KR20170003528A - 올레핀 중합용 촉매 성분들 - Google Patents

올레핀 중합용 촉매 성분들 Download PDF

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KR20170003528A
KR20170003528A KR1020167026837A KR20167026837A KR20170003528A KR 20170003528 A KR20170003528 A KR 20170003528A KR 1020167026837 A KR1020167026837 A KR 1020167026837A KR 20167026837 A KR20167026837 A KR 20167026837A KR 20170003528 A KR20170003528 A KR 20170003528A
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solid catalyst
catalyst component
esters
compound
polymerization
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Korean (ko)
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시모나 기도티
티치아노 달로꼬
다리오 리구오리
지암피에로 모리니
파브리지오 피에몬테시
지아니 비탈레
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바셀 폴리올레핀 이탈리아 에스.알.엘
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/00—Polymerisation catalysts
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C08F4/6545—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium and metals of C08F4/64 or compounds thereof
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/657—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656
    • C08F4/6576—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656 and aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
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    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020167026837A 2014-03-14 2015-03-10 올레핀 중합용 촉매 성분들 Ceased KR20170003528A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14159900 2014-03-14
EP14159900.1 2014-03-14
PCT/EP2015/054900 WO2015135903A1 (en) 2014-03-14 2015-03-10 Catalyst components for the polymerization of olefins

Related Child Applications (1)

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KR1020187011146A Division KR102138986B1 (ko) 2014-03-14 2015-03-10 올레핀 중합용 촉매 성분들

Publications (1)

Publication Number Publication Date
KR20170003528A true KR20170003528A (ko) 2017-01-09

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KR1020167026837A Ceased KR20170003528A (ko) 2014-03-14 2015-03-10 올레핀 중합용 촉매 성분들
KR1020187011146A Active KR102138986B1 (ko) 2014-03-14 2015-03-10 올레핀 중합용 촉매 성분들

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Country Link
US (1) US10113012B2 (enExample)
EP (1) EP3116921B1 (enExample)
JP (1) JP6470302B2 (enExample)
KR (2) KR20170003528A (enExample)
CN (1) CN106170500B (enExample)
BR (1) BR112016020160B1 (enExample)
ES (1) ES2974931T3 (enExample)
FI (1) FI3116921T3 (enExample)
RU (1) RU2649386C2 (enExample)
WO (1) WO2015135903A1 (enExample)

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WO2017042054A1 (en) * 2015-09-10 2017-03-16 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins
KR102046267B1 (ko) * 2015-09-11 2019-11-18 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분의 제조 방법
US10316122B2 (en) * 2015-11-05 2019-06-11 Basell Poliolefine Italia S.R.L. Heterophasic propylene copolymers
US10556972B2 (en) 2016-11-04 2020-02-11 Basell Poliolefine Italia S.R.L. Process for the polymerization of olefins
BR112020012882A2 (pt) * 2018-02-05 2020-12-08 Basell Poliolefine Italia S.R.L. Componentes e catalisadores para a polimerização de olefinas
US10722874B2 (en) 2018-04-16 2020-07-28 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst utilizing hydrated reagents
ES2946935T3 (es) 2018-08-14 2023-07-28 Basell Poliolefine Italia Srl Componentes y catalizadores para la polimerización de olefinas
CN110938161B (zh) * 2018-09-25 2022-05-24 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系和预聚合催化剂组合物及它们的应用
JP7106241B2 (ja) * 2019-01-09 2022-07-26 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィンの重合用触媒成分
FI4031588T3 (fi) * 2019-09-17 2023-10-18 Basell Poliolefine Italia Srl Katalyyttikomponentteja olefiinien polymerisoimiseksi
CN112707989B (zh) * 2019-10-25 2022-08-19 中国石油化工股份有限公司 一种不含塑化剂的乙丙无规共聚物和应用
CN112707991B (zh) * 2019-10-25 2022-08-19 中国石油化工股份有限公司 一种乙丙无规共聚物及其制备方法
EP4061858B1 (en) 2019-11-20 2023-12-20 Basell Poliolefine Italia S.r.l. Process for the preparation of a catalyst component and components therefrom obtained
CN114667303B (zh) * 2019-12-04 2024-01-26 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂
CN117467037A (zh) * 2022-07-21 2024-01-30 中国石油化工股份有限公司 烯烃聚合用催化剂载体及其制备方法与应用
CN117467044A (zh) * 2022-07-21 2024-01-30 中国石油化工股份有限公司 烯烃聚合用催化剂载体及其制备方法与应用
CN117467045A (zh) * 2022-07-21 2024-01-30 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分与催化剂及其应用
CN117467043A (zh) * 2022-07-21 2024-01-30 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分与用于烯烃聚合的催化剂及其应用

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BR112016020160A2 (enExample) 2017-08-15
KR20180042471A (ko) 2018-04-25
CN106170500A (zh) 2016-11-30
EP3116921A1 (en) 2017-01-18
US10113012B2 (en) 2018-10-30
JP2017507222A (ja) 2017-03-16
RU2649386C2 (ru) 2018-04-03
CN106170500B (zh) 2020-06-12
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US20170066851A1 (en) 2017-03-09
KR102138986B1 (ko) 2020-07-29
BR112016020160B1 (pt) 2021-12-14
ES2974931T3 (es) 2024-07-02
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