA1194014A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CA1194014A (en) | 1985-09-24 |
JPH0531533B2 (es) | 1993-05-12 |
DE3145091A1 (de) | 1983-05-19 |
EP0079491A1 (de) | 1983-05-25 |
JPS5896040A (ja) | 1983-06-07 |
ES517285A0 (es) | 1983-08-16 |
EP0079491B1 (de) | 1985-07-10 |
DE3264684D1 (en) | 1985-08-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19971001 |