KR20180006242A - Fertilizer compositions and methods for their preparation, including marine waste algae and Fish farm waste flounder fish - Google Patents

Abstract

The purpose of the present invention is to provide a functional fertilizer by maximizing fermentation and decomposition and producing high concentrations of amino acid using algae which is marine waste, fish farm waste flounder fish and fish by-products. A liquid fertilizer manufactured by marine waste algae, fish farm waste flounder fish and fish amino acids activates nutrition needed for plants and microorganisms useful for soil and promotes growth of roots, thereby improving soil with hazards caused by continuous cropping. Accordingly, various minerals and enzymes work so the liquid fertilizer of the present invention is effective in maintaining the sugar content, color and freshness.

Description

TECHNICAL FIELD [0001] The present invention relates to a fertilizer composition including a seaweed waste seaweed and a puffer fish, and a method for producing the same,

The present invention aims at economically producing high-concentration amino acid functional fertilizer by using seaweeds (marine algae, mung bean, etc.), aquaculture farmers and fish by-products. The present invention relates to a method for producing the same, and more particularly, to a more economical and highly efficient fertilizer production method for manufacturing a conventional single seaweed fertilizer and a fish liquid fertilizer.

It is aimed to maximize fermentation decomposition by using algae treated as coastal wastes together with fishermen and fish by-products, to produce high concentration of amino acid and to make functional fertilizer. copper. By fermenting and decomposing the vegetable together, it is economical to speed up the decomposition rate and increase the variety and content of amino acids. In particular, it increases the rate of decomposition of slow algae. In Jeju Island, environmental problems are caused by the green algae phenomenon of the hole corps, and capital and manpower are lost for disposal. On the other hand, one of the main characteristics of the perforated cormorant is that it contains a large amount of polysaccharide containing sulfuric acid group unlike the land plants. Therefore, prior art for methods of extraction, soy sauce manufacturing, this

But it aims to produce more efficient and economical fertilizer.

Fertilizers can be made competitively by making them economically suitable for the characteristics of the area.

It is aimed to produce fertilizer with higher value than using some algae that are considered to be local wastes and dead clams. In order to utilize our mineral water, we collect and process the collected water from the fish farms through auxiliary business in the fisheries cooperatives. Currently, it is 1300 won / Kg for simple primary processing. Most are sold on land, which is more economical to use. Focusing on the more economical production of high-efficiency liquid fertilizer, the emphasis was on increasing the amount of seaweed as much as possible. In particular, it is more efficient and economical to produce the high-functional fertilizer by the second production process in accordance with the actual characteristics of the Jeju area, and to accelerate decomposition of the seaweed and fish meal protein together with amino acid . Generally, seaweeds are not decomposed well and use high-temperature pyrolysis. On the contrary, they can keep the components lost by heating and heating, and it is possible to solve them by the microbial decomposition method. Modern agriculture is a reality that high-functional fertilizer is required for high density cultivation, especially house cultivation. And can be converted to realistic value resources rather than waste.

The hole cormorant is said to be a seaweed that warns of environmental pollution. "Although it is a factor of aesthetics and odor of a person like this, it is necessary to change the recognition as a report of true resources rather than as a waste resource." Recently, The number of seaweed products registered as eco-friendly organic materials in Korea is 20, however, in Korea, there are many seaweeds, In order to solve these problems, it is necessary to develop eco-friendly farming materials by utilizing abundant natural resources of Cheju Jeju and to use them easily in farmhouses. Production of fertilizer. The use of organic fertilizers that are beneficial to crops and prevent environmental pollution is increasing gradually. These organic fertilizers are vegetable amino acids, animal amino acids, among which the most effective algae liquid fertilizer Fish liquid fertilizer.According to the conventional production technology, they are separated and produced, and inefficient and non-economic method is improved, and the two kinds are combined and fermented and decomposed to accelerate the decomposition, and a fertilizer having various amino acids is produced. The lack of extracted amino acids can be met with animal-derived fish amino acids

Hydrolysis of enzymes according to the pretreatment conditions of the perforated rocks by stirring and hydrolyzing for 3 hours with the addition of sodium hydroxide (NaOH) or potassium hydroxide (KOH) at a ratio of 1: 0.15: Jung Sik Kim, Sung Jun Kim, Kwang Yong Kim * · Richard Kim **

Department of Environmental Engineering, Chonnam National University, ** Department of Earth and Environmental Sciences, Chonnam National University ** North Carolina State University: The rate of hydrolysis by temperature was found to be 51.6% in 0.1M HCl-treated autoclave at 121oC, 1.5 atm and 15min high pressure sterilization. Hydrolysis was performed using the hydrolysis enzyme Viscozyme Xylanase. Seaweed Extracts, Their Diets and Fertilizers, and Seaweed Extracts Using Hydrolytic Enzymes in Their Preparation Methods.

Publication No. 10-2009-0057539 Method of producing liquid fertilizer by fermenting algae hole cormorant 5% of algae spikelets are Aspergillus niger, Micobacterium thalcium, Bacillus sp. And the fermentation process is carried out for 3-5 days at a temperature of 25-30 ° C and a reaction rate of 200-250 rpm to prepare a liquid fertilizer

No. 10-2009-0092399 Fermentation broth using kimchi and its production method 3 to 10% by weight of a microorganism enzyme containing Alcaligenes faecalis and Bacillus spericus as main components, sugar 7 to 20 Fermentation additive to make fermentation additive by mixing% by weight.

Salting-off Process Patent Literature 10-2014-0133135 When lime and fly ash are injected into the aerobic fermentation broth treated in the liquefaction and aerobic fermentation process and the reaction is carried out for 30 to 40 minutes, the salt becomes insoluble in water. The salt which is insoluble in water is dehydrated after precipitation, the dehydrated cake containing the salt is discarded, and the desalted solution is sent to the composting process for composting. The mechanism of this reaction is as follows. Fly-ash contains a large amount of pozzolanic material such as activated SiO 2 and Al 2 O 3. The pozzolanic material is subjected to a pozzolanic reaction with lime (Ca (OH) 2) Calcium silicate hydrates (3CaO · 2SiO2 · 3H2O) and calcium aluminate hydrates (3CaO · Al2O3 · 6H2O) are produced.

6CaO + 2SiO2 + 6H2O? 3CaO.2SiO2.3H2O + 3Ca (OH) 2 ... ... ... ... (4)

4CaO + 2SiO2 + 4H2O? 3CaO.2SiO2.3H2O + Ca (OH) 2 ... ... ... ... (5)

] 3CaO + Al2O3 + 6H2O? 3CaO? Al2O3? 6H2O ... ... ... ... ... ... ... ... ... (6)

 The chlorine ion (Cl -) contained in the aerobic fermentation broth reacts with calcium aluminate hydrate (3CaO · Al2O3 · 6H2O) and is treated in the form of Friedel's salt, which is insoluble in water, -) concentration. 3CaO · Al2O3 · 6H2O + 2Cl - + Ca (OH) 2 + 4H2O → 3CaO · Al2O3 · CaCl2 · 10H2O (Friedel's salt) ↓ + 2OH ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... (7)

Sodium ion (Na +) reacts with calcium silicate hydrates (3CaO · 2SiO2 · 3H2O) to generate sodium insoluble sodium silicate (Na2O · 3CaO · 2SiO2 · xH2O) Lt; / RTI > 3CaO.2SiO2.3H2O + 2Na + + 2OH - + X-3H2O? Na2O? 3CaO.2SiO2.XH2O + H2O ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... (8)

The reaction of the reaction formula (7) should be removed immediately after the reaction system because there is a fear that the reverse reaction occurs due to the carbonate ion generated during the aerobic fermentation and the chlorine ion is released. CO2 + H2O - > 2H + + CO3 2- [0037] ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... (9) 3CaO · Al 2 O 3 · CaCl 2 · 10H 2 O + CO 3 2- → 3CaO · Al 2 O 3 · CaCO 3 · 10H 2 O + 2Cl - (10)

In addition to the coal fly ash, it can be used instead of fly ash because it contains incinerators, incinerators, steelworks, coal after burning coal, volcanic cones, and pozzolan cement also contain pozzolanic materials.

Registration No. 10-0855338 Liquid fertilizer using fish meal waste solution for environment friendly agriculture field

Method of manufacturing liquid fertilizer by fermenting algae hole cormorant (10-2007-0124157)

Application No. 10-2012-0158014 Marine fermented feed, marine compost and method of manufacturing the same

Functional Enhanced Liquid Fertilizer Using Seaweed and Its Production Method 10-1225890

Registration Method No. 10-1225890 Functionally Enhanced Liquid Fertilizer Using Seaweeds and Their Manufacturing Method

Korean Patent Registration No. 10-0284282 as a desalination device for food waste

DISCLOSURE OF THE INVENTION An object of the present invention is to provide a liquid fertilizer having enhanced functionality by adding various functional materials to a seaweed decomposition extract,

Korean Patent Publication No. 10-2012-0081043, desalination apparatus for dehydrating food waste,

Public number 10-2014-0133135 Desalination of food waste

Non-patent document No. 10-2012-0081043, a device for desalination of food waste dehydrated filtrate

Application No. 10-2012-0158014 Marine fermented feed, marine compost and its manufacturing method

The value of algae as a source of fertilizer and soil organic matter in relation to plant growth has long been known (Stephenson, 1974) and has been used as a soil organic resource mainly in coastal farmland where marine algae harvesting and transport is easy (Blunden, 1991). Due to the chemical properties contained in seaweeds, it is possible to replenish and replenish trace elements that are often prone to shortage in common ground soils. Compared with composting, the same amount of algae is known to have a similar nitrogen content but a higher potassium content and a lower phosphate content (Chapman and Chapman, 1980) Considering the chemical characteristics of soil in Korea, which has a lot of phosphoric acid accumulation, it is an agricultural fertilizer resource which is more advantageous in terms of practical use.

The use of seaweeds in dry and powdered seaweeds and seaweed concentrates in soils and crops can contain a variety of inorganic and trace elements in seaweeds, which can replenish soil nutrients and improve soil microbial activity, (Milton, 1964; Caiozzi et al., 1968). The main difference between these two types of materials is that, in the case of seaweed powder, it takes a considerable amount of time to develop the effect because the organic nutrients contained in the seaweed must be decomposed by microorganisms before being used in plants . On the other hand, in case of the liquid product, the cellulose type components are already decomposed or removed. (Crouch and Staden, 1994), because it can be readily absorbed through the roots or sides of the plant as a method of using the fertilizer. In addition, algae extracts can be treated in biological agriculture and horticultural crops to reduce crop growth, reduce insect pests, increase yields and improve quality. The effect of seaweed treatment is based on the supply of plant hormones and trace elements contained in seaweeds (Verkleij, 1992). In the seaweed-related experiments, when analyzing the effects of specific components contained in seaweeds, and cytokinin-like substances, and trace elements that may exist in the form of chelates.

In general, fresh seaweeds contain nitrogen and potassium components and effective trace elements (Stephenson, 1974; Senn and Kingman, 1978), because they contain important alginic acid as an ingredient that affects soil physical improvement (Quastel and Webley , 1947) fertilizer and soil remediation agent can satisfy both aspects at the same time.

It is commercially available as a seaweed extract or seaweed powder in foreign countries and has been recognized as a fertilizer in soils and various crops. It has been imported into Korea and used as a base material for the fourth type compound fertilizer product. Enzymatic Hydrolysis Characteristics of Pretreatment Conditions for Prey in the Horned Hawkweed, Jeong Sik Kim, Sung Jun Kim, Kwang Yong Kim, * Richard Kim **

Analysis of Nutritional Composition and Flavor Components of Leaf Gall

Physicochemical Components and Volatile Compounds of Enteromorpha prolifera and Enteromorpha linza

The present invention aims at economically producing high-functional amino acid functional fertilizer by using seaweeds (marine coral reefs, mung bean, etc.), aquaculture farmers and fish by-products. It is an object of the present invention to provide an economical and highly efficient fertilizer production method for producing seaweed fertilizer and fish liquid fertilizer. Using coastal waste seaweeds, farmers' poultry and fish by-products to maximize salt fermentation decomposition, produce high-concentration amino acids, and make functional fertilizers.

This problem is solved as a means of solving the problem of seaweeds, which are slow to decompose into seaweeds and amino acids, so that the addition of animal amino acid fish powder accelerates the decomposition and does not pyrolysis extraction, Respectively.

The liquid fertilizer produced according to the present invention is effective for the supply of crops by supplying the essential amino acid of the crop growth by absorbing directly to the plant with the side fertilization, Seaweed extracts have biological growth hormones that are found in various data, promote the growth of crops with natural hormones. And, considering the high functionality, minerals can be added to make more functional fertilizer. This fertilizer has better quality improvement effect than the case of using, improves storability, improves color and increases sugar content. In particular, fish amino acids are known to give an effective result in sugar content. Therefore, if an algae is fermented using an animal amino acid and utilized as an organic liquid fertilizer, it will be able to be economically utilized efficiently by using algae as a pollutant source and fishes as a farm waste, as well as growth of plants.

The method for producing a fertilizer composition containing seaweed waste seaweed and a fish farmer or a fish amino acid according to the present invention not only provides organic and inorganic nutrients to seaweeds and fishes but also reduces the occurrence of soil-borne diseases caused by each functional material, Improvement of nutrient holding ability, sugar content, improvement of color quality, application of functional liquid fertilizer to high-income crops has the effect of reducing product quality, production cost, and content of functional ingredients. This not only significantly reduces the input energy associated with the production of high-income crops, but also increases the quality and yield of crops, contributing significantly to the increase in income of farmers, and the advantage of supplying safe agricultural products to consumers

See also representative manufacturing process
A: Collection of waste algae. Dry milling step
B: Sales of Jeju Suhwa
C: Crushed waste seaweeds hydrolyze and remove chitin and contaminants from seaweed epidermis
D: Additional steps for salt-fermentation
E: Salting-out fermentation step
F: Enzymatic and microbial addition steps
G: filter using immersion method and filter using filter plus
H: Carbonate minerals (calcite CaCO3, kaolin CaMg (CO3) 2) or nephrite using one or more of these additional treatment steps for desalination.
I: Deposition step through desalting process
J: Deodorization and deodorization through the acetic acid fermentation step To facilitate storage.
K: Add minerals or enzymes for application-specific functionality.
(Embodiment 1) Referring to FIG.
Under the condition of the present invention, the decomposition amount and the rate of seaweed degradation according to the content of fish meal were investigated in fermentation digestion. Under the above conditions, it is effective when the content of fish meal in the solid content is 30% or more. It can be seen that the fermentation decomposition rate is increased. The optimum point for using seaweed as the maximum amount is around 30%.
Fig. 1 shows the decomposition amount of seaweeds according to the addition amount of fish powder

See also the representative.

A: Collection of waste algae. The dry milling step and possible drying thereof at the time of collection are comminuted to 5 cm or less.

B: Sales of abandoned fish meal in Jeju

C: Crushed waste seaweeds are hydrolyzed by immersing them in a solution of sodium hydroxide (NaOH) or potassium hydroxide (KOH) (5%) for 3 hours or more. Chitin and contaminant removal steps of seaweed epidermis

D: Add salt salinity (5 ~ 10%) to salted salty water or fresh salted salty sea salt for salting fermentation.

E: Seaweed fermentation tank with a ratio of 100:20 to 50% abalone: abandoned salt fermentation. Aqueous solution: 10: 3 to 5% solids for decomposition, aeration process. Keep the temperature at 28 ~ 30 ℃.

F: Enzymatic agent and microorganism addition step Microorganism is a microorganism which is selected from the group consisting of Bacillus cereus, Bacillus subtilis, Streptococcus genus, Enterococcus genus, Bifidobacterium genus, Pediococcus genus, Lactococcus genus, Bacillus genus, and Saccharomyces spp., And hoejung actinomycetes are selected and inoculated. The enzymes were hydrolyzed by the addition of α-Amylase, β-Amylase, β-Glucanase, Xylanase, Pectinase, Bacterial Protease, Pancreatin and Hemicellulase. Add 2% of molasses or other sugar.

G: Filter using immersion filter and filter plus

H: Carbonate minerals (calcite CaCO3 high-CaMg (CO3) 2) or nephrite using desalination treatment steps. Since the concentration of NaCl is high in the case of fertilizer, the growth disorder of the plant due to the osmotic phenomenon and Na are substituted with Ca and Mg in the soil to break the joint structure of the soil, resulting in a discrete structure, Supply

   As it becomes difficult, it hinders the growth of crops, so it reduces the salinity to 3% or less

I: desalination process

J: Through the fermentation of acetic acid, it is easy to remove odor and maintain storage property, and it is necessary to concentrate only for sale.

K: Minerals or enzymes are added for functional use.

Accordingly, the liquid fertilizer made from seaweed waste seaweeds, dried fishes and fish amino acids of fish farms is useful for activating microorganisms useful for nutrients and soil required by plants and promoting root growth, And enzymes and so on, it is excellent for maintaining sugar content and color.

Claims (4)

According to the present invention, seaweeds, fish powder or fish amino acids are subjected to a salting-fermentation decomposition process and a solid content (hereinafter, also referred to as " (5 ~ 10%), aeration, 28 ~ 30 ℃ temperature, 10: 3 ~ 5% for the salt fermentation decomposition. . [Claim 2] The microorganism according to claim 1, wherein the microorganism is a microorganism selected from the group consisting of Bacillus cereus, Bacillus subtilis, Streptococcus genus, Enterococcus genus, Bifidobacterium genus, Pediococcus genus, Lactococcus genus, Bacillus genus, And Saccharomyces spp., And hoejung actinomycetes are selected and inoculated. The enzymes were hydrolyzed by the addition of α-Amylase, β-Amylase, β-Glucanase, Xylanase, Pectinase, Bacterial Protease, Pancreatin and Hemicellulase. Add 2% molasses or other sugar. Process according to claim 1, comprising a step of desalting using a carbonate mineral (calcite CaCO3 high-CaMg (CO3) 2) or nephrite. In accordance with claim 1, the waste seaweed pulverized according to the present invention is hydrolyzed by immersion for 3 hours or more in an aqueous solution (5%) of sodium hydroxide (NaOH) or potassium hydroxide (KOH) And a step of removing chitin and contaminants from seaweed epidermis.

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