KR20220138054A - 루테늄 착체를 흡착한 활성탄을 포함하는 촉매 및 이를 이용한 환원 생성물의 제조 방법 - Google Patents

루테늄 착체를 흡착한 활성탄을 포함하는 촉매 및 이를 이용한 환원 생성물의 제조 방법 Download PDF

Info

Publication number
KR20220138054A
KR20220138054A KR1020227031757A KR20227031757A KR20220138054A KR 20220138054 A KR20220138054 A KR 20220138054A KR 1020227031757 A KR1020227031757 A KR 1020227031757A KR 20227031757 A KR20227031757 A KR 20227031757A KR 20220138054 A KR20220138054 A KR 20220138054A
Authority
KR
South Korea
Prior art keywords
group
catalyst
activated carbon
complex
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020227031757A
Other languages
English (en)
Korean (ko)
Inventor
나오타 요코야마
신지 츠카다
타케후미 지시로
유스케 미야지
Original Assignee
다카사고 고료 고교 가부시키가이샤
오사카 가스 케미칼 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다카사고 고료 고교 가부시키가이샤, 오사카 가스 케미칼 가부시키가이샤 filed Critical 다카사고 고료 고교 가부시키가이샤
Publication of KR20220138054A publication Critical patent/KR20220138054A/ko
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00Asymmetric syntheses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00Other general methods
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/30Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/159Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with reducing agents other than hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02Monohydroxylic acyclic alcohols
    • C07C31/125Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/18Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part
    • C07C33/20Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part monocyclic
    • C07C33/22Benzylalcohol; phenethyl alcohol
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/40Halogenated unsaturated alcohols
    • C07C33/46Halogenated unsaturated alcohols containing only six-membered aromatic rings as cyclic parts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/18Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/26Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/20Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/23Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing hydroxy or O-metal groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286Complexes comprising ligands or other components characterized by their function
    • B01J2531/0288Sterically demanding or shielding ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30Non-coordinating groups comprising sulfur
    • B01J2540/34Sulfonyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020227031757A 2020-03-03 2021-03-02 루테늄 착체를 흡착한 활성탄을 포함하는 촉매 및 이를 이용한 환원 생성물의 제조 방법 Pending KR20220138054A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2020036096 2020-03-03
JPJP-P-2020-036096 2020-03-03
PCT/JP2021/007899 WO2021177287A1 (ja) 2020-03-03 2021-03-02 ルテニウム錯体を吸着した活性炭を含む触媒、及びそれを用いた還元生成物の製造方法

Publications (1)

Publication Number Publication Date
KR20220138054A true KR20220138054A (ko) 2022-10-12

Family

ID=77612623

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020227031757A Pending KR20220138054A (ko) 2020-03-03 2021-03-02 루테늄 착체를 흡착한 활성탄을 포함하는 촉매 및 이를 이용한 환원 생성물의 제조 방법

Country Status (6)

Country Link
US (1) US20230285945A1 (https=)
EP (1) EP4115975A4 (https=)
JP (1) JP7713439B2 (https=)
KR (1) KR20220138054A (https=)
CN (1) CN115209993A (https=)
WO (1) WO2021177287A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116440890B (zh) * 2022-01-10 2024-10-18 万华化学(宁波)有限公司 一种用于光气合成的高活性可再生活性炭的制备方法及其在线再生工艺

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5718178B2 (https=) 1977-11-29 1982-04-15
JPS5727127B2 (https=) 1972-05-25 1982-06-09
JP3040353B2 (ja) 1996-10-25 2000-05-15 科学技術振興事業団 ルテニウム−ジアミン錯体及びこれを触媒とする光学活性アルコール類の製造方法
WO2016056669A1 (ja) 2014-10-10 2016-04-14 高砂香料工業株式会社 固相担持ルテニウム-ジアミン錯体及び光学活性化合物の製造方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990015791A1 (fr) * 1989-06-15 1990-12-27 Jgc Corporation Methode pour produire des esters carboniques et catalyseur relatif
JP4278220B2 (ja) * 1999-03-09 2009-06-10 ダイセル化学工業株式会社 アルデヒドの製造法
EP1180108B1 (en) * 1999-05-24 2003-08-27 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
GB0029356D0 (en) * 2000-12-01 2001-01-17 Avecia Ltd Transfer hydrogenation
WO2002076920A1 (en) * 2001-03-26 2002-10-03 Dow Global Technologies Inc. Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins
DE10326915A1 (de) * 2003-06-16 2005-01-05 Bayer Chemicals Ag Verfahren zur asymmetrischen Hydrierung von Ketocarbonsäureestern
KR101085804B1 (ko) * 2004-03-29 2011-11-22 간토 가가꾸 가부시키가이샤 광학 활성 알코올의 제법
GB0420605D0 (en) * 2004-09-16 2004-10-20 Johnson Matthey Plc "Heterogenised" homogeneous catalysts
JP2006312626A (ja) * 2005-04-07 2006-11-16 Kyowa Hakko Kogyo Co Ltd 光学活性アミノアルコールの製造法
JP5068960B2 (ja) * 2006-04-14 2012-11-07 第一三共株式会社 光学活性配位子
CN101176853B (zh) * 2006-11-09 2010-11-17 中国科学院大连化学物理研究所 手性二胺-金属配合物多相催化剂及制备方法和应用
JP5727127B2 (ja) 2009-04-10 2015-06-03 関東化学株式会社 不斉触媒およびこれを用いた光学活性アルコール類の製造方法
JP5244158B2 (ja) * 2010-07-26 2013-07-24 関東化学株式会社 光学活性アルコールの製法
CN103080118B (zh) * 2010-08-26 2016-05-11 高砂香料工业株式会社 钌-二胺络合物和生产光学活性化合物的方法
CN102050688A (zh) * 2010-12-07 2011-05-11 中国科学院化学研究所 一种酮衍生的n-烷基亚胺的不对称催化氢化方法
JPWO2012147944A1 (ja) * 2011-04-28 2014-07-28 高砂香料工業株式会社 ジアミン化合物の製造方法
CA2832994A1 (en) * 2011-05-06 2012-11-15 Takasago International Corporation Ruthenium-diamine complex and method for producing optically active compound
US20140296562A1 (en) * 2011-10-31 2014-10-02 Takasago International Corporation Method for producing optically active beta-hydroxy-alpha-aminocarboxylic acid ester
CN105149000B (zh) * 2015-09-08 2017-07-11 陕西师范大学 一种负载型环状金属铱催化剂及其制备方法和在二氢吲哚类化合物脱氢反应中的应用
CN105289738A (zh) * 2015-11-26 2016-02-03 上海师范大学 一种手性乙二胺钌配合物修饰的聚乙二醇功能化的介孔硅纳米球及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5727127B2 (https=) 1972-05-25 1982-06-09
JPS5718178B2 (https=) 1977-11-29 1982-04-15
JP3040353B2 (ja) 1996-10-25 2000-05-15 科学技術振興事業団 ルテニウム−ジアミン錯体及びこれを触媒とする光学活性アルコール類の製造方法
WO2016056669A1 (ja) 2014-10-10 2016-04-14 高砂香料工業株式会社 固相担持ルテニウム-ジアミン錯体及び光学活性化合物の製造方法

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
Acc. Chem. Res. 30 (1997) p. 97-102
Chem. Commun. 46 (2010) p. 8145-8147
J. Am. Chem. Soc. 133 (2011) p. 14960-14963
Org. Lett. 1 (1999) p. 713-715
Org. Lett. 4 (2002) p. 2369-2371
Org. Lett. 6 (2004) p. 169-172
Org. Process Res. Dev. 22 (2018) p. 1580-1585
Tetrahedron Asymmetry 9 (1998) p. 2015-2018

Also Published As

Publication number Publication date
EP4115975A4 (en) 2024-05-15
CN115209993A (zh) 2022-10-18
US20230285945A1 (en) 2023-09-14
JP7713439B2 (ja) 2025-07-25
WO2021177287A1 (ja) 2021-09-10
JPWO2021177287A1 (https=) 2021-09-10
EP4115975A1 (en) 2023-01-11

Similar Documents

Publication Publication Date Title
Wang et al. Hydrogen-bonded organic frameworks as a tunable platform for functional materials
Liu et al. Constructing donor‐acceptor covalent organic frameworks for highly efficient H2O2 photosynthesis coupled with oxidative organic transformations
Lu et al. Postsynthetic functionalization of three‐dimensional covalent organic frameworks for selective extraction of lanthanide ions
Xuan et al. A chiral quadruple-stranded helicate cage for enantioselective recognition and separation
Bhadra et al. Predesigned metal-anchored building block for in situ generation of Pd nanoparticles in porous covalent organic framework: Application in heterogeneous tandem catalysis
KR102011160B1 (ko) 예외적으로 큰 기공 간극을 갖는 금속 유기 골격체
Rosario‐Amorin et al. Metallodendritic Grafted Core–Shell γ‐Fe2O3 Nanoparticles Used as Recoverable Catalysts in Suzuki C C Coupling Reactions
Zhang et al. Engineering a zirconium MOF through tandem “click” reactions: A general strategy for quantitative loading of bifunctional groups on the pore surface
KR20150007484A (ko) 신규한 아연-금속 유기 구조체 화합물, 이를 포함하는 이산화탄소 흡착제 및 에스터 교환 반응 불균일 촉매
Jin et al. Homochiral BINAPDA-Zr-MOF for heterogeneous asymmetric cyanosilylation of aldehydes
KR20120129905A (ko) 카베노필릭 금속으로부터 유도된 유기-금속 프레임워크 및 그의 제조방법
KR20210025921A (ko) 2종 이상의 리간드를 포함하는, 3차원 다공성 구조를 갖는 신규한 알루미늄-기반 금속-유기 골격체, 이의 제조방법 및 용도
Patra et al. Silver nanoparticle-functionalized postsynthetically modified thiol MOF UiO-66-NH-SH for efficient CO2 fixation
Zhu et al. Facile synthesis of a fully fused, three-dimensional π-conjugated Archimedean cage with magnetically shielded cavity
Zhang et al. Raising the asymmetric catalytic efficiency of chiral covalent organic frameworks by tuning the pore environment
Zhang et al. Iodine adsorption–desorption-induced structural transformation and improved Ag+ turn-on luminescent sensing performance of a nonporous Eu (III) metal–organic framework
Yue et al. Homochiral porous metal–organic frameworks constructed from a v-shaped alanine derivative based on pyridyl-dicarboxylate
Zhao et al. UiO-67 metal–organic framework immobilized Fe 3+ catalyst for efficient Morita–Baylis–Hillman reaction
Li et al. Primary amine-functionalized chiral covalent organic framework enables high-efficiency asymmetric catalysis in water
KR20220138054A (ko) 루테늄 착체를 흡착한 활성탄을 포함하는 촉매 및 이를 이용한 환원 생성물의 제조 방법
Zhu et al. A biomimetic metal–organic framework with cuboid inner cavities for enantioselective separation
KR101676442B1 (ko) 금속-유기 골격체의 재생방법
Feng et al. Facile one-pot fabrication of a silica gel-supported chiral phase-transfer catalyst—N-(2-cyanobenzyl)-O (9)-allyl-cinchonidinium salt
JP2018192397A (ja) 共有結合性有機構造体、共有結合性有機構造体を用いた吸着材、及び共有結合性有機構造体の製造方法
CN115678026B (zh) 一种手性功能化改性MOFs吸附剂及制备与在尼古丁对映体拆分中的应用

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D21 Rejection of application intended

Free format text: ST27 STATUS EVENT CODE: A-1-2-D10-D21-EXM-PE0902 (AS PROVIDED BY THE NATIONAL OFFICE)

PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11 Amendment of application requested

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P11-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000