KR20170031157A - 디페닐메탄 시리즈의 디아민 및 폴리아민의 제조 방법 - Google Patents
디페닐메탄 시리즈의 디아민 및 폴리아민의 제조 방법 Download PDFInfo
- Publication number
- KR20170031157A KR20170031157A KR1020177002943A KR20177002943A KR20170031157A KR 20170031157 A KR20170031157 A KR 20170031157A KR 1020177002943 A KR1020177002943 A KR 1020177002943A KR 20177002943 A KR20177002943 A KR 20177002943A KR 20170031157 A KR20170031157 A KR 20170031157A
- Authority
- KR
- South Korea
- Prior art keywords
- zeolite
- acid
- alkali
- treatment
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 58
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- 238000004519 manufacturing process Methods 0.000 title abstract description 14
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 105
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 102
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
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- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/54—Preparation of compounds containing amino groups bound to a carbon skeleton by rearrangement reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
- C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/06—Amines
- C08G12/08—Amines aromatic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14175927 | 2014-07-07 | ||
| EP14175927.4 | 2014-07-07 | ||
| PCT/EP2015/065124 WO2016005269A1 (en) | 2014-07-07 | 2015-07-02 | Process for the production of di- and polyamines of the diphenylmethane series |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20170031157A true KR20170031157A (ko) | 2017-03-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020177002943A Withdrawn KR20170031157A (ko) | 2014-07-07 | 2015-07-02 | 디페닐메탄 시리즈의 디아민 및 폴리아민의 제조 방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10239984B2 (enExample) |
| EP (1) | EP3166922B1 (enExample) |
| JP (1) | JP2017523159A (enExample) |
| KR (1) | KR20170031157A (enExample) |
| CN (1) | CN106660938B (enExample) |
| HU (1) | HUE037918T2 (enExample) |
| PT (1) | PT3166922T (enExample) |
| WO (1) | WO2016005269A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10538480B2 (en) | 2016-06-30 | 2020-01-21 | Covestro Deutschland Ag | Process for the production of di- and polyamines of the diphenylmethane series |
| CN107814722A (zh) * | 2017-11-17 | 2018-03-20 | 上海毕得医药科技有限公司 | 一种2‑(4‑氨基苄基)苯胺的合成方法 |
| FR3075662B1 (fr) * | 2017-12-21 | 2022-06-24 | Ifp Energies Now | Procede de pretraitement pour ameliorer le remplissage d'une enceinte avec des particules solides |
| KR102267465B1 (ko) * | 2019-08-14 | 2021-06-22 | 고려대학교 산학협력단 | 단순 소성을 통한 나노판형 제올라이트의 제조방법과 이로부터 제조된 나노판형 제올라이트 입자 |
| US20230028994A1 (en) | 2019-12-13 | 2023-01-26 | Basf Se | Heterogeneous synthesis of methylene dianiline |
| WO2025238210A1 (en) | 2024-05-17 | 2025-11-20 | Basf Se | Additive concepts for methylenedianiline synthesis |
| WO2025238207A1 (en) | 2024-05-17 | 2025-11-20 | Basf Se | Catalyst concept for heterogeneous synthesis of methylenedianiline |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4243828A (en) * | 1963-02-27 | 1981-01-06 | Mobil Oil Corporation | Alkylation of aromatics using a high silica zeolite |
| US3362979A (en) | 1964-01-02 | 1968-01-09 | Jefferson Chem Co Inc | Mixtures of methylene-bridged polyphenyl polyisocyanates |
| US3860637A (en) | 1971-01-26 | 1975-01-14 | Jefferson Chem Co Inc | Selective manufacture of 4,4{40 -isomer of diaminodiphenyl-methane |
| US3971829A (en) | 1974-11-18 | 1976-07-27 | Jefferson Chemical Company, Inc. | Preparation of methylene-bridged polyphenylpolyamine mixtures |
| US4039581A (en) | 1975-06-27 | 1977-08-02 | The Upjohn Company | Process for the preparation of di(amino phenyl)methanes |
| US4039580A (en) | 1975-07-24 | 1977-08-02 | The Upjohn Company | Process for preparing di(aminophenyl)methanes |
| US4294987A (en) | 1979-12-31 | 1981-10-13 | The Upjohn Company | Process for preparing methylene dianilines |
| DE3783199T2 (de) | 1986-10-22 | 1993-04-29 | Enichem Sintesi | Verfahren zur herstellung von 4,4' diaminodiphenylmethan und derivaten davon. |
| JPH01207259A (ja) * | 1988-02-15 | 1989-08-21 | Mitsui Petrochem Ind Ltd | ４，４′−メチレンジアニリンの製造方法 |
| AU612786B2 (en) | 1988-02-15 | 1991-07-18 | Mitsui Petrochemical Industries, Ltd. | Method of preparing 4,4'-methylenedianiline |
| IT1312331B1 (it) | 1999-05-27 | 2002-04-15 | Enichem Spa | Procedimento per la produzione di diamminodifenilmetano e suoiomologhi superiori. |
| IT1313626B1 (it) | 1999-09-24 | 2002-09-09 | Eni Spa | Procedimento per la produzione di metilendianilina (mda) e suoiomologhi superiori |
| DE10006452A1 (de) | 2000-02-14 | 2001-08-16 | Bayer Ag | Verfahren zur Herstellung von Diaminodiphenylmethanen |
| IT1318591B1 (it) | 2000-06-22 | 2003-08-27 | Eni Spa | Procedimento per la rigenerazione di catalizzatori zeolitici. |
| IT1318686B1 (it) | 2000-09-07 | 2003-08-27 | Eni Spa | Procedimento per la sintesi di miscele di metilendianilina e suoiomologhi superiori con distribuzione controllata degli isomeri. |
| ITMI20010880A1 (it) | 2001-04-27 | 2002-10-27 | Enitecnologie Spa | Procedimento per la produzione di metilendianilina mediante catalizzatori zeolitici modificati |
| CA2478501C (en) | 2002-03-28 | 2011-05-03 | Huntsman International Llc | Process for the production of diaminodiphenylmethane and its higher homologues |
| JP4887493B2 (ja) * | 2006-06-15 | 2012-02-29 | 国立大学法人埼玉大学 | 疎水性ゼオライトの製造方法 |
| CN101259419B (zh) | 2008-04-09 | 2010-06-23 | 哈尔滨六环石油化工技术开发公司 | 一种固体酸催化剂的制备方法 |
| WO2010019844A1 (en) | 2008-08-14 | 2010-02-18 | Dow Global Technologies Inc. | Production of mixtures of methylenedianiline and its higher homologues using calcined metal oxide-silica catalysts |
| PT2379486E (pt) | 2008-12-22 | 2013-10-17 | Huntsman Int Llc | Processo para a produção de polifenilpoliaminas com pontes de metileno |
| CZ2009421A3 (cs) | 2009-07-01 | 2010-08-18 | Vysoká škola chemicko-technologická v Praze | Zpusob výroby 4,4´-methylendianilinu |
| JP2012131720A (ja) | 2010-12-20 | 2012-07-12 | Tosoh Corp | メチレンジアニリン誘導体の製造法 |
| JP2012250971A (ja) | 2011-05-12 | 2012-12-20 | Tosoh Corp | 芳香族ポリアミンの製造方法 |
| JP2013095724A (ja) * | 2011-11-02 | 2013-05-20 | Tosoh Corp | 芳香族ポリアミンの製造方法 |
-
2015
- 2015-07-02 KR KR1020177002943A patent/KR20170031157A/ko not_active Withdrawn
- 2015-07-02 HU HUE15732006A patent/HUE037918T2/hu unknown
- 2015-07-02 WO PCT/EP2015/065124 patent/WO2016005269A1/en not_active Ceased
- 2015-07-02 JP JP2017500831A patent/JP2017523159A/ja active Pending
- 2015-07-02 EP EP15732006.0A patent/EP3166922B1/en not_active Not-in-force
- 2015-07-02 PT PT157320060T patent/PT3166922T/pt unknown
- 2015-07-02 US US15/323,999 patent/US10239984B2/en active Active
- 2015-07-02 CN CN201580036983.7A patent/CN106660938B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP3166922A1 (en) | 2017-05-17 |
| WO2016005269A1 (en) | 2016-01-14 |
| US10239984B2 (en) | 2019-03-26 |
| JP2017523159A (ja) | 2017-08-17 |
| US20170158798A1 (en) | 2017-06-08 |
| HUE037918T2 (hu) | 2018-09-28 |
| CN106660938A (zh) | 2017-05-10 |
| CN106660938B (zh) | 2019-03-12 |
| EP3166922B1 (en) | 2018-03-14 |
| PT3166922T (pt) | 2018-06-15 |
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