CN106660938B - 生产二苯基甲烷系列的二胺和多胺的方法 - Google Patents

生产二苯基甲烷系列的二胺和多胺的方法 Download PDF

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Publication number
CN106660938B
CN106660938B CN201580036983.7A CN201580036983A CN106660938B CN 106660938 B CN106660938 B CN 106660938B CN 201580036983 A CN201580036983 A CN 201580036983A CN 106660938 B CN106660938 B CN 106660938B
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zeolite
acid
alkali
mda
catalyst
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CN106660938A (zh
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J.阿拉斯
S.韦尔绍芬
J.佩雷斯-拉米雷斯
T.C.凯勒
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Covestro Deutschland AG
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/54—Preparation of compounds containing amino groups bound to a carbon skeleton by rearrangement reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/06—Amines
    • C08G12/08—Amines aromatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201580036983.7A 2014-07-07 2015-07-02 生产二苯基甲烷系列的二胺和多胺的方法 Expired - Fee Related CN106660938B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14175927 2014-07-07
EP14175927.4 2014-07-07
PCT/EP2015/065124 WO2016005269A1 (en) 2014-07-07 2015-07-02 Process for the production of di- and polyamines of the diphenylmethane series

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CN106660938A CN106660938A (zh) 2017-05-10
CN106660938B true CN106660938B (zh) 2019-03-12

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US (1) US10239984B2 (enExample)
EP (1) EP3166922B1 (enExample)
JP (1) JP2017523159A (enExample)
KR (1) KR20170031157A (enExample)
CN (1) CN106660938B (enExample)
HU (1) HUE037918T2 (enExample)
PT (1) PT3166922T (enExample)
WO (1) WO2016005269A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10538480B2 (en) 2016-06-30 2020-01-21 Covestro Deutschland Ag Process for the production of di- and polyamines of the diphenylmethane series
CN107814722A (zh) * 2017-11-17 2018-03-20 上海毕得医药科技有限公司 一种2‑(4‑氨基苄基)苯胺的合成方法
FR3075662B1 (fr) * 2017-12-21 2022-06-24 Ifp Energies Now Procede de pretraitement pour ameliorer le remplissage d'une enceinte avec des particules solides
KR102267465B1 (ko) * 2019-08-14 2021-06-22 고려대학교 산학협력단 단순 소성을 통한 나노판형 제올라이트의 제조방법과 이로부터 제조된 나노판형 제올라이트 입자
US20230028994A1 (en) 2019-12-13 2023-01-26 Basf Se Heterogeneous synthesis of methylene dianiline
WO2025238210A1 (en) 2024-05-17 2025-11-20 Basf Se Additive concepts for methylenedianiline synthesis
WO2025238207A1 (en) 2024-05-17 2025-11-20 Basf Se Catalyst concept for heterogeneous synthesis of methylenedianiline

Citations (6)

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EP0329367A2 (en) * 1988-02-15 1989-08-23 Mitsui Petrochemical Industries, Ltd. Method of preparing 4,4'-methylenedianiline
CN101259419A (zh) * 2008-04-09 2008-09-10 哈尔滨六环石油化工技术开发公司 一种固体酸催化剂的制备方法
CN102256931A (zh) * 2008-12-22 2011-11-23 亨茨曼国际有限公司 生产亚甲基-桥联多苯基多胺的方法
JP2012131720A (ja) * 2010-12-20 2012-07-12 Tosoh Corp メチレンジアニリン誘導体の製造法
JP2012250971A (ja) * 2011-05-12 2012-12-20 Tosoh Corp 芳香族ポリアミンの製造方法
JP2013095724A (ja) * 2011-11-02 2013-05-20 Tosoh Corp 芳香族ポリアミンの製造方法

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US3860637A (en) 1971-01-26 1975-01-14 Jefferson Chem Co Inc Selective manufacture of 4,4{40 -isomer of diaminodiphenyl-methane
US3971829A (en) 1974-11-18 1976-07-27 Jefferson Chemical Company, Inc. Preparation of methylene-bridged polyphenylpolyamine mixtures
US4039581A (en) 1975-06-27 1977-08-02 The Upjohn Company Process for the preparation of di(amino phenyl)methanes
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JPH01207259A (ja) * 1988-02-15 1989-08-21 Mitsui Petrochem Ind Ltd ４，４′−メチレンジアニリンの製造方法
IT1312331B1 (it) 1999-05-27 2002-04-15 Enichem Spa Procedimento per la produzione di diamminodifenilmetano e suoiomologhi superiori.
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JP2012131720A (ja) * 2010-12-20 2012-07-12 Tosoh Corp メチレンジアニリン誘導体の製造法
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Publication number Publication date
EP3166922A1 (en) 2017-05-17
WO2016005269A1 (en) 2016-01-14
US10239984B2 (en) 2019-03-26
JP2017523159A (ja) 2017-08-17
US20170158798A1 (en) 2017-06-08
HUE037918T2 (hu) 2018-09-28
CN106660938A (zh) 2017-05-10
KR20170031157A (ko) 2017-03-20
EP3166922B1 (en) 2018-03-14
PT3166922T (pt) 2018-06-15

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