JP2017523159A - ジフェニルメタンシリーズのジアミンおよびポリアミンの製造方法 - Google Patents

ジフェニルメタンシリーズのジアミンおよびポリアミンの製造方法 Download PDF

Info

Publication number
JP2017523159A
JP2017523159A JP2017500831A JP2017500831A JP2017523159A JP 2017523159 A JP2017523159 A JP 2017523159A JP 2017500831 A JP2017500831 A JP 2017500831A JP 2017500831 A JP2017500831 A JP 2017500831A JP 2017523159 A JP2017523159 A JP 2017523159A
Authority
JP
Japan
Prior art keywords
zeolite
acid
treatment
alkali
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2017500831A
Other languages
English (en)
Japanese (ja)
Other versions
JP2017523159A5 (enExample
Inventor
ユルゲン、アラス
シュテファン、ベルスホーフェン
ハビエル、ペレス−ラミレス
トビアス、シーザー、ケラー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Covestro Deutschland AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Covestro Deutschland AG filed Critical Covestro Deutschland AG
Publication of JP2017523159A publication Critical patent/JP2017523159A/ja
Publication of JP2017523159A5 publication Critical patent/JP2017523159A5/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/54—Preparation of compounds containing amino groups bound to a carbon skeleton by rearrangement reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/06—Amines
    • C08G12/08—Amines aromatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
JP2017500831A 2014-07-07 2015-07-02 ジフェニルメタンシリーズのジアミンおよびポリアミンの製造方法 Pending JP2017523159A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14175927 2014-07-07
EP14175927.4 2014-07-07
PCT/EP2015/065124 WO2016005269A1 (en) 2014-07-07 2015-07-02 Process for the production of di- and polyamines of the diphenylmethane series

Publications (2)

Publication Number Publication Date
JP2017523159A true JP2017523159A (ja) 2017-08-17
JP2017523159A5 JP2017523159A5 (enExample) 2018-08-09

Family

ID=51062723

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2017500831A Pending JP2017523159A (ja) 2014-07-07 2015-07-02 ジフェニルメタンシリーズのジアミンおよびポリアミンの製造方法

Country Status (8)

Country Link
US (1) US10239984B2 (enExample)
EP (1) EP3166922B1 (enExample)
JP (1) JP2017523159A (enExample)
KR (1) KR20170031157A (enExample)
CN (1) CN106660938B (enExample)
HU (1) HUE037918T2 (enExample)
PT (1) PT3166922T (enExample)
WO (1) WO2016005269A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021031383A (ja) * 2019-08-14 2021-03-01 コリア ユニバーシティ リサーチ アンド ビジネス ファウンデーションＫｏｒｅａ Ｕｎｉｖｅｒｓｉｔｙ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｂｕｓｉｎｅｓｓ Ｆｏｕｎｄａｔｉｏｎ 単純焼成を用いたナノ板状ゼオライトの製造方法及びこれによって製造されたナノ板状ゼオライト粒子

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10538480B2 (en) 2016-06-30 2020-01-21 Covestro Deutschland Ag Process for the production of di- and polyamines of the diphenylmethane series
CN107814722A (zh) * 2017-11-17 2018-03-20 上海毕得医药科技有限公司 一种2‑(4‑氨基苄基)苯胺的合成方法
FR3075662B1 (fr) * 2017-12-21 2022-06-24 Ifp Energies Now Procede de pretraitement pour ameliorer le remplissage d'une enceinte avec des particules solides
EP4072726A1 (en) 2019-12-13 2022-10-19 Basf Se Heterogeneous synthesis of methylene dianiline
WO2025238210A1 (en) 2024-05-17 2025-11-20 Basf Se Additive concepts for methylenedianiline synthesis
WO2025238207A1 (en) 2024-05-17 2025-11-20 Basf Se Catalyst concept for heterogeneous synthesis of methylenedianiline

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243828A (en) * 1963-02-27 1981-01-06 Mobil Oil Corporation Alkylation of aromatics using a high silica zeolite
JPH01207259A (ja) * 1988-02-15 1989-08-21 Mitsui Petrochem Ind Ltd ４，４′−メチレンジアニリンの製造方法
JP2007331982A (ja) * 2006-06-15 2007-12-27 Saitama Univ 疎水性ゼオライトの製造方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3362979A (en) 1964-01-02 1968-01-09 Jefferson Chem Co Inc Mixtures of methylene-bridged polyphenyl polyisocyanates
US3860637A (en) 1971-01-26 1975-01-14 Jefferson Chem Co Inc Selective manufacture of 4,4{40 -isomer of diaminodiphenyl-methane
US3971829A (en) 1974-11-18 1976-07-27 Jefferson Chemical Company, Inc. Preparation of methylene-bridged polyphenylpolyamine mixtures
US4039581A (en) 1975-06-27 1977-08-02 The Upjohn Company Process for the preparation of di(amino phenyl)methanes
US4039580A (en) 1975-07-24 1977-08-02 The Upjohn Company Process for preparing di(aminophenyl)methanes
US4294987A (en) 1979-12-31 1981-10-13 The Upjohn Company Process for preparing methylene dianilines
DE3783199T2 (de) 1986-10-22 1993-04-29 Enichem Sintesi Verfahren zur herstellung von 4,4' diaminodiphenylmethan und derivaten davon.
AU612786B2 (en) 1988-02-15 1991-07-18 Mitsui Petrochemical Industries, Ltd. Method of preparing 4,4'-methylenedianiline
IT1312331B1 (it) 1999-05-27 2002-04-15 Enichem Spa Procedimento per la produzione di diamminodifenilmetano e suoiomologhi superiori.
IT1313626B1 (it) 1999-09-24 2002-09-09 Eni Spa Procedimento per la produzione di metilendianilina (mda) e suoiomologhi superiori
DE10006452A1 (de) 2000-02-14 2001-08-16 Bayer Ag Verfahren zur Herstellung von Diaminodiphenylmethanen
IT1318591B1 (it) 2000-06-22 2003-08-27 Eni Spa Procedimento per la rigenerazione di catalizzatori zeolitici.
IT1318686B1 (it) 2000-09-07 2003-08-27 Eni Spa Procedimento per la sintesi di miscele di metilendianilina e suoiomologhi superiori con distribuzione controllata degli isomeri.
ITMI20010880A1 (it) 2001-04-27 2002-10-27 Enitecnologie Spa Procedimento per la produzione di metilendianilina mediante catalizzatori zeolitici modificati
WO2003082803A1 (en) 2002-03-28 2003-10-09 Huntsman International Llc Process for the production of diaminodiphenylmethane and its higher homologues
CN101259419B (zh) * 2008-04-09 2010-06-23 哈尔滨六环石油化工技术开发公司 一种固体酸催化剂的制备方法
WO2010019844A1 (en) 2008-08-14 2010-02-18 Dow Global Technologies Inc. Production of mixtures of methylenedianiline and its higher homologues using calcined metal oxide-silica catalysts
EP2379486B1 (en) 2008-12-22 2013-10-09 Huntsman International LLC Process for production of methylene-bridged polyphenyl polyamines
CZ301977B6 (cs) 2009-07-01 2010-08-18 Vysoká škola chemicko-technologická v Praze Zpusob výroby 4,4´-methylendianilinu
JP2012131720A (ja) * 2010-12-20 2012-07-12 Tosoh Corp メチレンジアニリン誘導体の製造法
JP2012250971A (ja) * 2011-05-12 2012-12-20 Tosoh Corp 芳香族ポリアミンの製造方法
JP2013095724A (ja) * 2011-11-02 2013-05-20 Tosoh Corp 芳香族ポリアミンの製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243828A (en) * 1963-02-27 1981-01-06 Mobil Oil Corporation Alkylation of aromatics using a high silica zeolite
JPH01207259A (ja) * 1988-02-15 1989-08-21 Mitsui Petrochem Ind Ltd ４，４′−メチレンジアニリンの製造方法
JP2007331982A (ja) * 2006-06-15 2007-12-27 Saitama Univ 疎水性ゼオライトの製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021031383A (ja) * 2019-08-14 2021-03-01 コリア ユニバーシティ リサーチ アンド ビジネス ファウンデーションＫｏｒｅａ Ｕｎｉｖｅｒｓｉｔｙ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｂｕｓｉｎｅｓｓ Ｆｏｕｎｄａｔｉｏｎ 単純焼成を用いたナノ板状ゼオライトの製造方法及びこれによって製造されたナノ板状ゼオライト粒子

Also Published As

Publication number Publication date
US10239984B2 (en) 2019-03-26
US20170158798A1 (en) 2017-06-08
EP3166922A1 (en) 2017-05-17
CN106660938A (zh) 2017-05-10
WO2016005269A1 (en) 2016-01-14
PT3166922T (pt) 2018-06-15
KR20170031157A (ko) 2017-03-20
CN106660938B (zh) 2019-03-12
EP3166922B1 (en) 2018-03-14
HUE037918T2 (hu) 2018-09-28

Similar Documents

Publication Publication Date Title
JP2017523159A (ja) ジフェニルメタンシリーズのジアミンおよびポリアミンの製造方法
RU2607633C2 (ru) Формованный катализатор для превращения метанола в ароматические углеводороды и способ получения указанного катализатора
KR100958149B1 (ko) Ｕｚｍ-8 및 ｕｚｍ-8ｈｓ 결정질 알루미노실리케이트제올라이트 조성물 및 이 조성물을 이용하는 방법
KR101615462B1 (ko) 탄화수소 전환을 위한 촉매 및 방법
CN103889572B (zh) 用于制备介孔化催化剂的方法、由此获得的催化剂及其在催化工艺中的用途
US8779205B2 (en) Method for pre-treating hydroamination catalysts
JP5525545B2 (ja) メチレン架橋ポリフェニルポリアミンの製造方法
KR100385779B1 (ko) 디아미노디페닐메탄 및 그것의 고급 동족체의 제조 방법
Botella et al. Towards an industrial synthesis of diamino diphenyl methane (DADPM) using novel delaminated materials: A breakthrough step in the production of isocyanates for polyurethanes
WO2009062742A2 (en) Porous solid acid catalysts, methods of manufacturing the same, and methods of manufacturing organics molecules using the same
JP4890727B2 (ja) 制御された異性体分布をもったメタンジフェニルジアミンとその高級同族体の混合物の合成方法
EP1294481B1 (en) Process for the regeneration of solid acid catalysts
CN107556200B (zh) 制备二苯基甲烷系列的二胺和多胺的方法
JP6451311B2 (ja) ピペラジン及びトリエチレンジアミンの製造方法
KR100874120B1 (ko) 이성체 분포가 조절된, 메탄 디페닐 디아민과 이의 고급 동족체의 혼합물의 합성방법
JP2004532232A5 (enExample)
US20050101801A1 (en) Process for the production of diaminodiphenylmethane and its higher homologues
JP2008508345A (ja) 芳香族炭化水素とアルカンとの直接アルキル化によるアルキル芳香族化合物の製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180629

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20180629

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20190618

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20190918

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20200204