CN106146115A - A kind of biological soil amendment utilizing oyster shell to extract marine organisms calcium ion and preparation technology thereof - Google Patents

A kind of biological soil amendment utilizing oyster shell to extract marine organisms calcium ion and preparation technology thereof Download PDF

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Publication number
CN106146115A
CN106146115A CN201510143904.4A CN201510143904A CN106146115A CN 106146115 A CN106146115 A CN 106146115A CN 201510143904 A CN201510143904 A CN 201510143904A CN 106146115 A CN106146115 A CN 106146115A
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oyster shell
fertilizer
shell
calcium ion
soil amendment
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CN201510143904.4A
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马振宇
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Abstract

The invention discloses a kind of biological soil amendment utilizing oyster shell to extract marine organisms calcium ion and preparation technology thereof, being made up of oyster shell 6-8 part, the fertile 6-8 part of fermentation fish meal, anti-continuous cropping microbial inoculum 1-2 part, bentonite 1-4 part, azophoska 3-4 part, middle trace element fertilizer 0.1-0.5 part, shell calcium ion 1-4 part, chitin 1-4 part, shitosan 1-4 part, preparation method includes moise-heat sterilization, drying, pulverizing, grinding, screening, mixing, granulation, the step such as filling;It is an advantage of the current invention that: the biological soil amendment being obtained by the method can make the nutrition of oyster shell fully be discharged, it is applicable to plantation, soil remediation, poultry cultivation and aquaculture cultivation, reach to mend the purpose of shell ionization calcium, crops easily absorb, fertilizer efficiency is high, increases effect obvious, additionally it is possible to play diseases prevention bactericidal effect, meanwhile, improve economic benefit.

Description

A kind of biological soil utilizing oyster shell to extract marine organisms calcium ion conditioning Agent and preparation technology thereof
Technical field
The present invention relates to the preparation technology of a kind of marine organism calcium, specifically one utilizes oyster Shell extracts biological soil amendment and the preparation technology thereof of marine organisms calcium ion, it is adaptable to cultivation Industry, soil remediation function, reach to mend the purpose of shell ionization calcium, belong to fertilizer preparation field.
Background technology
Oyster, has another name called oyster, and another name oyster is yellow, oyster.Lamellibranchiata is belonged in animal classification, Ostreidae, Latin Ostrea.Oyster belongs to shellfish, in the world in respect of kind more than 100, China There are about kind more than 20 along marine products, propagated artificially mainly have Crassostrea rivularis, long oyster, Pleat oyster and Pacific oyster etc..That consumes shell is mainly composed of calcium carbonate, accounts for 90%, carbonic acid Calcium is that calcium substance composition in growth course in enriching seawater for the raw oyster is formed, and is different from lime The mineral calciums such as stone, it has biologically active, it is easy to absorbed.And wherein rich in carbonic acid Calcium, is many common germs, including salmonella, tinea pedis germ, colibacillary Jinx.But, the remaining oyster shell after edible oyster is often dropped, and discarded oyster shell is not only tight Heavily have impact on environment, and cause the waste of resource.At present, some Feed Enterprise domestic are also Just it is directly pulverized in addition feed as additive, also preferably do not process the side of shell Method.Entitled " marine organism calcium Multi-element fertilizer " Application No. " 201110128368.2 " Chinese invention patent disclose oyster shell powder and oyster shell whiting are carried out microorganism species fermentation make The method of standby fertilizer, but, the method is excessively simple for the process of shell, causes nutrition not Can fully discharge, crop is difficult to absorb, and fertilizer efficiency is relatively low.
Content of the invention
In order to solve the problems referred to above, the present invention devises one and utilizes oyster shell to extract marine organism calcium The biological soil amendment of ion and preparation technology thereof, the bio-feritlizer energy being obtained by the method The nutrition enough making oyster shell is fully discharged, it is adaptable to plantation, soil remediation, poultry cultivation and Aquaculture cultivates, and reaches to mend the purpose of shell ionization calcium, and crops easily absorb, and fertilizer efficiency is high, Increase effect obvious, additionally it is possible to play diseases prevention bactericidal effect, meanwhile, improve economic benefit.
The technical scheme is that
A kind of biological soil amendment utilizing oyster shell to extract marine organisms calcium ion, by following heavy The raw material of amount part is prepared from:
Oyster shell 6-8 part, the fertile 6-8 part of fermentation fish meal, anti-continuous cropping microbial inoculum 1-2 part, bentonite 1-4 part, azophoska 3-4 part, middle trace element fertilizer 0.1-0.5 part, shell calcium ion 1-4 Part, chitin 1-4 part, shitosan 1-4 part.
Wherein, described fermentation fish meal fertilizer be will be enriched in organic matter thick fish meal, peat, pomace, Any one or arbitrary composition of this potato slag and fowl and animal excrement adds beneficial microbe colony to carry out Fermentation so that it is change into and be easy to, rich in humic acid, amino acid crop, the material that directly absorbs, i.e. Obtain fermentation fish meal fertile.Described shell calcium ion, chitin, shitosan are from oyster shell Extraction obtains, and wherein shell calcium ion is alkali ion calcium, due to movement, the high suction of calcium ion Receipts power, high calcium functional, by increasing capacitance it is possible to increase soil remediation function, make heavy metal decompose and remove, carry High productivity and soil productivity.
In addition, described azophoska is the common fertilizer sold on market;Described middle trace unit The fertile middle trace element fertilizer for the boron zinc of sulphur containing magnesium and iron of element, all there is sale in market.
A kind of above-mentioned preparation technology utilizing oyster shell to extract marine organisms calcium ion bio-fertilizer, specifically Comprise the following steps:
Moise-heat sterilization-drying-pulverizing-grinding-screening-mixing-granulation-filling.
Bio-fertilizer of the present invention has the advantage that hard soil and mineral matter in assimilation soil; Excellent nutriment is provided and promotes the breeding of edaphon;New talent germinates, seedling in seedling stage Strong;Crops root of hair is fast, it is strong to absorb nutrient ability;Decompose and be excessively used chemical fertilizer mineral matter And the fertilizer damage that salt accumulation brings, make the soil being acidified be repaired, anti-rotten of dead seedling;Anti- Only fruit drop, increases fruit sweetness, increasing both production and income;Improve soil property, keep ecological environment, Reduce diseases and pests of agronomic crop, improve quality of agricultural product;Increase the water conservation fertilizer-preserving ability of soil, anti- Only soil desertification and nutrient loss;Flower crop cauline leaf is healthy and strong, bright-colored, strengthens disease-resistant energy Power;The multi-Functional Fertilizers of cultivation feature high calcium agricultural product;Balanced soil pH value, prevents ammonia The loss that gas or other pernicious gases bring to crops;Use the time of infertility crop will not be subject to disease Evil invasion and attack.
It is demonstrated experimentally that bio-fertilizer of the present invention can pulverize soil firmly firm again in soil and mineral Matter;There is provided excellent nutriment to promote the breeding of edaphon;New talent is helped to germinate; The growth helping Crop Root allows them absorb abundant nutrition simultaneously;Decompose and use because of excessive Chemical fertilizer and the mineral matter accumulated and salinity, also make the soil being acidified be repaiied Multiple, prevent other loss;Prevent fruit from shifting to an earlier date shedding, allow fruit increase income and make its sugariness increase Add;Improve soil property, keep ecological environment, make the infectious disease of crops reduce;Increase soil Moisture holding capacity, prevents soil loss;Floriculture poem cauline leaf is grown up strong and sturdy, and keeps the most natural color of flower And cultivate its vitality, solve the difficulty of plantation;Can reduce crops because ammonia or other have The loss doing harm to gas and occurring;If beginning to use when new talent, it becomes possible to become disease resistance Crop.
It is an advantage of the current invention that: the bio-feritlizer being obtained by the method can make the battalion of oyster shell Support and fully discharged, it is adaptable to plantation, soil remediation, poultry cultivation and aquaculture cultivation, Reaching to mend the purpose of shell ionization calcium, crops easily absorb, and fertilizer efficiency is high, increase effect obvious, Diseases prevention bactericidal effect can also be played, meanwhile, improve economic benefit.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that described herein Preferred embodiment is merely to illustrate and explains the present invention, is not intended to limit the present invention.
Unless otherwise stated, the percentage employed in the present invention is percetage by weight.
Experimental example
Fertilizer of the present invention is carried out field experiment, can apply to following crop, its using method With using effect such as following table:
Embodiment 1
A kind of biological soil amendment utilizing oyster shell to extract marine organisms calcium ion, by following heavy The raw material of amount part is prepared from:
Oyster shell 6-8 part, the fertile 6-8 part of fermentation fish meal, anti-continuous cropping microbial inoculum 1-2 part, bentonite 1-4 part, azophoska 3-4 part, middle trace element fertilizer 0.1-0.5 part, shell calcium ion 1-4 Part, chitin 1-4 part, shitosan 1-4 part.
Embodiment 2
A kind of above-mentioned preparation technology utilizing oyster shell to extract marine organisms calcium ion bio-fertilizer, specifically Comprise the following steps:
(1) pretreatment of raw material: after being carried out oyster shell, carries out HTHP boiling, protects Hold pressure 1.2~1.5MPa, temperature 150 DEG C~200 DEG C, boiling 2 hours;By to oyster shell Carry out HTHP boiling and not only reached the purpose of sterilization, remove harmful substance, and And make the calcium substance in oyster shell be released out;
(2) pulverizing is dried: the oyster shell that step (1) obtains is carried out dry and pulverize, be crushed to 500 mesh, obtain oyster shell powder;Therefrom extract shell calcium ion, chitin, shitosan.
(3) biofermentation: the oyster shell powder that step (2) is obtained in proportion fertile with fermentation fish meal, Anti-continuous cropping microbial inoculum, bentonite, shell calcium ion, chitin, shitosan mixing, carry out biology Fermentation, control temperature is at 50-70 DEG C, and the time is 2-3 days, makes oyster shell powder activate, by adding Add bentonite and be not only able to play the effect of absorption microbial inoculum, but also the fermentation of microbial inoculum can be improved Effect, increases fertilizer efficiency;
(4) fertilizer compounds: oyster shell powder and azophoska after step (3) is fermented and in micro- Secondary element fertilizer compounds, and obtains multicomponent fertilizer.
Described anti-continuous cropping microbial inoculum but from middle peasant shake space (Beijing) Bioisystech Co., Ltd buy Anti-continuous cropping microbial inoculum;Described azophoska is the common fertilizer sold on market;In described micro- The fertile middle trace element fertilizer for the boron zinc of sulphur containing magnesium and iron of secondary element, all there is sale in market;Described Shell calcium ion, chitin, shitosan are and conventional method can be used to extract from oyster shell Arrive, be the conventional products on market.
The fertilizer obtaining said method carries out celery experiment in cultivation, and result shows:
The cultivation of the celery incidence of disease more conventional fertilizer is low by 38%, the more conventional fertilizer of insect pest incidence Low by 13%, diseases prevention vermins-proof effect is good, and output increased 16%, output increased is obvious.
Embodiment 3
A kind of above-mentioned preparation technology utilizing oyster shell to extract marine organisms calcium ion bio-fertilizer, specifically Comprise the following steps:
(1) pretreatment of raw material: after being carried out oyster shell, carries out HTHP boiling, protects Hold pressure 1.2~1.5MPa, temperature 150 DEG C~200 DEG C, boiling 2 hours;By to oyster shell Carry out HTHP boiling and not only reached the purpose of sterilization, remove harmful substance, and And make the calcium substance in oyster shell be released out;
(2) pulverize: the oyster shell that step (1) obtains is pulverized, is crushed to 800 mesh, Obtain oyster shell powder;
(3) biofermentation: the oyster shell powder that step (2) is obtained in proportion fertile with fermentation fish meal, Anti-continuous cropping microbial inoculum, bentonite, shell calcium ion, chitin, shitosan mixing, carry out biology Fermentation, carries out biofermentation, and control temperature is at 50-70 DEG C, and the time is 2-3 days, makes oyster shell Powder activates, and is not only able to play the effect of absorption microbial inoculum by adding bentonite, but also can Improve the ferment effect of microbial inoculum, increase fertilizer efficiency;
(4) fertilizer compound: by step (3) ferment after oyster shell powder with azophoska and in Trace element fertilizer compounds, and obtains multicomponent fertilizer.
The fertilizer obtaining said method carries out celery experiment in cultivation, and result shows:
The cultivation of the celery incidence of disease more conventional fertilizer is low by 41%, the more conventional fertilizer of insect pest incidence Low by 15%, diseases prevention vermins-proof effect is good, and output increased 18%, output increased is obvious.
Embodiment 4
A kind of above-mentioned preparation technology utilizing oyster shell to extract marine organisms calcium ion bio-fertilizer, specifically Comprise the following steps:
(1) pretreatment of raw material: after being carried out oyster shell, carries out HTHP boiling, protects Hold pressure 1.2~1.5MPa, temperature 150 DEG C~200 DEG C, boiling 2 hours;By to oyster shell Carry out HTHP boiling and not only reached the purpose of sterilization, remove harmful substance, and And make the calcium substance in oyster shell be released out;
(2) pulverize: the oyster shell that step (1) obtains is pulverized, is crushed to 700 mesh, Obtain oyster shell powder;
(3) biofermentation: the oyster shell powder that step (2) is obtained proportionally with bentonite, Shell calcium ion, chitin, the mixing of chitosan biological fermenting agent, carry out biofermentation, control Temperature processed is at 50-70 DEG C, and the time is 2-3 days, makes oyster shell powder activate, by adding bentonite It is not only able to play the effect of absorption microbial inoculum, but also the ferment effect of microbial inoculum can be improved, increase Add fertilizer efficiency;
Described biofermentation microbial inoculum is composite bacteria agent;Described composite bacteria agent be Bacillus, saccharomycete, Lactic acid bacteria and the mixture of acetic acid bacteria, mixed weight ratio is 2: 3: 2: 1;
(4) fertilizer compound: by step (3) ferment after oyster shell powder with azophoska and in Trace element fertilizer compounds, and obtains multicomponent fertilizer.
The fertilizer obtaining said method carries out celery experiment in cultivation, and result shows:
The cultivation of the celery incidence of disease more conventional fertilizer is low by 44%, the more conventional fertilizer of insect pest incidence Low by 18%, diseases prevention vermins-proof effect is good, and output increased 19%, output increased is obvious.
It is demonstrated experimentally that the calcium ion in bio-fertilizer of the present invention can be pulverized in soil firmly firm again Soil and mineral matter;There is provided excellent nutriment to promote the breeding of edaphon;Help New talent germinates;The growth helping Crop Root allows them absorb abundant nutrition simultaneously;Decompose The mineral matter accumulated because of overuse of chemical fertilizer and salinity, also make the soil being acidified Earth is repaired, and prevents other loss;Prevent fruit from shifting to an earlier date shedding, allow fruit increase income and make Its sugariness increases;Improve soil property, keep ecological environment, make the infectious disease of crops reduce;Increase Add the moisture holding capacity of soil, prevent soil loss;Floriculture poem cauline leaf is grown up strong and sturdy, and keeps flower the most certainly Right color simultaneously cultivates its vitality, solves the difficulty of plantation;Crops can be reduced because of ammonia Or other pernicious gases and the loss that occurs;If beginning to use when new talent, it becomes possible to become The crop of disease resistance.

Claims (3)

1. utilizing oyster shell to extract a biological soil amendment for marine organisms calcium ion, it is special Levy and be, be prepared from by the raw material of following weight portion:
Oyster shell 6-8 part, the fertile 6-8 part of fermentation fish meal, anti-continuous cropping microbial inoculum 1-2 part, bentonite 1-4 part, azophoska 3-4 part, middle trace element fertilizer 0.1-0.5 part, shell calcium ion 1-4 Part, chitin 1-4 part, shitosan 1-4 part.
2. biological soil amendment according to claim 1, it is characterised in that: described Fermentation fish meal fertilizer is thick fish meal, peat, pomace, this potato slag and the manure of livestock and poultry that will be enriched in organic matter Just any one or arbitrary composition adds beneficial microbe colony to ferment so that it is change into It is easy to the material directly absorbing rich in humic acid, amino acid crop, i.e. obtain fermentation fish meal fertile.
3. the oyster shell that utilizes as described in claim 1-2 any one extracts marine organism calcium The preparation technology of ion biological soil amendment, it is characterised in that comprise the following steps: steam Sterilization-dry-pulverize-grind-screening-mixing-granulation-filling.
CN201510143904.4A 2015-03-31 2015-03-31 A kind of biological soil amendment utilizing oyster shell to extract marine organisms calcium ion and preparation technology thereof Pending CN106146115A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107814657A (en) * 2017-11-09 2018-03-20 福建省恒祥渔业有限公司 A kind of soil conditioner of oyster shell combination fish ferment and preparation method thereof
CN110367023A (en) * 2019-08-19 2019-10-25 大连地拓环境科技有限公司 A method of promoting plant lignifying of sowing grass seeds by duster
CN110476969A (en) * 2019-08-29 2019-11-22 段青文 Accelerate the composition and its preparation method and application of degradation of pesticide
CN110663436A (en) * 2019-10-25 2020-01-10 晴隆心间茶业农业有限公司 Yellow tea planting method rich in minerals
CN112919990A (en) * 2021-02-02 2021-06-08 甘肃省敦煌种业集团股份有限公司研究院 Seed corn field continuous cropping obstacle repairing agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102070369A (en) * 2010-11-25 2011-05-25 大连丹丰有机肥制造有限公司 Marine bioactive environment-friendly fertilizer and preparation method thereof
CN102153393A (en) * 2011-05-06 2011-08-17 陈景河 Multielement fertilizer with marine organism calcium
CN103553815A (en) * 2013-11-08 2014-02-05 苏州仁成生物科技有限公司 Multielement microbial fertilizer and preparation method thereof
CN104230600A (en) * 2014-09-13 2014-12-24 青岛瀚普生物科技有限公司 Saline-alkali soil conditioner and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102070369A (en) * 2010-11-25 2011-05-25 大连丹丰有机肥制造有限公司 Marine bioactive environment-friendly fertilizer and preparation method thereof
CN102153393A (en) * 2011-05-06 2011-08-17 陈景河 Multielement fertilizer with marine organism calcium
CN103553815A (en) * 2013-11-08 2014-02-05 苏州仁成生物科技有限公司 Multielement microbial fertilizer and preparation method thereof
CN104230600A (en) * 2014-09-13 2014-12-24 青岛瀚普生物科技有限公司 Saline-alkali soil conditioner and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107814657A (en) * 2017-11-09 2018-03-20 福建省恒祥渔业有限公司 A kind of soil conditioner of oyster shell combination fish ferment and preparation method thereof
CN110367023A (en) * 2019-08-19 2019-10-25 大连地拓环境科技有限公司 A method of promoting plant lignifying of sowing grass seeds by duster
CN110367023B (en) * 2019-08-19 2021-06-15 大连地拓环境科技有限公司 Method for promoting lignification of spray-sowed plants
CN110476969A (en) * 2019-08-29 2019-11-22 段青文 Accelerate the composition and its preparation method and application of degradation of pesticide
CN110663436A (en) * 2019-10-25 2020-01-10 晴隆心间茶业农业有限公司 Yellow tea planting method rich in minerals
CN112919990A (en) * 2021-02-02 2021-06-08 甘肃省敦煌种业集团股份有限公司研究院 Seed corn field continuous cropping obstacle repairing agent and preparation method thereof

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Application publication date: 20161123

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