KR20140044944A - 방향족 카복실산 공정에서의 스팀 재압축 - Google Patents
방향족 카복실산 공정에서의 스팀 재압축 Download PDFInfo
- Publication number
- KR20140044944A KR20140044944A KR1020147007616A KR20147007616A KR20140044944A KR 20140044944 A KR20140044944 A KR 20140044944A KR 1020147007616 A KR1020147007616 A KR 1020147007616A KR 20147007616 A KR20147007616 A KR 20147007616A KR 20140044944 A KR20140044944 A KR 20140044944A
- Authority
- KR
- South Korea
- Prior art keywords
- steam
- pressure steam
- carboxylic acid
- process stream
- heat transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims abstract description 109
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000012546 transfer Methods 0.000 claims abstract description 37
- 238000007906 compression Methods 0.000 claims abstract description 31
- 230000006835 compression Effects 0.000 claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 claims abstract description 22
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- 230000003647 oxidation Effects 0.000 claims description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 10
- 238000004821 distillation Methods 0.000 claims description 4
- 238000006073 displacement reaction Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract description 15
- 230000003134 recirculating effect Effects 0.000 abstract description 7
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 13
- 239000007789 gas Substances 0.000 description 10
- 238000000926 separation method Methods 0.000 description 9
- -1 Aromatic carboxylic acids Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000010354 integration Effects 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 238000004378 air conditioning Methods 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- XSLGXTDGDJULAR-UHFFFAOYSA-N 2,5-diphenylterephthalic acid Chemical compound OC(=O)C=1C=C(C=2C=CC=CC=2)C(C(=O)O)=CC=1C1=CC=CC=C1 XSLGXTDGDJULAR-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007907 direct compression Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K17/00—Using steam or condensate extracted or exhausted from steam engine plant
- F01K17/02—Using steam or condensate extracted or exhausted from steam engine plant for heating purposes, e.g. industrial, domestic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K15/00—Adaptations of plants for special use
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/772,819 | 2004-02-05 | ||
| US10/772,819 US7213540B2 (en) | 2004-02-05 | 2004-02-05 | Steam recompression in carboxylic acid processes |
| PCT/US2005/002659 WO2005077879A1 (en) | 2004-02-05 | 2005-02-02 | Steam recompression in aromatic carboxylic acid processes |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127029263A Division KR101434771B1 (ko) | 2004-02-05 | 2005-02-02 | 방향족 카복실산 공정에서의 스팀 재압축 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140044944A true KR20140044944A (ko) | 2014-04-15 |
Family
ID=34826662
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147007616A Ceased KR20140044944A (ko) | 2004-02-05 | 2005-02-02 | 방향족 카복실산 공정에서의 스팀 재압축 |
| KR1020127029263A Expired - Lifetime KR101434771B1 (ko) | 2004-02-05 | 2005-02-02 | 방향족 카복실산 공정에서의 스팀 재압축 |
| KR1020067015711A Expired - Lifetime KR101357517B1 (ko) | 2004-02-05 | 2005-02-02 | 방향족 카복실산 공정에서의 스팀 재압축 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127029263A Expired - Lifetime KR101434771B1 (ko) | 2004-02-05 | 2005-02-02 | 방향족 카복실산 공정에서의 스팀 재압축 |
| KR1020067015711A Expired - Lifetime KR101357517B1 (ko) | 2004-02-05 | 2005-02-02 | 방향족 카복실산 공정에서의 스팀 재압축 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7213540B2 (https=) |
| EP (1) | EP1716094B1 (https=) |
| JP (1) | JP2007526915A (https=) |
| KR (3) | KR20140044944A (https=) |
| CN (1) | CN100582077C (https=) |
| BR (1) | BRPI0506961B1 (https=) |
| CA (1) | CA2554281A1 (https=) |
| ES (1) | ES2733316T3 (https=) |
| LT (1) | LT1716094T (https=) |
| MY (1) | MY140552A (https=) |
| PL (1) | PL1716094T3 (https=) |
| PT (1) | PT1716094T (https=) |
| RU (1) | RU2375647C2 (https=) |
| TR (1) | TR201909795T4 (https=) |
| TW (1) | TW200530173A (https=) |
| WO (1) | WO2005077879A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987816B (zh) * | 2009-07-31 | 2013-12-04 | 宜兴市前成生物有限公司 | 富马酸生产过程余热综合利用装置 |
| CN101979129B (zh) * | 2010-10-20 | 2012-10-17 | 南京大学 | 一种苯同系物空气氧化过程尾气的绿色治理工艺 |
| US9062690B2 (en) * | 2010-11-30 | 2015-06-23 | General Electric Company | Carbon dioxide compression systems |
| US20150075450A1 (en) * | 2013-09-13 | 2015-03-19 | Uop Llc | Heat recovery from a high pressure stream |
| JP6564381B2 (ja) * | 2013-12-31 | 2019-08-21 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | 精製芳香族カルボン酸の製造における高圧の凝縮物の生成 |
| US20160010852A1 (en) * | 2014-07-10 | 2016-01-14 | Babcock & Wilcox Power Generation Group, Inc. | Energy recovery for waste gas capture systems |
| CN104649516A (zh) * | 2015-01-29 | 2015-05-27 | 无锡昊瑜节能环保设备有限公司 | 废水及热能回收利用装置 |
| CN115929417A (zh) * | 2022-11-04 | 2023-04-07 | 荣盛石化股份有限公司 | 一种适用于低压蒸汽余热发电的长距离输送方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1373230A (en) | 1971-12-23 | 1974-11-06 | Mitsui Petrochemical Ind | Process for producing terephthalic acid |
| JPS5328421B2 (https=) | 1973-05-15 | 1978-08-15 | ||
| JPS5328901B2 (https=) | 1973-07-28 | 1978-08-17 | ||
| US4158738A (en) | 1977-05-26 | 1979-06-19 | E. I. Du Pont De Nemours And Company | Process for the production of fiber-grade terephthalic acid |
| IT1129759B (it) | 1980-01-23 | 1986-06-11 | Montedison Spa | Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico |
| SU1148848A1 (ru) * | 1984-05-18 | 1985-04-07 | Ленинградский Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета | Непрерывный способ получени галоген-или нитрозамещенных ароматических карбоновых кислот |
| US4939297A (en) | 1989-06-05 | 1990-07-03 | Eastman Kodak Company | Extraction process for removal of impurities from terephthalic acid filtrate |
| US5183933A (en) * | 1991-10-15 | 1993-02-02 | Amoco Corporation | Process for preparing 2,6-naphthalene-dicarboxylic acid |
| JP3291749B2 (ja) | 1992-02-06 | 2002-06-10 | 三菱化学株式会社 | 芳香族カルボン酸の製造方法 |
| GB9210832D0 (en) * | 1992-05-21 | 1992-07-08 | Ici Plc | Bromine catalysed oxidation process |
| JP3198711B2 (ja) | 1993-03-30 | 2001-08-13 | 三井化学株式会社 | テレフタル酸の製造方法および装置 |
| US5612007A (en) * | 1994-10-14 | 1997-03-18 | Amoco Corporation | Apparatus for preparing aromatic carboxylic acids with efficient energy recovery |
| US5567842A (en) | 1994-11-16 | 1996-10-22 | Mitsubishi Chemical Corporation | Process for producing terephthalic acid |
| US5510521A (en) | 1995-03-27 | 1996-04-23 | Eastman Chemical Company | Process for the production of aromatic carboxylic acids |
| US5961942A (en) | 1995-06-05 | 1999-10-05 | E. I. Du Pont De Nemours And Company | Effluent gas treatment |
| US5959140A (en) | 1997-10-03 | 1999-09-28 | Mitsubishi Gas Chemical Company, Inc. | Process for producing aromatic carboxylic acid |
| JP2000072714A (ja) | 1998-08-24 | 2000-03-07 | Mitsui Chemicals Inc | 芳香族カルボン酸の製造方法 |
| JPH11349523A (ja) | 1998-06-10 | 1999-12-21 | Mitsubishi Chemical Corp | 酢酸回収方法 |
| JP3864565B2 (ja) * | 1998-06-19 | 2007-01-10 | 三井化学株式会社 | 芳香族カルボン酸の製造方法 |
| US6143926A (en) | 1999-09-21 | 2000-11-07 | E. I. Du Pont De Nemours And Company | Process for producing pure terephthalic acid with improved recovery of precursors, solvent and methyl acetate |
| US6765113B2 (en) * | 2000-07-19 | 2004-07-20 | E.I. Du Pont De Nemours And Company | Production of aromatic carboxylic acids |
| SE0100244D0 (sv) | 2001-01-25 | 2001-01-25 | Addpower Ab | Sätt att ombandla värmeenergi till mekaniskt arbete |
| US6504051B1 (en) | 2001-06-04 | 2003-01-07 | Eastman Chemical Company | Process for production of aromatic carboxylic acids with improved water removal technique |
| JP2003073327A (ja) | 2001-09-03 | 2003-03-12 | Nippon Shokubai Co Ltd | 有機酸の製造方法 |
| RU2220097C2 (ru) * | 2002-03-06 | 2003-12-27 | Ферд Максим Лейбович | Способ утилизации тепла в процессе производства азотной кислоты |
-
2004
- 2004-02-05 US US10/772,819 patent/US7213540B2/en not_active Expired - Lifetime
-
2005
- 2005-02-01 TW TW094102969A patent/TW200530173A/zh unknown
- 2005-02-02 PL PL05712198T patent/PL1716094T3/pl unknown
- 2005-02-02 PT PT05712198T patent/PT1716094T/pt unknown
- 2005-02-02 KR KR1020147007616A patent/KR20140044944A/ko not_active Ceased
- 2005-02-02 CN CN200580003888A patent/CN100582077C/zh not_active Expired - Lifetime
- 2005-02-02 RU RU2006131668/06A patent/RU2375647C2/ru active
- 2005-02-02 LT LTEP05712198.0T patent/LT1716094T/lt unknown
- 2005-02-02 WO PCT/US2005/002659 patent/WO2005077879A1/en not_active Ceased
- 2005-02-02 CA CA002554281A patent/CA2554281A1/en not_active Abandoned
- 2005-02-02 ES ES05712198T patent/ES2733316T3/es not_active Expired - Lifetime
- 2005-02-02 BR BRPI0506961A patent/BRPI0506961B1/pt active IP Right Grant
- 2005-02-02 KR KR1020127029263A patent/KR101434771B1/ko not_active Expired - Lifetime
- 2005-02-02 JP JP2006552159A patent/JP2007526915A/ja active Pending
- 2005-02-02 KR KR1020067015711A patent/KR101357517B1/ko not_active Expired - Lifetime
- 2005-02-02 EP EP05712198.0A patent/EP1716094B1/en not_active Expired - Lifetime
- 2005-02-02 TR TR2019/09795T patent/TR201909795T4/tr unknown
- 2005-02-04 MY MYPI20050442A patent/MY140552A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR101434771B1 (ko) | 2014-08-26 |
| US7213540B2 (en) | 2007-05-08 |
| RU2006131668A (ru) | 2008-03-10 |
| CA2554281A1 (en) | 2005-08-25 |
| US20050176992A1 (en) | 2005-08-11 |
| KR20060131833A (ko) | 2006-12-20 |
| TW200530173A (en) | 2005-09-16 |
| WO2005077879A1 (en) | 2005-08-25 |
| CN100582077C (zh) | 2010-01-20 |
| PT1716094T (pt) | 2019-07-11 |
| EP1716094B1 (en) | 2019-05-01 |
| LT1716094T (lt) | 2019-07-25 |
| JP2007526915A (ja) | 2007-09-20 |
| RU2375647C2 (ru) | 2009-12-10 |
| CN1922126A (zh) | 2007-02-28 |
| BRPI0506961B1 (pt) | 2015-11-24 |
| MY140552A (en) | 2009-12-31 |
| KR101357517B1 (ko) | 2014-02-03 |
| EP1716094A1 (en) | 2006-11-02 |
| KR20120132581A (ko) | 2012-12-05 |
| ES2733316T3 (es) | 2019-11-28 |
| PL1716094T3 (pl) | 2019-09-30 |
| TR201909795T4 (tr) | 2019-07-22 |
| BRPI0506961A (pt) | 2007-06-26 |
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